Strontium rubidium tartrate tetrahydrate compound nonlinear optical crystal as well as preparation method and application thereof
A compound, tetrahydrate technology, used in nonlinear optics, optics, instruments, etc., can solve problems such as narrow tuning range, and achieve the effect of simple crystal preparation and short growth cycle
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Embodiment 1
[0035] Taking the chemical reaction formula (1) as an example, the specific operation steps are as follows:
[0036] Weigh SrCl with a molar ratio of 1:2:2 2 ·6H 2 O, L(+)-C 4 h 6 o 6 and H 3 BO 3 For solid powder, dissolve it in a container filled with 100mL deionized water, shake the solution gently, and let it stand for half an hour to dissolve completely. In order to make the dissolution and mixing even, treat it in ultrasonic waves at a temperature of 30°C for 30 minutes, and finally become clear and transparent;
[0037] Then take out the container with the solution, let it cool down to room temperature naturally, and then add Rb 2 CO 3 Add about 0.1g to the solution one by one, shake the container gently during the addition process, when the pH value reaches 7, white insoluble matter begins to appear in the solution, continue to adjust the pH value to 8 and stop adding Rb 2 CO 3 , treated in ultrasonic for 30min, so that the reaction is sufficient, and the whit...
Embodiment 2
[0042] Take the chemical reaction formula (2) as an example:
[0043] Weigh 1:3:3 SrCl 2 ·6H 2 O, L(+)-C 4 h 6 o 6 and H 3 BO 3 For solid powder, dissolve it in a container filled with 200mL of deionized water, shake the solution gently, and let it stand for half an hour to dissolve completely. In order to make the solution mix evenly, treat it in an ultrasonic wave at a temperature of 35°C for 30 minutes, and finally become clear and transparent;
[0044] Then take out the container containing the solution, let it cool down to room temperature naturally, then add about 0.1g of RbOH to the solution one by one, shake the container constantly during the addition process, when the pH value reaches 7, the solution begins to appear white For insoluble matter, continue to adjust the pH value to 9, stop adding RbOH, and treat it in ultrasonic wave for 30 minutes, so that the reaction is sufficient, and the white insoluble matter is evenly deposited on the bottom of the containe...
Embodiment 3
[0049] Take the chemical reaction formula (1) as an example:
[0050] Weigh SrCl with a molar ratio of 1:2:10 2 ·6H 2 O, L(+)-C4H 6 o 6 and H 3 BO 3 For solid powder, dissolve it in a container filled with 500mL deionized water, shake the solution gently, and let it stand for half an hour to dissolve completely. In order to make the solution mix evenly, treat it in an ultrasonic wave at a temperature of 40°C for 30 minutes, and finally become clear and transparent;
[0051] Then take out the container with the solution, let it cool down to room temperature naturally, and then add Rb 2 CO 3 Add about 0.1g to the solution one by one, shake the container gently during the addition process, when the pH value reaches 7, white insoluble matter begins to appear in the solution, continue to adjust the pH value to 12 and stop adding Rb 2 CO 3 , treated in ultrasonic for 30 minutes, so that the reaction is sufficient, and the white insoluble matter is evenly deposited on the bot...
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