Electrode and electricity storage element
A technology for storage components and electrodes, applied in the direction of electrical components, positive electrodes, electrode carriers/collectors, etc.
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Embodiment 1
[0103] [Example 1] (production of positive electrode)
[0104] On the surface of an aluminum foil (average thickness: 15 μm) serving as a positive electrode base material, an intermediate layer was formed in the following manner. Weigh acetylene black (AB) and alumina (manufactured by Sumitomo Chemical Co., Ltd., with a particle size of about 300 nm and a BET specific surface area of 4.9 m) at a mass ratio of 8:77:15. 2 / g) and polyvinylidene fluoride (PVDF). These were mixed to N-methyl-2-pyrrolidone (NMP) as a dispersion medium to prepare a paste for intermediate layer formation. The paste for forming an intermediate layer was applied to an aluminum foil. Thereafter, drying was performed to obtain an intermediate layer having an average thickness of 8 μm.
[0105] Prepare Li(Ni 0.82 co 0.15 Al 0.03 )O 2 , AB, and PVDF, and a positive electrode active material layer-forming paste using N-methyl-2-pyrrolidone as a dispersion medium. The positive electrode active mate...
Embodiment 2
[0107] Weigh acetylene black (AB) and aluminum oxide (manufactured by AEROSIL Japan, with a particle size of about 70 nm and a BET specific surface area of 94 m) with a mass ratio of 8:62:30. 2 / g) and polyvinylidene fluoride (PVDF), they were mixed into N-methyl-2-pyrrolidone (NMP) as a dispersion medium to prepare a paste for intermediate layer formation, except that it was the same as in Example 1 Operation, obtain the positive pole of embodiment 2.
Embodiment 3
[0109] Acetylene black (AB), aluminum oxide (manufactured by Japan Aerosil Co.), a reaction product of bismaleimide and barbituric acid as a heat-crosslinkable compound were weighed at a mass ratio of 8:55:20:15, and polyvinylidene fluoride (PVDF), they were mixed into N-methyl-2-pyrrolidone (NMP) as a dispersion medium to prepare a paste for forming an intermediate layer, except that, the same operation as in Example 1 was obtained to obtain The positive electrode of Example 3.
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