Active energy ray curable resin composition and spacer for display element and/or color filter protective film using same

An active energy ray, curable resin technology, used in optical filters, optical elements, nonlinear optics, etc., can solve problems such as poor elastic recovery rate, and achieve the effects of excellent toughness, excellent developability, and high radiation sensitivity

Active Publication Date: 2019-06-28
NIPPON KAYAKU CO LTD
View PDF11 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The polymer component, which is the main component of the composition, is excellent in developability and flexibility, but has the problem of poor elastic recovery required as a photo-spacer

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Active energy ray curable resin composition and spacer for display element and/or color filter protective film using same
  • Active energy ray curable resin composition and spacer for display element and/or color filter protective film using same
  • Active energy ray curable resin composition and spacer for display element and/or color filter protective film using same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1-1～1-40

[0154] Examples 1-1 to 1-40: Preparation of reactive polycarboxylic acid compound (A)

[0155] NC-3000H (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 288 g / eq) and NC-2000 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 230 g) were added as epoxy resin (a) in the amount described in Table 1 / eq), XD-1000 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 254g / eq), EOCN-103S (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 200g / eq), EPPN-201 (Nippon Kayaku Co., Ltd. Manufactured by the company, epoxy equivalent 190g / eq), NER-1302 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 280g / eq), NER-7403 (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 292g / eq), EPPN -502H (manufactured by Nippon Kayaku Co., Ltd., epoxy equivalent 170g / eq), add acrylic acid (abbreviated as AA, Mw=72) as compound (b) in the amount described in Table 1, add in the amount described in Table 1 Dimethylol propionic acid (DMPA for short, Mw=134) ...

Synthetic example 1

[0179] 7 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 200 parts by mass of diethylene glycol methyl ethyl ether were charged into a flask equipped with a condenser tube and a stirrer. Next, 5 parts by mass of styrene, 16 parts by mass of methacrylic acid, 34 parts by mass of tetrahydrodicyclopentadienyl methacrylate, 40 parts by mass of glycidyl methacrylate, α-methylstyrene two 3 parts by mass of the polymer were replaced with nitrogen, and then 5 parts by mass of 1,3-butadiene was added, and stirring was started slowly. The temperature of the solution was raised to 70°C, and the temperature was maintained for 5 hours to obtain a polymer solution containing the copolymer [G-1]. The solid content concentration of the obtained polymer solution was 33.1%, and the weight average molecular weight of the polymer was 10,000.

[0180]

[0181] H-1: Fluorine-containing surfactant (Neos Co., Ltd., Futhergent FTX-218)

[0182] H-2: Silicone surfactant (Toray Dow Corni...

Embodiment 2-1

[0187] (B-1 ) 100 parts by mass, 10 parts by mass of (C-3) as a photopolymerization initiator (C), and adding PGMEA and DEGDM as an organic solvent to achieve the desired solid content concentration, mixed as a surfactant (H) ( H-1) 0.3 parts by mass were filtered through a membrane filter with a pore diameter of 0.2 μm to prepare the composition (S-1). In addition, the numerical value of the organic solvent in Table 2 is the mass ratio of PGMEA and DEGDM.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
viscosityaaaaaaaaaa
epoxy equivalentaaaaaaaaaa
epoxy equivalentaaaaaaaaaa
Login to view more

Abstract

The present invention relates to an active energy ray-curable resin composition and a spacer for a display element and / or a color filter protective film using the composition. An object of the present invention is to provide a spacer for a display element and a color filter protective film excellent in heat-resistant transparency, flatness, flexibility, and toughness. Active energy ray-curable resin composition for a spacer for a display element or a protective film for a color filter, containing a reactive polyvalent carboxylic acid compound (A) and a reactive compound other than the reactive polycarboxylic acid compound (A) (B), a photopolymerization initiator (C) and an organic solvent (D), the reactive polycarboxylic acid compound (A) is an epoxy resin (a) having at least two or more epoxy groups in one molecule and a molecule Reaction product of compound (b) having more than one polymerizable ethylenically unsaturated group and more than one carboxyl group and compound (c) having at least two or more hydroxyl groups and more than one carboxyl group in one molecule and polybasic acid anhydride (d) Reactive polyhydric carboxylic acid compound (A) obtained by further reaction.

Description

technical field [0001] The present invention relates to an active energy ray-curable resin composition, a spacer for a display element, and / or a color filter protective film. Background technique [0002] As a material for a display device, a resin composition containing a binder polymer, a photopolymerizable monomer, a photopolymerization initiator, and the like has been used. In recent years, as materials for display devices (LCD, EL, PDP, FED (SED), rear projection displays, electronic paper or digital cameras, etc., especially display elements, display element peripheral materials), such as color liquid crystal display Devices (LCDs) are rapidly gaining popularity. Generally speaking, the structure of a color liquid crystal display device is: a color filter is opposed to an electrode substrate such as a TFT substrate and a gap of about 1 to about 10 μm is provided, a liquid crystal compound is filled in the gap, and the surrounding area is sealed. The material is seale...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): G03F7/027G02F1/1339G02B1/10
CPCC08F2/46C08F220/06C08F220/18C08F220/32C08F222/04C08F222/1006C08G59/14C08F220/281C08F220/325C08F220/343G02B5/20G02F1/0107
Inventor 小木聪小渊香津美堀口尚文山本和义
Owner NIPPON KAYAKU CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap