Graphene aluminum composite conductive coating and preparation method thereof

A graphene composite, conductive coating technology, applied in conductive coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problem that conductive coatings cannot have both, and achieve improved material performance, easy to prepare raw materials, excellent performance effect

Pending Publication Date: 2022-05-13
广州盛门新材料科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The purpose of the present invention is to provide a graphene-aluminum composite conductive coating and its preparation method to solve the technical problem that existing conductive coatings cannot have good heat dissipation, electrical conductivity and mechanical strength

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  • Graphene aluminum composite conductive coating and preparation method thereof

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preparation example Construction

[0035] The present invention provides the preparation method of described graphene-aluminum composite conductive coating on the other hand, comprises the steps:

[0036] S01: Preparation of modified graphene composite aluminum powder: heat treatment of modified graphene and aluminum powder, and then heat treatment in air atmosphere;

[0037] S02: Disperse the modified graphene composite aluminum powder, resin, catalyst, and crosslinking agent in an organic solvent, and react for 1 hour under vigorous stirring.

[0038] Specifically in the step S01, the preparation method of the modified graphene is: react potassium permanganate in an ice bath for 0.5-1 hour, react potassium permanganate at 10°C for 0.5-2 hours, and react with hydrogen peroxide for 1-2 hours . In this method, the graphene oxide is first activated, and then reacted to generate a modified hydroxyl group, and finally the reaction is quenched with hydrogen peroxide and washed to a certain extent with the generated...

Embodiment 1

[0045] Preparation of hydroxyl-rich graphene: 2.4 parts of potassium permanganate was reacted in ice bath for 0.5-1 hour, 1.2 parts of potassium permanganate was reacted at 10°C for 0.5-2 hours, and 1.2 parts of hydrogen peroxide was reacted for 1-2 hours.

[0046] Preparation of graphene-aluminum composite powder: 1 part of the obtained hydroxyl-rich graphene and 99 parts of aluminum powder were treated at 300° C. under a pressure of 400 MPa for 2 hours. Then, heat treatment was carried out at 400° C. for 1 hour in an air atmosphere.

[0047] Proportion: 50 parts of epoxy resin, 10 parts of graphene-aluminum composite material powder including 1% hydroxyl-rich graphene and 99% pure aluminum, DMF as solvent, 8 parts of DTA as crosslinking agent, 1.5 parts of catalyst;

[0048] The preparation method is vigorous stirring at 60°C for one hour.

Embodiment 2

[0050] Preparation of hydroxyl-rich graphene: 2.4 parts of potassium permanganate was reacted in ice bath for 0.5-1 hour, 1.2 parts of potassium permanganate was reacted at 10°C for 0.5-2 hours, and 1.2 parts of hydrogen peroxide was reacted for 1-2 hours.

[0051] Preparation of graphene-aluminum composite powder: 1 part of the obtained hydroxyl-rich graphene and 99 parts of aluminum powder were treated at 300° C. under a pressure of 400 MPa for 2 hours. Then, heat treatment was carried out at 400° C. for 1 hour in an air atmosphere.

[0052] Ratio: 20 parts of polyurethane, 20 parts of silicone resin, 10 parts of graphene-aluminum composite material powder including 1% hydroxyl-rich graphene and 99% pure aluminum, NMP as solvent, 2 parts of BPO, DTBP, DBHP each Joint agent, 3 parts of catalyst;

[0053] The preparation method is vigorous stirring at 60°C for one hour.

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Abstract

The invention provides a graphene aluminum composite conductive coating. The graphene aluminum composite conductive coating is prepared from the following components in parts by mass through reaction: 30-60 parts of resin, 5-10 parts of modified graphene composite aluminum powder, 20-40 parts of an organic solvent, 1.5-3 parts of a catalyst and 10-20 parts of a cross-linking agent. The graphene-aluminum composite material is adopted as a conductive agent, firstly, aluminum has good conductivity and low density, after graphene is subjected to hot press molding, due to the fact that a small amount of interface layer of Al4C3 is formed, the performance of the material is improved, and due to the fact that the hot press temperature and time are controlled, no more Al4C3 is formed, and the performance of the material is lowered; the specific surface of the machine is selected from materials, and the electric conduction and heat dissipation performance is excellent. The overall mechanical strength is further improved through the viscosity of the resin and the cross-linking effect of the cross-linking agent, and the modified graphene is hydroxyl-rich graphene oxide and can be partially cross-linked with the resin to form an organic whole, so that the overall material performance is further improved, and finally, the conductive coating with good conductivity, high heat dissipation capability and high mechanical strength is obtained.

Description

technical field [0001] The invention belongs to the field of polymer coatings, in particular to a graphene-aluminum composite conductive coating and a preparation method thereof. Background technique [0002] Conductive coating is a special functional coating developed rapidly along with modern science and technology, with a development history of about half a century. In 1948, the United States published a patent for making conductive adhesive from silver and epoxy resin, which was the earliest disclosed conductive paint. my country also began to study and apply conductive coatings in the 1950s. In recent decades, conductive coatings have been applied in various military and civilian industrial fields such as electronics, electrical appliances, aviation, chemical industry, and printing. Correspondingly, the theoretical research on conductive coatings has also developed rapidly, and has promoted the increasingly mature and perfect application technology. Conductive paint ...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D175/04C09D183/04C09D5/24C09D7/63
CPCC09D163/00C09D175/04C09D183/04C09D5/24C09D7/63C08K2003/0812C08K2201/001C08K3/08C08K3/042C08K9/02C08K5/17C08K13/02C08L83/04C08K5/14C08L75/04
Inventor陈稳城蔡铭李俊
Owner广州盛门新材料科技有限公司