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Cuprous complex crystal material and preparation method thereof

A technology of complexes and cuprous cyanide, which is applied in the direction of copper organic compounds, luminescent materials, chemical instruments and methods, etc., can solve the problems of high cost and environmental harm

Inactive Publication Date: 2014-04-30
ANQING NORMAL UNIV
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Problems solved by technology

At present, the central metal atoms of these photofunctional complexes are mainly transition metals in the fifth and sixth periods, especially the transition metals of the eighth subgroup, osmium, iridium, and platinum. disadvantages such as high cost and high cost limit their further application

Method used

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  • Cuprous complex crystal material and preparation method thereof
  • Cuprous complex crystal material and preparation method thereof
  • Cuprous complex crystal material and preparation method thereof

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Embodiment 1

[0019] Example 1: 0.2mmol of CuCN, 0.1mmol of K 4 [Fe(CN) 6 ]·3H 2 O and 0.1 mmol of PymNH 2 The ligand is miscible in 12 mL of CH 3 OH and H 2 O (volume ratio = 1:2) mixed solvent, stirred at room temperature for 30 minutes, sealed into a 25mL stainless steel reaction kettle, kept at 160°C for 72 hours, and naturally cooled to room temperature to obtain yellow blocky crystals. Yield calculated based on CuCN was 75%.

[0020] The 2-aminopyrimidine ligand cuprous cyanide complex of the present invention is further characterized, and its process is as follows:

[0021] (1) Crystal structure determination of 2-aminopyrimidine ligand cuprous cyanide complex

[0022] The crystallographic X-ray diffraction data of 2-aminopyrimidine ligand cuprous cyanide complex were collected by Bruker Smart APEX II CCD single crystal diffractometer, using Mo-kα(λ=0.71073 ) target, measured at 296(2)K at room temperature, with ω- Diffraction data were collected by scanning, analyzed by th...

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Abstract

The invention relates to a cuprous cyanide complex of a 2-aminopyrimidine ligand and a preparation method of the cuprous cyanide complex. The cuprous cyanide complex has a chemical formula [Cu2(CN)2(PymNH2)]n, wherein PymNH2 is 2-aminopyrimidine. The cuprous cyanide complex is a novel three-dimensional framework cuprous complex containing the 2-aminopyrimidine ligand and is simple in synthetic method, easy to crystallize, high in synthetic yield and easily available in raw materials; a crystal material of the complex is high in thermal stability and good in green luminescent properties, and can serve as a green luminescent material to be further applied in the field of material chemistry.

Description

technical field [0001] The invention belongs to the technical field of functional complexes and molecular-based optical materials thereof, and particularly relates to a 2-aminopyrimidine ligand cuprous cyanide complex and a preparation method thereof. Background technique [0002] Functional complex optical materials generally have the characteristics of good thermal stability, high fluorescence efficiency and easy film formation, and are considered to be one of the research hotspots in the field of functional complexes and the most promising category in recent years. Luminescent material. Therefore, the research on the photophysical and photochemical properties of functional complexes has aroused great interest of scientists. At present, the central metal atoms of these photofunctional complexes are mainly transition metals in the fifth and sixth periods, especially the transition metals of the eighth subgroup, osmium, iridium, and platinum. Disadvantages such as high cos...

Claims

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Application Information

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IPC IPC(8): C07F1/08C09K11/06
Inventor 黄荣谊王钧伟张宇烽薛晨朱昌海
Owner ANQING NORMAL UNIV
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