Dehydration tower extraction process in ethyl acetate production
A technology of ethyl acetate and dehydration tower, which is applied in the separation/purification of carboxylic acid esters, organic chemistry, etc. It can solve the problems of poor dehydration effect, residual impurities that easily pollute the environment, extraction and condensation effects, etc., to achieve easy control and improve preparation The purity of the finished product and the effect of simple operation steps
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specific Embodiment 1
[0058] 1. Put crude ethyl acetate containing water, acetic acid and ethanol at a temperature of 75°C into the dehydration tower from the middle of the rectification tower to form a ternary azeotrope of ethanol, water and ethyl ester;
[0059] 2. After the ternary azeotrope rectification, the head oil containing ethanol, water and a small amount of ethyl acetate is obtained at the top of the dehydration tower, the residual liquid containing acetic acid is obtained at the bottom of the dehydration tower, and ethyl acetate is obtained in the dehydration tower;
[0060] 3. Discharge the residual liquid from the bottom of the dehydration tower;
[0061] 4. Extract the head oil from the top of the dehydration tower, after condensation, carry out phase separation treatment to obtain water and oil phases, discharge the water, reflux part of the oil phase, the reflux ratio is 8:1, and recover the rest of the oil phase;
[0062] 5. Cool the ethyl acetate obtained in the tower, and parti...
specific Embodiment 2
[0064] 1. Put crude ethyl acetate containing water, acetic acid and ethanol at a temperature of 80°C into the dehydration tower from the middle of the rectification tower to form a ternary azeotrope of ethanol, water and ethyl ester;
[0065] 2. After the ternary azeotrope rectification, the head oil containing ethanol, water and a small amount of ethyl acetate is obtained at the top of the dehydration tower, the residual liquid containing acetic acid is obtained at the bottom of the dehydration tower, and ethyl acetate is obtained in the dehydration tower;
[0066] 3. Discharge the residual liquid from the bottom of the dehydration tower;
[0067] 4. Extract the head oil from the top of the dehydration tower, after condensation, carry out phase separation treatment to obtain water and oil phases, discharge the water, reflux part of the oil phase, the reflux ratio is 11:1, and recover the rest of the oil phase;
[0068] 5. Cool the ethyl acetate obtained in the tower, and part...
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