Provided are a method of efficiently procuding
fullerene into which a OH group or a SO3H group is introduced, such as fullerenol, or a derivative thereof, the
fullerene and its derivative being preferable as a
proton conductor, and a novel and
usable proton conductor obtained by the method. Further, provided is an electrochemical device using the
proton conductor such as a fuel
cell or the like. In the producing method of the
fullerene derivative, halogated fullerene, which is obtained through halogating a
fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one
carbon atom of a
fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of
fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of
fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a
proton conductor, and an electrochemical device using the
proton conductor such as a fuel
cell can be downsized and simplified without
atmosphere constraints.