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Solid oxide cell stack with differential pressure between anode and cathode compartments

A solid oxide and battery stack technology, applied in the field of solid oxide fuel cells, SOC stacks, and solid oxide electrolysis cells, can solve problems such as failure of the entire stack

Pending Publication Date: 2022-05-27
HALDOR TOPSOE AS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Mechanical failure of a single SOC in the stack will often result in failure of the entire stack

Method used

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  • Solid oxide cell stack with differential pressure between anode and cathode compartments

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Embodiment

[0049] The design of the present invention was tested in two short SOC stacks containing 9 single repeating cells. The distance between the contact points / ribs on the low pressure oxygen side was 1.3mm and the fuel side was pressurized to 1.75bara, creating a fuel to oxygen side pressure differential of up to 750mbar.

[0050] The first test was conducted in electrolysis mode, where the fuel contained 5% hydrogen in steam. The oxygen side was flushed with air and kept at ambient pressure (1.013 bara) throughout the test. The inlet gas was heated to 750°C and the stack was installed in the furnace to stabilize the temperature around the stack at 750°C. stack at about 0.75A / cm 2 run at the current density. The table below shows the average cell voltage at selected operating points with increasing fuel side pressure.

[0051] fuel side pressure differential pressure Average battery voltage [bara] [mbar] [mV] 1.02 8 1255 1.26 250 1253 1.5...

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Abstract

The SOC stack has an interconnect with a maximum distance between contact points, which is designed to compensate for a pressure difference between one side and the other side of the interconnect.

Description

technical field [0001] The present invention relates to a solid oxide cell (SOC) stack, in particular a solid oxide fuel cell (SOFC) cell or a solid oxide electrolysis cell (SOEC) cell, in particular for oxygen in the fuel compartment of the SOC cell and in the SOC cell An SOC stack with a pressure difference between the compartments, the cells are stacked on top of each other to form an SOC stack. Background technique [0002] The present invention proposes a design for a solid oxide cell (SOC) stack that is mechanically robust to operate in the presence of a pressure differential between the fuel and oxygen compartments of the stack. This is achieved by choosing the distance between the contact points / ribs on the low pressure side of the SOC such that the maximum tensile stress of the SOC due to the applied pressure difference between the two sides of the cell is significantly lower than the Weibull strength of the SOC. [0003] Solid oxide cells (SOCs) typically consist ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/0254H01M8/0256H01M8/026H01M8/0432H01M8/0438H01M8/12
CPCH01M8/0254H01M8/0256H01M8/026H01M8/0432H01M8/0438H01M8/04432H01M8/12H01M2008/1293Y02E60/50H01M8/0247H01M8/0236H01M8/0228H01M8/04104H01M8/2425H01M2300/0071
Inventor R·金加斯T·海雷达尔-克劳森B·P·G·布伦诺T·H·诺比J·拉斯-汉森
Owner HALDOR TOPSOE AS