Halogen-free flame-retardant resin and preparation method thereof

A flame retardant resin and epoxy resin technology, applied in the field of halogen-free flame retardant resin and its preparation, can solve the problems of precipitation of flame retardants, poor mechanical properties of products, easy water absorption on the surface, etc. Good barrier properties, mechanical properties and anti-aging properties

Inactive Publication Date: 2018-04-03
SHENZHEN POLYTECHNIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the large amount of flame retardant, it is difficult to compound plastics, and the mechanical properties of the obtained products are poor
Due to the large amount of flame retardant used, the stability of the resulting plastic product is poor, the flame retardant is precipitated, and the surface is easy to absorb water
Conventional halogenated flame retardants and phosphorus flame retardants are prone to produce more smoke and other toxic gases when they are flame retardant

Method used

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  • Halogen-free flame-retardant resin and preparation method thereof
  • Halogen-free flame-retardant resin and preparation method thereof
  • Halogen-free flame-retardant resin and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of halogen-free flame-retardant resin, the weight percentage content of nylon 66 is 72.5%, the weight percentage content of glass flakes is 15%, the weight percentage content of POE toughening agent is 5%, and the weight percentage content of POE-g-MAH compatibilizer is The content is 5%, the weight percentage content of epoxy resin TDE-85 is 1%, the weight percentage content of coupling agent is 0.5%, the weight percentage content of antioxidant is 0.5%, and the weight percentage content of lubricant EBS is 0.5% %.

[0033] First dilute the coupling agent and epoxy resin with solvent acetone, the amount of solvent is 10 times of the amount of coupling agent and epoxy resin. Then the glass flakes and the diluted mixed solution are stirred evenly in a high-speed mixer to allow the solvent to evaporate. Then, the compatibilizer, the toughening agent, and the treated glass flakes are uniformly mixed in a double-roll mill, and then formed into granules for later use...

Embodiment 2

[0036] A kind of halogen-free flame-retardant resin, the weight percentage content of nylon 66 is 62.5%, the weight percentage content of glass flakes is 25%, the weight percentage content of POE toughening agent is 5%, the weight percentage content of POE-g-MAH compatibilizer The content is 5%, the weight percentage content of epoxy resin TDE-85 is 1%, the weight percentage content of coupling agent is 0.5%, the weight percentage content of antioxidant is 0.5%, and the weight percentage content of lubricant EBS is 0.5% %.

[0037] First dilute the coupling agent and epoxy resin with solvent acetone, the amount of solvent is 10 times of the amount of coupling agent and epoxy resin. Then the glass flakes and the diluted mixed solution are stirred evenly in a high-speed mixer to allow the solvent to evaporate. Then, the compatibilizer, the toughening agent, and the treated glass flakes are uniformly mixed in a double-roll mill, and then formed into granules for later use. The ...

Embodiment 3

[0040] A kind of halogen-free flame-retardant resin, the weight percentage content of nylon 66 is 52.5%, the weight percentage content of glass flakes is 35%, the weight percentage content of POE toughening agent is 5%, the weight percentage content of POE-g-MAH compatibilizer The content is 5%, the weight percentage content of epoxy resin TDE-85 is 1%, the weight percentage content of coupling agent is 0.5%, the weight percentage content of antioxidant is 0.5%, and the weight percentage content of lubricant EBS is 0.5% %.

[0041] First dilute the coupling agent and epoxy resin with solvent acetone, the amount of solvent is 10 times of the amount of coupling agent and epoxy resin. Then the glass flakes and the diluted mixed solution are stirred evenly in a high-speed mixer to allow the solvent to evaporate. Then, the compatibilizer, the toughening agent, and the treated glass flakes are uniformly mixed in a double-roll mill, and then formed into granules for later use. The ...

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Abstract

The invention provides a halogen-free flame-retardant resin and a preparation method thereof. The halogen-free flame-retardant resin comprises the following components in percentage by weight: 50-80%of a thermoplastic substrate resin, 15-35% of glass flakes, 5-10% of a thickening agent, 5-10% of a compatilizer, 0.5-5% of an epoxy resin, 0.2-1% of a coupling agent, 0.2-1% of an antioxidant and 0.2-1% of a lubricant. According to the technical scheme of the invention, the glass flakes in plastic form a labyrinth structure, a plastic material is filled with the glass flakes, very good flame retardancy is achieved, very good barrier properties and mechanical properties can be achieved, the halogen-free flame-retardant resin is applied to barrier packaging materials or containers, and high requirements of automobile plastic fuel tank materials on strength, flame retardancy and gas barrier properties are met.

Description

technical field [0001] The invention belongs to the field of halogen-free flame-retardant polymers, and in particular relates to a halogen-free flame-retardant resin and a preparation method thereof. Background technique [0002] During the development of nearly a hundred years, plastics and plastic products have brought great contributions and infinite convenience to human production and life. However, since most plastics are flammable products, the production of plastic parts with flame-retardant requirements is subject to limit. In order to meet the requirements of flame retardancy, the current domestic market mainly uses flame retardants compounded with halogen-containing organic compounds and antimony trioxide to produce flame-retardant plastics. In recent years, brominated flame retardants have been plagued by the problem of dioxins. At the same time, the polymer materials used for flame retardancy (bromine-antimony system) will generate a large amount of smoke and co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L23/08C08L51/06C08L63/00C08L67/02C08L69/00C08K9/06C08K9/04C08K7/00C08K3/40C08K5/20
CPCC08L77/06C08L67/02C08L69/00C08L2201/02C08L2201/08C08L2201/14C08L2201/22C08L2205/035C08L23/0815C08L51/06C08L63/00C08K9/06C08K9/04C08K9/08C08K7/00C08K3/40C08K5/20
Inventor 罗超云左建东林峰徐志娟
Owner SHENZHEN POLYTECHNIC
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