Application of diacetyl baicalein in preparing antifebrile
A technology of baicalein and diacetyl, which is applied in the application field of diacetylated baicalein in the pharmaceutical field, and can solve problems such as unsatisfactory antipyretic and analgesic effects
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Embodiment 1
[0061] Preparation of diacetylated baicalein:
[0062] (a). Preparation of baicalein: 1 kg of baicalin was dissolved in 30 liters of water, 0.3 kg of glucuronidohydrolase was added, stirred at 50°C for 4 days, filtered, and the precipitate was washed with water and dried to obtain baicalein ( 0.6 kg).
[0063] Identification of Baicalein: Mass Spectrometry EI-MS: m / z 270[M] + ; UV spectrum max (MeOH) nm: 277,315; mp.273-275.
[0064] 1H-NMR (dmso-d6): 12.64 (1H, s, 5-OH), 10.55 (1H, 7-OH s), 8.80 (1H, s, 6-OH), 8.04 (2H, d , J=6.0Hz, H-2', 6'), 7.56(3H, m, H-3', 4', 5'), 6.92(1H, s, H-3), 6.61(1H, s, H-8).
[0065] 13C-NMR (dmso-d6): 182.1 (C-4), 162.8 (C-2), 153.6 (C-7), 149.8 (C-9), 147.0 (C-5), 131.7 ( C-4'), 131.0(C-1'), 129.3(C-6), 129.0(C-2', 6'), 126.2(C-3', 5'), 104.4(C-3), 104.2 (C-10), 94.0 (C-8).
[0066] These data are consistent with the baicalein data reported in the literature (isolation and identification of the chemical constituents of Scutellaria baica...
Embodiment 2
[0074] Diacetylated baicalein oral solution:
[0075] Dissolve 5000mg of diacetylated baicalein in 1000ml of water to make a 0.5% aqueous solution, adjust the pH to 6-6.5, heat to dissolve, mix well, put it into a 20ml medicine bottle, seal and sterilize.
[0076] Dosage: Take orally, take diacetylated baicalein 100-300mg daily.
Embodiment 3
[0078] Diacetylated Baicalein Injection:
[0079] Take 2000 mg of diacetylated baicalein, dissolve it in 1000 ml of water to make an aqueous solution, adjust the pH to 6-6.5, heat to dissolve, mix evenly, dispense into 20 mg / 10 ml / bottle injection, and steam for 30 minutes to sterilize.
[0080] Usage and dosage: intramuscular injection or intravenous injection, 50-100mg per day.
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