Cellulose fiber cationic modification method
A technology of cationic modification and cellulose fiber, which is applied in the treatment of cellulose fiber and the field of cationic modification of cellulose fiber. It can solve the problems of difficult wastewater treatment, large amount of alkali consumption, pollution, etc., and achieve low cost and high reaction rate. full effect
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Embodiment 1
[0060] Modification process of cellulose fiber:
[0061] Put the cellulose fiber into the container, add water to the container, and then modify the cellulose fiber with two cationic modifiers, the small molecule quaternary ammonium salt cationic modifier and the high molecular quaternary ammonium salt cationic modifier , modified cellulose fibers are obtained after the modification treatment is completed; the small molecule quaternary ammonium salt cationic modifier is the epichlorohydrin parent derivative of the epoxy quaternary ammonium salt, and the high molecular quaternary ammonium salt cationic modified The agent is cationic starch.
[0062] The above-mentioned process is the cellulose fiber modification process of the present invention, and when the pH value is 6.5-8.5, the modified cellulose fiber with a Zeta electrode potential value of 0-15mV is obtained. Due to the small molecular weight of the small molecular quaternary ammonium salt cationic modifier, it can not...
Embodiment 2
[0064] Modification process of cellulose fiber:
[0065] Put the cellulose fiber into the container, add water to the container, and then modify the cellulose fiber with two cationic modifiers, the small molecule quaternary ammonium salt cationic modifier and the high molecular quaternary ammonium salt cationic modifier , modified cellulose fibers are obtained after the modification treatment is completed; the small molecule quaternary ammonium salt cationic modifier is the epichlorohydrin parent derivative of the epoxy quaternary ammonium salt, and the high molecular quaternary ammonium salt cationic modified The agent is cationic starch.
[0066] The cellulose fibers are selected from viscose filaments, viscose staple fibers, modal, tencel, cotton fibers, yarns and fabrics made from the aforementioned cellulose fibers.
[0067] The modification process of the present invention is applicable to all kinds of cellulose fibers, and also includes twisted yarns (hank form or chee...
Embodiment 3
[0069] Small molecule quaternary ammonium salt cationic modifier of the present invention is the epichlorohydrin parent derivative of epoxy quaternary ammonium salt;
[0070] The polymer quaternary ammonium salt cationic modifier of the present invention is cationic starch.
[0071] Epichlorohydrin parent derivatives of epoxy quaternary ammonium salts:
[0072]
[0073] Cationic starch:
[0074]
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