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Cementitious compositions and a method of their use

A composition, cement technology, applied in the field of surface treatment, rock surface

Inactive Publication Date: 2005-03-30
FOSROC MINING INT LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] Another issue is the need to increase early tensile strength, such as that exhibited at 2 or 4 hours after the coating is used in mines

Method used

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  • Cementitious compositions and a method of their use
  • Cementitious compositions and a method of their use
  • Cementitious compositions and a method of their use

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-4

[0082] Examples 1-3 are not according to the invention, but are intended for comparison.

[0083] A series of curable coating compositions were prepared with varying amounts of calcium sulfate and the various compositions were used as coatings.

[0084] After the coating was formed, the tensile strength was measured at intervals from 2 hours.

[0085] Flexibility at 6 months was also measured.

[0086] Details of the composition are summarized in Table 1 along with the results of the tensile strength and flexibility measurements.

[0087] All parts used are by weight.

[0088] R.H. means relative humidity.

[0089] HAC means high alumina cement.

[0090] Table 1

[0091] Example 1

Example 2

Example 3

Example 4

Component A

HAC *

70.36

80.27

88.40

99.40

Anhydrite

29.31

19.13

11.00

0.00

lithium carbonate

0.10

...

Embodiment 5 and 6

[0098] Examples 5 and 6 are examples according to the present invention. Different amounts of fiber were included in Examples 5 and 6.

[0099] The tensile strength of the coating obtained from the composition was measured at time intervals from 2 hours after the coating was formed.

[0100] Details of the composition and tensile strength measurements are shown in Table 2.

[0101] Table 2

[0102] Component A

Example 4

Example 5

Example 6

HAC

99.4

98.1

96.8

Anhydrite

0.00

0.00

0.00

lithium carbonate

0.44

0.44

0.44

Sodium enanthate

0.16

0.16

0.16

Fiber (+%)

0

1.3

2.6

total

100.00

100.00

100.00

Component B

Taevalon

200.00

200.00

200.00

Weight ratio of component B to component A

2∶1

...

Embodiment 7-12

[0112] A series of compositions were prepared with varying amounts of fiber and used as coatings.

[0113] HAC and fibers were the same as those used in Examples 5 and 6.

[0114] After the coating was formed, the tensile strength was measured at intervals from 2 hours.

[0115] Flexibility at 6 months was also measured.

[0116] The details of the compositions are reported in Table 3 along with the results of the tensile strength measurements.

[0117] table 3

[0118] Example number

7

8

9

10

11

12

Component A

weight

weight

weight

weight

weight

weight

HAC

99.41

98.91

98.41

97.41

96.41

95.41

lithium carbonate

0.43

0.43

0.43

0.43

0.43

0.43

Sodium enanthate

0.16

0.16

0.16

0.16

0.16...

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Abstract

A settable composition comprising (i) a cementitious component comprising at least 25 % of calcium aluminate of which at least 40 % is calcium monoaluminate said cementitious component optionally containing one or more particulate fillers but containing less than 10 % by weight of calcium sulphate, the % being by weight being based on the weight of the cementitious component and (ii) an aqueous emulsion of an organic polymer, the amount of (ii) in relation to (i) being such as to provide a weight ratio of polymer solids to weight of (i) of from 0.5:1 to 10:1, preferably 0.6:1 to 2.5:1 or (iii) a dispersible organic polymer and where the amount of dispersible polymer is such as to give a weight ratio of polymer to weight of (i) of from 0.5:1 to 10:1, preferably 0.6:1 to 2.5:1. The cementitious component (i) preferably contains an amount of fibre effective to improve the tensile strength of coatings obtained from the settable composition but not exceeding 5 % by weight of the cementitious component (i). The dry composition comprising parts (i) and (iii) above can be mixed with water in the mine.

Description

technical field [0001] The present invention relates to materials suitable for coating surfaces, especially rocky surfaces, to methods for their preparation and to methods of surface treatment using the materials of the invention. Background technique [0002] Coatings have been proposed in the past to be applied to rock surfaces in mines for the purpose of providing support or gas barriers by spraying an aqueous emulsion of an organic polymer and allowing the emulsion to coagulate to create a film or gas barrier on the surface. A flexible coating in the form of a skin. Polymers that have been disclosed for this purpose include polyurethanes and polychloroprene. The latter has been disclosed in South African Patent No. 8203384. [0003] More recently WO 98 / 58886 discloses a two-part composition. Some are aqueous emulsions of organic polymers, such as copolymers of ethylene and vinyl acetate. The other part is a cementitious composition capable of absorbing at least its o...

Claims

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Application Information

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IPC IPC(8): C04B7/32C04B7/36C04B9/11C04B11/28C04B28/00C04B28/06
CPCC04B28/06C04B2111/00155C04B2111/00482C04B2111/00724C04B20/0048C04B22/143C04B24/26C04B40/065C04B22/064
Inventor 雅罗斯瓦夫·拉齐米日·德罗兹德罗德里克·麦克唐纳·斯马特
Owner FOSROC MINING INT LTD