Surface modifying agent, laminated structure and transistor including the same, and method of manufacturing the laminated structure
a technology of surface modifying agent and laminated structure, which is applied in the direction of group 3/13 element organic compounds, natural mineral layered products, nuclear engineering, etc., can solve the problems of difficult to provide a fine pattern, complicated solution process, and low energy and material efficiency,
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example 1
Manufacturing Laminated Structure
[0216]A silicon oxide layer may be formed on a surface of a silicon wafer (Si wafer) in accordance with heat treatment. The silicon oxide layer has a thickness of 300 Å.
[0217]The silicon wafer formed with silicon oxide layer may be immersed in a solution in which 400 μl 7-octynyltrichlorosilane may be dissolved in 200 ml of hexane, for 20 minutes. As a result, a self-assembled monolayer of a 7-octynyl trichlorosilyl group may be formed on the silicon oxide layer of the silicon wafer.
[0218]The silicon wafer formed with the self-assembled monolayer may be subjected to H2 plasma treatment using a mask. On the exposure region treated with H2 plasma, the terminal ethynyl group may be transferred mostly to an ethyl group and partially to an ethenyl group.
[0219]FIG. 9 shows Raman spectra before and after the H2 plasma treatment. In FIG. 9, A refers to the Raman spectrum before the plasma treatment, and B refers to the Raman spectrum after the plasma treatme...
example 2
Manufacturing Copper (Cu)-Deposited Laminated Structure
[0222]Copper (Cu) may be deposited on a self-assembled monolayer including a 1,2,3-triazole group of the silicon wafer obtained from Example 1 at a deposition speed of 1.0 Å / sec according to a thermal evaporation method. The copper (Cu) has a deposition thickness of 700 Å. Thereby, a copper (Cu)-deposited laminated structure may be provided.
example 3
Manufacturing Transistor Using Copper (Cu)
[0225]A copper (Cu)-deposited laminated structure may be manufactured in accordance with the same processes as in Examples 1 and 2, except that silicon doped with phosphorus (P) may be deposited on a part of a silicon wafer (Si wafer) before a silicon oxide layer may be formed on the surface of the silicon wafer. A transistor having the structure shown in FIG. 7 may be manufactured by evaporating pentacene on the region without deposited copper (Cu) in the laminated structure.
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