Preparation method of poly-L-lactic acid microspheres
A technology of L-polylactic acid and polylactic acid solution is applied in the field of medical cosmetic materials, which can solve the problems of high cost, environment and harm, and achieve the effects of improving safety, short reconstitution time and uniform appearance.
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Embodiment 1
[0027] Example 1 Dissolve L-polylactic acid in dichloromethane to prepare a polylactic acid solution with a concentration of 0.5 g / L, and place it in a solution holding tank. Adjust the condenser and preheater to the specified temperature of 30°C. Liquid CO 2 Pressed into the high-pressure granulation kettle by the high-pressure pump, after reaching the predetermined pressure of 14MPa, adjust the valve to keep the granulation kettle and the separation kettle in a dynamic balance at a specific temperature and pressure; into the autoclave, the solution and supercritical CO 2 High-speed mixing so that the solution is crushed into very fine droplets, droplets and CO 2 The rapid transfer between them makes the solute in the system supersaturated, and the polylactic acid microspheres are precipitated and precipitated; after the reaction is completed, the pressure in the autoclave is reduced to normal pressure, and the product is centrifugally washed with ultrapure water at a speed...
Embodiment 2
[0028] Example 2 Dissolve L-polylactic acid in methylene chloride to form a polylactic acid solution with a concentration of 0.5 g / L, and place it in a solution holding tank. Adjust the condenser and preheater to the specified temperature of 75°C. Liquid CO 2 Pressed into the high-pressure granulation kettle by the high-pressure pump, after reaching the predetermined pressure of 14MPa, adjust the valve to keep the granulation kettle and the separation kettle in a dynamic balance at a specific temperature and pressure; into the autoclave, the solution and supercritical CO 2 High-speed mixing so that the solution is crushed into very fine droplets, droplets and CO 2 The rapid transfer between them makes the solute in the system supersaturated, and the polylactic acid microspheres are precipitated and precipitated; after the reaction is completed, the pressure in the autoclave is reduced to normal pressure, and the product is centrifugally washed with ultrapure water at a speed...
Embodiment 3
[0029] Example 3 Dissolve L-polylactic acid in methylene chloride to form a polylactic acid solution with a concentration of 50 g / L, and place it in a solution holding tank. Adjust the condenser and preheater to the specified temperature of 30°C. Liquid CO 2 Pressed into the high-pressure granulation kettle by the high-pressure pump, after reaching the predetermined pressure of 14MPa, adjust the valve to keep the granulation kettle and the separation kettle in a dynamic balance at a specific temperature and pressure; into the autoclave, the solution and supercritical CO 2 High-speed mixing so that the solution is crushed into very fine droplets, droplets and CO 2The rapid transfer between them makes the solute in the system supersaturated, and the polylactic acid microspheres are precipitated and precipitated; after the reaction is completed, the pressure in the autoclave is reduced to normal pressure, and the product is centrifugally washed with ultrapure water at a speed o...
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