Activated carbon modification method for removing nitric oxide and nitrogen dioxide in air

A technology of nitric oxide and nitrogen dioxide, applied in the application field of activated carbon in air purification, can solve the problems of decreased hydrophobic capacity of activated carbon, pollution of customer site environment, increase of water content of activated carbon, etc., to improve adsorption effect, increase removal efficiency, The effect of guaranteeing the adsorption efficiency

Pending Publication Date: 2021-12-10
MAYAIR TECH (CHINA) CO LTD
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Problems solved by technology

[0005] 1. The existing columnar activated carbon activated by conventional water vapor or KOH is mainly physical adsorption, and its adsorption capacity for nitrogen dioxide and nitrogen monoxide is low;
[0006] 2. Existing modification methods for NOx-removing activated carbon mostly adopt the method of loading potassium hydroxide or potassium carbonate for modification. The precipitation of loads on the surface of activated carbon will block the pores of activated carbon and seriously affect the adsorption capacity of activated carbon for gaseous small molecules, resulting in The removal efficiency of nitric oxide gas is significantly reduced, which is not conducive to the comprehensive adsorption eff

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  • Activated carbon modification method for removing nitric oxide and nitrogen dioxide in air

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[0032] In order to make a further understanding of the purposes of the present invention, it is described in detail with reference to the apparatus.

[0033] Please refer to figure 1 , An embodiment of the present invention provides a method of modifying activated carbon monoxide and nitrogen dioxide in the air a gas removal, comprising the steps of:

[0034] S1: preparing activated carbon, steam activation or selection of the activated potassium coconut / columnar activated carbon coal; further, a specific surface area of ​​activated carbon is greater than 800m2 / g, a total pore volume greater than 0.5 cm3 / g, mesopore volume greater than 0.2 cm3 / g of the activated carbon column; by selection of such activated carbon, activated carbon having a micropore structure rich while facilitating a supported catalyst;

[0035] S2: clear channel activated carbon, using an excess of 3-8% concentration of hydrochloric acid solution prepared in the washing step S1 of activated carbon to re...

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Abstract

The invention provides an activated carbon modification method for removing nitric oxide and nitrogen dioxide in air. The method comprises the following steps: preparing activated carbon, dredging pores of the activated carbon, loading a catalyst on the surface of the activated carbon, preparing a dipping modification solution, preparing an ammonia water solution, controlling the heating temperature of an activation furnace, modifying the activated carbon, discharging redundant ammonia gas and carrying out cooling. According to the method, active carbon surface functional group modification and supported vanadium oxide (V2O5) combined modification are adopted, so the removal efficiency and the adsorption capacity of nitrogen oxides are improved, the problem of hole blockage caused by metal salt/alkali dipping precipitation is avoided, the problem of environment pollution caused by dipping substance falling is prevented, and meanwhile, the hydrophobicity of the active carbon is improved.

Description

technical field [0001] The invention relates to the application field of activated carbon in air purification, in particular to an activated carbon modification method for removing nitrogen monoxide and nitrogen dioxide in air. Background technique [0002] Activated carbon is a kind of highly adsorbable granular substance with porous and high specific surface area, which has a strong adsorption effect on gas molecular substances and small molecular substances in liquid solution; during the gas adsorption process of activated carbon, gas molecules can pass through The microporous structure of activated carbon, some gas molecules are attached to the active site of activated carbon and stay on the active site; the active site of activated carbon will lose its adsorption capacity after being occupied by gas molecules; the binding ability of each gas molecule to the active site of activated carbon Different, according to the different molecular binding ability, the separation of...

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Application Information

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IPC IPC(8): B01D53/02B01D53/86B01D53/56B01J20/20B01J20/28B01J20/30
CPCB01D53/02B01D53/8628B01J20/20B01J20/28011B01D2255/20723Y02A50/20
Inventor 王哲朱蕾冯伟豪陈玲叶伟强
Owner MAYAIR TECH (CHINA) CO LTD
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