Preparation method of fresh-keeping film with high carbon dioxide permeability and application thereof
A carbon dioxide, high permeability technology, used in applications, fruit and vegetable preservation, food preservation, etc., can solve problems such as mechanical damage, loss of permeability selectivity, and poor strength
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Embodiment 1
[0013] Mix 100mL of 20% polyethyleneimine (molecular weight 75000) aqueous solution with 5% polyvinyl alcohol (molecular weight 18000, alcoholysis degree 95%) aqueous solution 200mL, defoam and filter and evenly coat on the blue non-woven fabric On, coating amount 200mL / m 2 . Afterwards, put it flat into a clean constant temperature and humidity chamber set at 50°C for 18 hours, then raise the temperature to 130°C and maintain it for 1 hour to obtain a carbon dioxide highly gas-permeable film. The carbon dioxide permeability coefficient of the membrane is 4.5×10 by air permeability measurement. 6 mL / m 2 ·d·atm (the difference in partial pressure of carbon dioxide on both sides of the membrane is 1% of atmospheric pressure), and the permeation ratio of carbon dioxide / oxygen is 386:1. The obtained film is cut into a square of 10cm * 15cm, and the edge of the square film is heat-sealed on the central part of one side of a common polyethylene fresh-keeping bag whose specificati...
Embodiment 2
[0017] Mix 50mL of 25% polyethyleneimine (molecular weight 75000) aqueous solution with 5% polyvinyl alcohol (molecular weight 18000, alcoholysis degree 95%) aqueous solution 200mL, defoam and filter and evenly coat on the blue non-woven fabric On, coating amount 150mL / m 2 . Afterwards, put it flat into a clean constant temperature and humidity chamber set at 60°C for 20 hours, then raise the temperature to 140°C and maintain it for 1 hour to prepare a carbon dioxide highly gas-permeable film. The carbon dioxide permeability coefficient of the membrane is 4.8×10 after air permeability measurement. 6 mL / m 2 ·d·atm (the partial pressure difference of carbon dioxide on both sides of the membrane is 1% of atmospheric pressure), and the carbon dioxide / oxygen permeation ratio is 353:1. The obtained film is cut into a square of 10cm * 15cm, and it is heat-sealed on the common polyethylene fresh-keeping bag of the same specification in the same manner as the previous example. Pack...
Embodiment 3
[0021] Among the above-mentioned examples: use polyethyleneimine with molecular weight between 2000-750000, the concentration of its solution is 10%; use polyvinyl alcohol with molecular weight between 10000-50000, alcoholysis degree more than 90%, the concentration of its solution is 1 %.
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