A kind of multi-cation side chain type anion exchange membrane prepared based on soft template method and its preparation method

An anion exchange membrane and polycation technology, applied in the field of polycation side chain type anion exchange membrane and its preparation, can solve the problems of poor selectivity, low ion flux, etc., to promote formation, increase ion flux, and improve selectivity Effect

Active Publication Date: 2022-03-29
DALIAN UNIV OF TECH
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at the problems of low ion flux and poor selectivity mentioned above, the present invention proposes an anion exchange membrane induced by a soft template method to be applied in electrodialysis. Polyphenylene ether with excellent chemical stability and thermal stability as the main chain, the membrane has high ion flux and good selectivity

Method used

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  • A kind of multi-cation side chain type anion exchange membrane prepared based on soft template method and its preparation method
  • A kind of multi-cation side chain type anion exchange membrane prepared based on soft template method and its preparation method
  • A kind of multi-cation side chain type anion exchange membrane prepared based on soft template method and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0041] (1) Preparation of brominated polyphenylene ether

[0042] Dissolve 12g of polyphenylene ether in 100mL of chlorinated benzene, and add a mixed reagent of N-bromosuccinimide and azobisisobutyronitrile at a molar ratio of 10:1, wherein N-bromosuccinimide 5.34g. The reaction was carried out at 120° C. for 4 hours. The reactant was poured into 1000 mL of absolute ethanol for precipitation, washed with absolute ethanol until the supernatant was colorless, and then vacuum-dried at 40° C. for 48 hours to obtain a polymer: brominated polyphenylene ether. The degree of bromination of the brominated polyphenylene ether is 10%.

[0043] figure 1 H for the brominated polyphenylene ether prepared in Example 1 1 NMR spectrum, wherein the peak generated at 4.3ppm is the peak of bromomethyl group, which proves the successful preparation of brominated polyphenylene ether.

[0044] (2) Preparation of ionizing reagents

[0045] First, 37.9 mL of 1,6-dibromohexane was dissolved in ...

Embodiment 2

[0055] (1) Preparation of brominated polyphenylene ether

[0056] Dissolve 12g of polyphenylene ether in 100mL of chlorinated benzene, and add a mixed reagent of N-bromosuccinimide and azobisisobutyronitrile at a molar ratio of 12:1, wherein N-bromosuccinimide 6.23 g. The reaction was carried out at 125°C for 3.5 hours. The reactant was poured into 1000 mL of methanol for precipitation, washed with methanol until the supernatant was colorless, and then vacuum-dried at 40° C. for 48 hours to obtain a polymer: brominated polyphenylene ether. The degree of bromination of the brominated polyphenylene ether is 10%.

[0057] (2) Preparation of ionizing reagents

[0058] First, dissolve 37.9mL of 1,6-dibromohexane in 90mL of tetrahydrofuran to form a co-solution, pass 59.1mL of trimethylamine solution into the co-melt solution 1 at 80°C, react at 30°C for 18 hours and then vacuum After filtration, it was washed with tetrahydrofuran, and vacuum-dried at 40°C for 48 hours to obtain...

Embodiment 3

[0066] (1) Preparation of brominated polyphenylene ether

[0067] Dissolve 12g of polyphenylene ether in 100mL of chlorinated benzene, and add a mixed reagent of N-bromosuccinimide and azobisisobutyronitrile at a molar ratio of 15:1, wherein N-bromosuccinimide 7.12 g. The reaction was carried out at 130° C. for 3 hours. The reactant was poured into 1000 mL of absolute ethanol for precipitation, washed with absolute ethanol until the supernatant was colorless, and then vacuum-dried at 40° C. for 48 hours to obtain a polymer: brominated polyphenylene ether. The degree of bromination of the brominated polyphenylene ether is 10%.

[0068] (2) Preparation of ionizing reagents

[0069] First, dissolve 37.9mL of 1,6-dibromohexane in 90mL of tetrahydrofuran to form a co-solution, pass 52.6mL of trimethylamine solution into the co-melt 1 at 80°C, react at 35°C for 14 hours, and then vacuum After filtration, it was washed with tetrahydrofuran, and vacuum-dried at 40°C for 48 hours t...

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Abstract

The invention relates to a multi-cation side chain type anion exchange membrane prepared based on a soft template method and a preparation method thereof, belonging to the field of electrodialysis anion exchange membrane materials. First, brominated polyphenylene ether was prepared by bromination of polyphenylene ether, and then three polycation side chains of quaternary ammonium salts in series were prepared by two-step synthesis, and finally the polycation side chain and brominated polyphenylene ether were synthesized by Menshow The anion exchange membrane is prepared by gold reaction, and the introduction of small molecules containing two sulfonic acid heels is induced by electrostatic force, and finally the anion exchange membrane is prepared by solution casting. The prepared polycation side chain type anion exchange membrane can be applied in the field of electrodialysis. The preparation method of the present invention is simple, and the prepared anion exchange membrane has a high ion exchange capacity, and the membrane can ensure a high concentration of fixed ion groups under the condition of low water absorption and high ion exchange capacity, thereby improving the selectivity of the anion exchange membrane; The channels enhance the ion flux of the anion exchange membrane.

Description

technical field [0001] The invention belongs to the field of electrodialysis anion exchange membrane materials, and relates to a polycation side chain type anion exchange membrane prepared based on a soft template method and a preparation method thereof. Background technique [0002] With the rapid development of society and rapid population growth, the problems of resource scarcity and environmental pollution are becoming more and more serious. These problems force people to devote themselves to the research and development of efficient technologies for resource recovery and pollutant treatment. Compared with physical separation (distillation, rectification, etc.) and chemical precipitation separation technology, electrodialysis technology occupies a place in the separation industry with its inherent advantages of low energy consumption, low cost, high-efficiency separation, environmental friendliness and convenient operation. Electrodialysis desalination technology has bec...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G65/48B01D61/48
CPCC08G65/485B01D61/485
Inventor 张凤祥张安然李旅马玲玲白雷
Owner DALIAN UNIV OF TECH
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