A kind of fullerene complex and its application in scavenging free radicals in flue gas
A technology of fullerene complexes and free radicals, applied in the direction of alkali metal compounds, other chemical processes, alkali metal oxides/hydroxides, etc., to achieve optimal results
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[0042]Dissolve 0.40g of zinc nitrate hexahydrate and 40.0mg of 1,3,5-(tricarboxyphenyl)benzene in 10mL of N,N-diethylformamide (sonicate the sample for about half an hour, and shake it during the sonication process) The sample was dissolved 2-3 times to promote its dissolution), the solution was reacted in the reactor for 3500min, and the reaction temperature was set at 85°C. After the reaction, the solvent was removed from the obtained solid, and washed 2 to 3 times with toluene solvent. After standing for a period of time, continue to rinse with toluene solvent for 2 to 3 times, and repeat this several times to replace all the solvent in the solid pores with toluene. Take the solid, air dry it, and take an optical photo such as figure 1 As shown, this is MOF-177.
[0043] Weigh 200 mg of air-dried MOF-177 in 30 mL C 60 Toluene solution (concentration is 1.0×10 -3 mol / L) to make it fully adsorb C 60 . As the immersion time prolongs, the color of the solution gradually b...
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