Chemical coloring method for copper alloys
A chemical coloring and copper alloy technology, applied in the direction of metal material coating process, can solve problems such as imperfection and trouble, and achieve uniform tooth color, strong color fastness, and good corrosion resistance.
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Embodiment 1
[0026] First of all, the surface of the copper alloy zipper to be colored is mechanically polished, refined and polished, and then the oil stain on the cloth tape and zipper is removed with degreasing powder. After cleaning, the oxide film layer on the surface is removed with dilute sulfuric acid to activate the surface. Clean it and put it into a mixed solution of 85% phosphoric acid: 20ml / L, selenous acid: 5g / L, ammonium persulfate: 5g / L, sodium hypophosphite: 12g / L to micro-etch the surface of the zipper The treatment time is more than 10 seconds, and then the ingredients are 85% phosphoric acid: 10ml / L, 98% sulfuric acid: 10ml / L selenous acid: 10g / L, ammonium persulfate: 30g / L, copper sulfate pentahydrate: 10g / L of chemical coloring solution for 5 seconds of coloring treatment.
Embodiment 2
[0028] Grind and polish the surface of the copper alloy zipper to be colored, use degreasing powder to remove the oil on the cloth tape and zipper, use dilute sulfuric acid to remove the oxide film on the surface, activate the surface, clean it and then put it into the ingredients For 85% phosphoric acid: 50ml / L, selenous acid: 10g / L, ammonium persulfate: 50g / L, sodium hypophosphite: 30g / L mixed solution carries out micro-etching treatment to the slide fastener surface, and the time is 10 For more than a second, then add chemical coloring with ingredients of 85% phosphoric acid: 8ml / L, 98% sulfuric acid: 7ml / L selenous acid: 6g / L, ammonium persulfate: 26g / L, copper sulfate pentahydrate: 7g / L The coloring process is carried out in the liquid for 5 seconds.
Embodiment 3
[0030] Grind and polish the surface of the copper alloy zipper to be colored, use degreasing powder to remove the oil stains on the cloth tape and zipper, use dilute sulfuric acid to remove the oxide film on the surface, activate the surface, clean it and put it away Into the mixed solution of 85% phosphoric acid: 30ml / L, selenous acid: 8g / L, ammonium persulfate: 28g / L, sodium hypophosphite: 20g / L to carry out micro-etching treatment on the surface of the zipper, and the time is 10 seconds Above, after making the surface of copper alloy form a light yellow zinc-rich film layer, take it out and clean it up, put in the composition of 85% phosphoric acid: 2ml / L, 98% sulfuric acid: 2ml / L, selenous acid: 0.5 / L, Ammonium persulfate: 20 g / L, copper sulfate pentahydrate: 5 g / L chemical coloring solution, coloring treatment was performed for 5 seconds.
[0031] After implementing the surface treatment and coloring processes of the above three embodiments, the zinc-rich film layer on th...
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