Medicament and method for synchronously fixing and reducing trichloro ethylene in soil and/or underground water
A technology of trichloroethylene and groundwater, applied in chemical instruments and methods, restoration of polluted soil, soil conditioning materials, etc. Low environmental risk, improved removal rate, and low secondary pollution
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Embodiment 1
[0061] Present embodiment provides a kind of medicament for synchronously fixing and reducing trichlorethylene in soil and / or ground water, and this medicament comprises the bentonite of 3200g, the nano-iron of 800g, the persulfate and water of 384g, the total mass of bentonite and nano-iron The mass ratio of water to water is 1:50; among them, bentonite is sodium-based bentonite, and Na in sodium-based bentonite + The content is 2.6wt%, the total organic carbon content is 13.7mg / L, the pH is 10.5, and the particle size is 150μm; the persulfate is sodium persulfate; Fe in nano-iron 0 content of 70wt%, α-Fe content of 74wt%, Fe 3 o 4 The content is 18wt%, the FeO content is 8wt%, and the particle size is 50nm;
[0062] The microscopic characterization of bentonite in this embodiment is as follows: Figure 13 and Figure 14 ,from Figure 13 It can be known that the surface of bentonite is irregular polygon, smooth and angular; Figure 14 It can be known that it is mainly c...
Embodiment 2
[0066] Present embodiment provides a kind of medicament for synchronously fixing and reducing trichlorethylene in soil and / or ground water, and this medicament comprises the bentonite of 3200g, the nano iron of 800g, the persulfate of 384g and water, and the mass ratio of bentonite and water is 1:50; Among them, bentonite is sodium bentonite, Na in sodium bentonite + The content is 2.6wt%, the total organic carbon content is 13.7mg / L, the pH is 10.6, the particle size is 120μm, the persulfate is potassium persulfate; Fe in nano-iron 0 content of 70wt%, α-Fe content of 74wt%, Fe 3 o 4 The content is 18wt%, the FeO content is 8wt%, and the particle size is 50nm;
[0067]Simulate the application environment, apply the medicament in this embodiment to 10 mg / kg of TCE-containing soil, the specific application method is as follows: add the persulfate in the medicament to 10 mg / kg of TCE-containing soil, and then add the medicament Bentonite, nano-iron and water in the medicament,...
Embodiment 3
[0069] Present embodiment provides a kind of medicament for synchronously fixing and reducing trichlorethylene in soil and / or ground water, and this medicament comprises the bentonite of 3800g, the nano-iron of 750g, the persulfate and water of 400g, the total mass of bentonite and nano-iron The mass ratio of water to water is 1:55; among them, bentonite is sodium-based bentonite, and Na in sodium-based bentonite + The content is 2.5wt%, the total organic carbon content is 14mg / L, the pH is 10.8, the particle size is 130μm, and the persulfate is sodium persulfate; Fe in nano-iron 0 content of 65wt%, α-Fe content of 78wt%, Fe 3 o 4 The content is 15wt%, the FeO content is 10wt%, and the particle size is 25nm;
[0070] Simulate the application environment, apply the medicament in this embodiment to the groundwater containing TCE of 10mg / L, the specific application method is as follows: the persulfate and water in the medicament are added to the groundwater containing TCE of 10...
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