Method for preparing coordination polymer having frequency-doubled effect

A technology of coordination polymer and frequency doubling effect, applied in the field of preparation of coordination polymers, can solve the problem of not being widely usable, and achieve the effects of easy control, high yield and simple process

Inactive Publication Date: 2017-04-05
LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] The present invention proposes a method for preparing a coordination polymer with frequency-doubling effect, which has wide applicability and solves the problem that the synthesis method of metal organic framework compounds in the prior art can only synthesize one kind of metal organic framework compound , which in turn causes the problem that the usability is not very wide

Method used

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  • Method for preparing coordination polymer having frequency-doubled effect
  • Method for preparing coordination polymer having frequency-doubled effect
  • Method for preparing coordination polymer having frequency-doubled effect

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Embodiment 1

[0026] A kind of preparation method of the coordination polymer with frequency doubling effect, the step is metal salt Y(NO 3 ) 3 ·6H 2 O and sodium isophthalic acid-5-sulfonate are dissolved in water and mixed, and the ratio of metal salt, sodium isophthalic acid-5-sulfonate and water is metal salt: sodium isophthalic acid-5-sulfonate: Water = 1 mmol: 1 mmol: 20 mL, the mixed liquid was put into a reaction kettle and heated at 140 °C for 2 days, then cooled and filtered to obtain block crystal complex 1.

Embodiment 2

[0028] A kind of preparation method of the coordination polymer with frequency doubling effect, the step is metal salt Nd(NO 3 ) 3 ·6H 2 O and sodium isophthalic acid-5-sulfonate are dissolved in water and mixed, and the ratio of metal salt, sodium isophthalic acid-5-sulfonate and water is metal salt: sodium isophthalic acid-5-sulfonate: Water = 1 mmol: 1 mmol: 20 mL, put the mixed liquid into a reaction kettle, heat at 130 °C for 5 days, then cool and filter to obtain block crystal complex 2.

Embodiment 3

[0030] A kind of preparation method of the coordination polymer with frequency doubling effect, the step is metal salt Ce(NO 3 ) 3 ·6H 2 O and sodium isophthalic acid-5-sulfonate are dissolved in water and mixed, and the ratio of metal salt, sodium isophthalic acid-5-sulfonate and water is metal salt: sodium isophthalic acid-5-sulfonate: Water = 0.5 mmol: 1 mmol: 20 mL, the mixed liquid was put into a reaction kettle and heated at 150 °C for 3 days, then cooled and filtered to obtain block crystals.

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Abstract

The invention relates to the field of second-order nonlinear optics and concretely relates to a method for preparing a coordination polymer having a frequency-doubled effect. The method comprises dissolving a metal salt and 5-sulfoisophthalic acid monosodium salt in water according to ratio of the metal salt, 5-sulfoisophthalic acid monosodium salt to water of 0.5 to 2mmol: 0.5 to 2mmol: 10 to 30mL, carrying out mixing, putting the mixed liquid into a reactor, heating the mixed liquid at a temperature of 120 to 150 DEG C for 2 to 5 days, and carrying out cooling and filtration to obtain bulk crystals. The kind of the materials with the frequency-doubled effect is expanded to the field of metal organic framework compounds. The produced compound has the frequency-doubled effect, fluorescence properties and magnetic properties. The synthesis method is simple and is easy to control and has a high yield.

Description

technical field [0001] The invention relates to the field of second-order nonlinear optics, in particular to a preparation method of a coordination polymer with frequency doubling effect. Background technique [0002] The existing second-order nonlinear optical materials are mostly concentrated in lithium iodate, lithium niobate, etc., and semiconductor crystals, such as tellurium and red silver ore (Ag 3 AsS 3 ), etc. These materials have good thermal stability and do not decompose at higher temperatures. [0003] At the same time, the existing methods for synthesizing metal-organic framework compounds with frequency-doubling effect are not very widely used, and only a metal-organic framework compound with frequency-doubling effect is synthesized. [0004] Chinese patent application CN 105568380 A "A Novel Infrared Nonlinear Optical Material and Its Preparation Method and Application" discloses a novel infrared nonlinear optical material with the molecular formula RbHgI ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G83/00
CPCC08G83/008
Inventor 关磊王莹
Owner LIAONING UNIVERSITY OF PETROLEUM AND CHEMICAL TECHNOLOGY
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