Reference electrode-free GaN-based pH sensor based on groove structure and manufacturing method thereof

A reference electrode and pH sensor technology, which is applied in the field of GaN-based pH sensor without reference electrode and its preparation, can solve the problems of oxide/aluminum gallium nitrogen interface defects, surface contamination, transfer curve hysteresis, etc., and achieve improvement Long-term reliability, solving slow response speed, and improving detection sensitivity

Active Publication Date: 2019-03-29
SUN YAT SEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] (2) Materials that are sensitive to pH changes are generally amphoteric metal oxides, and heterogeneous epitaxy needs to be carried out by physical or chemical vapor deposition. During the preparation process, it is very easy to introdu

Method used

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  • Reference electrode-free GaN-based pH sensor based on groove structure and manufacturing method thereof
  • Reference electrode-free GaN-based pH sensor based on groove structure and manufacturing method thereof
  • Reference electrode-free GaN-based pH sensor based on groove structure and manufacturing method thereof

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Embodiment 1

[0043] Such as Figure 7 As shown, a GaN-based pH sensor based on a groove structure without a reference electrode, its structure includes a substrate 1 from bottom to top; a stress buffer layer 2; a GaN epitaxial layer 3; a thin AlGaN barrier layer with low aluminum composition 4; AlN insertion layer 5; secondary growth AlGaN thin barrier layer with high aluminum composition 6: grooves are formed in the middle of thin AlGaN barrier layer 6 with high aluminum composition; high-sensitivity detection material 7: deposited and filled with high aluminum composition In the groove of the AlGaN thin barrier layer 6 ; ohmic contact electrode 8 : ohmic electrodes are formed at both ends of the high-sensitivity detection material 7 ; packaging material 9 .

[0044] Wherein, the substrate 1 is any one of Si substrate 1, sapphire substrate 1, silicon carbide substrate 1, and GaN self-supporting substrate 1; the stress buffer layer 2 is AlN, AlGaN, GaN Any one or a combination of; the thi...

Embodiment 2

[0055] The structural diagram of embodiment 2 is similar to that of embodiment 1, except that the groove structure is not obtained by selective area growth, but by dry or wet etching.

[0056] In addition, it should be noted that the drawings of the above embodiments are only for illustrative purposes, and thus are not necessarily drawn to scale.

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Abstract

The invention relates to the technical field of semiconductor pH sensors, and relates to a reference electrode-free GaN-based pH sensor based on a groove structure and a manufacturing method thereof.The method comprises the following steps: a thin-layer low-Al component AlGaN barrier layer and an AlN insertion layer firstly grow on a GaN epitaxial material, a layer of dielectric layer is deposited on the surface of the material as a mask layer, a photoetching developing technology and wet etching are adopted to remove the dielectric layer outside a detection area, patterning of the mask layeris realized, a high-Al component AlGaN thin barrier layer further grows on a mask-free area to form a groove structure, a detection material sensitive to pH changes is deposited in the groove area, an ohmic contact electrode is manufactured, and an area outside the groove is finally packaged to form a sensing device. The process is simple, while the thin-layer low-Al component AlGaN in the groovearea keeps a two-dimensional electronic airway, the transconductance of the device is effectively enhanced, the high-Al component AlGaN in an access area can form a high-concentration two-dimensionalelectronic device to reduce the sensor loss and enhance the sensor reaction speed.

Description

technical field [0001] The invention relates to the technical field of semiconductor pH sensors, in particular to a GaN-based pH sensor without a reference electrode based on a groove structure and a preparation method thereof. Background technique [0002] The pH sensor is an essential inspection device for measuring the pH of liquid media, precise monitoring and scientific certification. It has important applications in the fields of environmental, medical, industrial, agricultural and biological solutions. With the continuous development of science and technology, the all-solid-state pH sensor based on Ion Sensitive Field Effect Transistor (ISFET: Ion Sensitive Field Effect Transistor) has been favored for its small size, non-fragile, high sensitivity, stable performance, and portability. favor. At present, Si-based MOSFET has become the main material for the preparation of ISFET pH sensors due to its low price, mass production compatibility with traditional CMOS process...

Claims

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Application Information

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IPC IPC(8): G01N27/30
CPCG01N27/30
Inventor 李柳暗丘秋凌刘扬
Owner SUN YAT SEN UNIV
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