Novel APG curing agent for Pb < 2 + > pollution treatment and preparation method thereof

A curing agent and a new type of technology, used in adsorption water/sewage treatment, water/sludge/sewage treatment, flocculation/sedimentation water/sewage treatment, etc. Difficult to use polymers and other problems, to achieve the effect of increased strength

Pending Publication Date: 2022-07-29
SHAOXING UNIVERSITY +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the activator used in the base-activated polymer is strongly basic NaOH, Na 2 SiO 3 The solution is highly corrosive and will corrode construction equipment, making it difficult for alkali-activated polymers to be used in projects
The wastewater discharged from many mines is mostly strongly acidic wastewater. For example, sulfur-containing mine wastewater is acidic water, and its pH is generally 4.5-6.5. Especially, the pH of mine water in southern China is generally 3.0-3.5, and sometimes the pH can reach 2. In such a In a strongly acidic environment, conventional curing agents are obviously not suitable for treating polluted soil around mines

Method used

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  • Novel APG curing agent for Pb &lt; 2 + &gt; pollution treatment and preparation method thereof
  • Novel APG curing agent for Pb &lt; 2 + &gt; pollution treatment and preparation method thereof
  • Novel APG curing agent for Pb &lt; 2 + &gt; pollution treatment and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0034] This example is for Pb 2+ A novel APG curing agent for pollution treatment, characterized in that the components of the APG curing agent include a phosphate activator solution and fly ash powder, and the amounts of the phosphate activator solution and the fly ash powder are used The ratio is 0.3 to 0.4.

[0035] In this embodiment, the phosphate activator solution is an aluminum dihydrogen phosphate solution, and the concentration of the aluminum dihydrogen phosphate solution is 35%; the fly ash powder low-calcium fly ash, the fly ash The particle size of the powder is 1250 mesh.

[0036] Preferably, the dosage ratio of the phosphate activator solution and the fly ash powder is 0.317.

Embodiment 2

[0038] For Pb in Example 1 2+ The preparation method of the novel APG curing agent for pollution treatment comprises the following steps:

[0039] The fly ash powder with a particle size of 1250 mesh and the aluminum dihydrogen phosphate solution with a concentration of 35% are mixed and stirred evenly, and the stirring time is 60s to prepare a phosphoric acid base polymer curing agent slurry, that is, APG curing agent; The dosage ratio of the phosphate activator solution and the fly ash powder is 0.317;

[0040] The heavy metal Pb (NO 3 ) 2 Dissolved in distilled water to obtain Pb-containing 2+ of polluted water, the Pb-containing 2+ of Pb in contaminated water 2+ The content of Pb is 0%, 0.4% and 1.0% respectively, and then added to the prepared phosphoric acid base polymer curing agent slurry, uniformly stirred for 1 min to obtain a slurry; the Pb-containing 2+ The dosage ratio of the polluted water and the fly ash powder is 0.064; the obtained slurry is poured into ...

Embodiment 3

[0051] For Pb in Example 1 2+ The preparation method of the novel APG curing agent for pollution treatment comprises the following steps:

[0052] The fly ash powder with a particle size of 1250 mesh and the aluminum dihydrogen phosphate solution with a concentration of 35% are mixed and stirred evenly, and the stirring time is 90s to prepare a phosphoric acid base polymer curing agent slurry, that is, APG curing agent; The dosage ratio of the phosphate activator solution and the fly ash powder is 0.4;

[0053] The APG curing agent for Pb 2+ The use method of pollution treatment is: the Pb 2+ The pollutants are dissolved in distilled water to obtain Pb-containing 2+ of contaminated water, and then the Pb-containing 2+ The polluted water was added to the prepared phosphoric acid base polymer curing agent slurry, and stirred uniformly for 2 minutes to obtain a slurry; the slurry was poured into a size of 20 × 20 × 20 m 3 d mold (see figure 1 ) in and after the maintenance,...

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Abstract

The invention provides a novel APG curing agent for Pb < 2 + > pollution treatment, the APG curing agent comprises a phosphate activator solution and fly ash powder, and the dosage ratio of the phosphate activator solution to the fly ash powder is 0.3-0.4; the invention also provides a preparation method of the APG curing agent, which comprises the following steps: uniformly mixing and stirring fly ash powder and an aluminum dihydrogen phosphate solution to prepare phosphoric acid-based geopolymer curing agent slurry, namely the APG curing agent; the use method of the APG curing agent for Pb < 2 + > pollution treatment comprises the following steps: dissolving a Pb < 2 + > pollutant in distilled water, then adding into a phosphoric acid-based geopolymer curing agent, and uniformly stirring to obtain slurry; and pouring the slurry into a mold for curing. The preparation method is simple and convenient, low in cost and stable in performance, the prepared APG curing agent belongs to an acid curing agent and is different from an existing curing agent, and the prepared APG curing agent is good in curing effect, low in carbon and environmentally friendly.

Description

technical field [0001] The invention belongs to the technical field of curing agents, in particular to a kind of curing agent for Pb 2+ A novel APG curing agent for pollution treatment and a preparation method thereof. Background technique [0002] Lead is a potentially toxic element that, when absorbed by the body, accumulates in organs such as the blood, bones, liver, kidneys, brain, and skin. Pb 2+ It not only harms human health, but also pollutes soil and groundwater resources. Therefore, by using low-cost and efficient curing agent in Pb 2+ It is necessary to treat contaminated soil or solid waste before the material is released. [0003] Solidification / stabilization (S / S) is a relatively mature, fast, economical and convenient method for the treatment of contaminated soil. Cement stabilization is a practical way to treat lead-contaminated soils, but cement treatment of Pb 2+ There are some problems. During the hydration process of cement, it is difficult for cem...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C04B12/00C04B28/00C02F1/56C02F1/28C02F101/20
CPCC04B12/005C04B28/006C02F1/56C02F1/285C02F2101/20C04B2111/00784C04B2201/50C04B22/16C04B18/08C04B22/0046
Inventor浦少云王伟段伟李娜姜屏
OwnerSHAOXING UNIVERSITY