Preparation method and application of bimetallic photocatalytic functional POM/MOFs

A metal catalyzed light and functional technology, applied in the field of photocatalytic materials, which can solve the problems of large amount of substrate, low catalytic yield, and unrecyclable catalyst.

Active Publication Date: 2015-02-04
DALIAN UNIV OF TECH
View PDF2 Cites 39 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows creation of new types of molecules called Bimodals that have specific properties like pores size, shape, surface area, etc., which can be used to improve chemical reactions such as selective oxidation processes (SOR). These Bimods also allow for more precise control over their structures during production process compared to existing methods.

Problems solved by technology

This patents describes various methods for preparing special types of carboxylated pyridazole/ferrocanoimides called phthorods, which exhibits excellent characteristics like optically excited electronics, magnetic sensitivity, hydrothermal conductance, and reversible electrochromicity. These techniques allow us to efficiently attach these carriages onto surfaces while maintaining stability during operation.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method and application of bimetallic photocatalytic functional POM/MOFs
  • Preparation method and application of bimetallic photocatalytic functional POM/MOFs
  • Preparation method and application of bimetallic photocatalytic functional POM/MOFs

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Will K 5 [SiW 11 o 39 Ru(H 2 O)]·10H 2 O (70.0mg, 0.02mmol), Cu(NO 3 ) 2 ·3H 2 O (30.4mg, 0.12mmol) and 4,4′-bipyridine (19.3mg, 0.12mmol) were dissolved in a mixed solution of water (5.0mL) and acetonitrile (3.0mL), and mixed with 1mol·L –1 HAc adjusted the pH value of the solution to 4.4. After stirring for 12 hours, the above mixed solution was placed in an oven at 120°C. After reacting for 80 hours, it was cooled to room temperature, and brown-black columnar crystals were produced. After washing and drying, the target material POM / MOFs was obtained. (Catalyst Cu-BPY1), the yield is about 52%.

Embodiment 2

[0036] Will K 5 [SiW 11 o 39 Ru(H 2 O)]·10H 2 O (70.0mg, 0.02mmol) and Cu(NO 3 ) 2 ·3H 2 O (9.1 mg, 0.04 mmol) was dissolved in water (5.0 mL) to obtain a lower layer solution, 4,4′-bipyridine (12.5 mg, 0.08 mmol) was dissolved in acetonitrile (5.0 mL) to obtain an upper layer solution, and the middle layer was The mixed solution of acetonitrile and water (1:1, 10.0mL) was slowly added to the test tube (20mL) by layered diffusion method. , brown-black massive crystals were produced, washed and dried to obtain the target material POM / MOFs (catalyst Cu–BPY2), with a yield of about 59%.

Embodiment 3

[0038] Will K 5 [SiW 11 o 39 Ru(H 2 O)]·10H 2 O (70.0mg, 0.02mmol) and CoCl 2 ·6H 2 O (9.5 mg, 0.04 mmol) was dissolved in water (5.0 mL) to obtain a lower layer solution, 4,4′-bipyridine (12.5 mg, 0.08 mmol) was dissolved in acetonitrile (5.0 mL) to obtain an upper layer solution, and the middle layer was The mixed solution of acetonitrile and water (1:1, 10.0mL) was slowly added to the test tube (20mL) by layered diffusion method. , brown-black massive crystals were produced, washed and dried to obtain the target material POM / MOFs (catalyst Co-BPY1), with a yield of about 53%.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the technical field of photocatalytic materials, and relates to a preparation method and an application of bimetallic photocatalytic functional POM/MOFs. Bimetallic photocatalytic functional POM/MOF target materials with a porous structure are prepared through a hydrothermal synthesis technology or a layered diffusion technology with polyoxometalate POM as a functional group, L as a connection ligand and Cu<2+>, Co<2+> or Fe<2+> in a transition metal salt Tm as nodes, and the target materials POM/MOFs are applied in a functional photocatalytic carbon- carbon coupling reaction. The preparation method has the advantages of simple synthetic steps, easy operation, low energy consumption and high yield, and the obtained functional materials have the advantages of stable chemical properties, and easy large-area popularization and application. The MOF photocatalytic materials have a large specific surface area, have a very good conversion rate and reusability under the irritation of a 18W energy saving lamp when the use amount is 6/1000 of the amount of a substrate, and are suitable for the needs of large-scale industrial production.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Owner DALIAN UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap