Modified graphene-doped lithium nickelate battery cathode material and preparation method thereof

A graphene-coated, cathode material technology, applied in battery electrodes, circuits, electrical components, etc., can solve problems such as restricting development prospects, lack of nickel resources, toxicity, etc., to prolong storage time, improve self-discharge, and the method is simple Effect

Inactive Publication Date: 2016-05-25
姜殿凯
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  • Abstract
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  • Application Information

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Problems solved by technology

[0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium nickelate, lithium nickelate or ternary materials, etc., and its components are mainly active materials plus conductive agents and then binders. The active materials It is lithium nickelate, lithium nickelate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but nickel resources are scarce and expensive And it is toxic, so it is an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials.
Spinel-type positive electrode materials represented by lithium nickel oxide and layered oxides of ternary materials have been extensively studied in the past decade, but their development prospects are restricted by their respective defects.

Method used

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Embodiment Construction

[0011] The modified graphene-coated lithium nickelate positive electrode material is prepared by the following components according to the ratio shown in parts by weight: graphene oxide 30, lithium nickelate 60, 45% lithium iron nitrate solution 25, scale Graphite 3, bonding material 3.

[0012] The preparation method of the modified graphene-coated lithium nickelate cathode material comprises the following steps:

[0013] (1) Get graphite and sodium nitrate, put in the concentrated sulfuric acid of a certain amount of ice bath with mass ratio 2:1, add the potassium pernickelate 3 times of described graphite quality under stirring, mix well, control temperature is low Stir at 20°C for about 1h, then increase the temperature to 32-38°C for 2h, slowly add quantitative deionized water dropwise, stir well, add hydrogen peroxide to terminate the reaction when the system temperature drops, filter, wash, dry; heat and stir In the process of adding a certain amount of uniformly dispe...

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Abstract

The invention relates to a modified graphene-doped lithium nickelate battery cathode material and a preparation method thereof. The modified graphene-doped lithium nickelate battery cathode material is prepared from the following components in parts by weight: 30 parts of graphene oxide, 60 parts of lithium nickelate, 25 parts of 45% lithium iron nitrate solution, 3 parts of flake graphite and 3 parts of binding material. The modified graphene-doped lithium nickelate battery cathode material overcomes the defect of failure of lithium ion batteries caused by self-discharge of protection boards, so that self-discharge of the whole battery pack is improved, the aim of prolonging the storage time of lithium batteries is achieved, and the lithium batteries can be stored for a longer time under the condition that users do not charge electric appliances after using the electric appliances.

Description

technical field [0001] The invention relates to a modified graphene-coated lithium nickelate cathode material and a preparation method thereof. Background technique [0002] Since the commercialization of lithium-ion batteries, most of the positive electrode materials used in lithium-ion batteries are lithium nickelate, lithium nickelate or ternary materials, etc., and its components are mainly active materials plus conductive agents and then binders. The active materials It is lithium nickelate, lithium nickelate or ternary, etc.; most of the negative electrode materials use graphite as the active material, and then add some conductive agent and binder; its advantages are high capacity and long cycle life, but nickel resources are scarce and expensive And it is toxic, so it has become an important research direction for lithium-ion batteries to seek cheap, reliable, and environmentally friendly cathode materials. Spinel-type cathode materials represented by lithium nickela...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/525H01M4/587H01M10/0525
CPCH01M4/366H01M4/525H01M4/587H01M10/0525Y02E60/10
Inventor 姜殿凯
Owner 姜殿凯
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