Graphene aluminum composite conductive coating and preparation method thereof
A graphene composite, conductive coating technology, applied in conductive coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problem that conductive coatings cannot have both, and achieve improved material performance, easy to prepare raw materials, excellent performance effect
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[0035] The present invention provides the preparation method of described graphene-aluminum composite conductive coating on the other hand, comprises the steps:
[0036] S01: Preparation of modified graphene composite aluminum powder: heat treatment of modified graphene and aluminum powder, and then heat treatment in air atmosphere;
[0037] S02: Disperse the modified graphene composite aluminum powder, resin, catalyst, and crosslinking agent in an organic solvent, and react for 1 hour under vigorous stirring.
[0038] Specifically in the step S01, the preparation method of the modified graphene is: react potassium permanganate in an ice bath for 0.5-1 hour, react potassium permanganate at 10°C for 0.5-2 hours, and react with hydrogen peroxide for 1-2 hours . In this method, the graphene oxide is first activated, and then reacted to generate a modified hydroxyl group, and finally the reaction is quenched with hydrogen peroxide and washed to a certain extent with the generated...
Embodiment 1
[0045] Preparation of hydroxyl-rich graphene: 2.4 parts of potassium permanganate was reacted in ice bath for 0.5-1 hour, 1.2 parts of potassium permanganate was reacted at 10°C for 0.5-2 hours, and 1.2 parts of hydrogen peroxide was reacted for 1-2 hours.
[0046] Preparation of graphene-aluminum composite powder: 1 part of the obtained hydroxyl-rich graphene and 99 parts of aluminum powder were treated at 300° C. under a pressure of 400 MPa for 2 hours. Then, heat treatment was carried out at 400° C. for 1 hour in an air atmosphere.
[0047] Proportion: 50 parts of epoxy resin, 10 parts of graphene-aluminum composite material powder including 1% hydroxyl-rich graphene and 99% pure aluminum, DMF as solvent, 8 parts of DTA as crosslinking agent, 1.5 parts of catalyst;
[0048] The preparation method is vigorous stirring at 60°C for one hour.
Embodiment 2
[0050] Preparation of hydroxyl-rich graphene: 2.4 parts of potassium permanganate was reacted in ice bath for 0.5-1 hour, 1.2 parts of potassium permanganate was reacted at 10°C for 0.5-2 hours, and 1.2 parts of hydrogen peroxide was reacted for 1-2 hours.
[0051] Preparation of graphene-aluminum composite powder: 1 part of the obtained hydroxyl-rich graphene and 99 parts of aluminum powder were treated at 300° C. under a pressure of 400 MPa for 2 hours. Then, heat treatment was carried out at 400° C. for 1 hour in an air atmosphere.
[0052] Ratio: 20 parts of polyurethane, 20 parts of silicone resin, 10 parts of graphene-aluminum composite material powder including 1% hydroxyl-rich graphene and 99% pure aluminum, NMP as solvent, 2 parts of BPO, DTBP, DBHP each Joint agent, 3 parts of catalyst;
[0053] The preparation method is vigorous stirring at 60°C for one hour.
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