Three-D nano-porous film and its manufacturing method

Abstract

The invention relates to a 3D nano-porous film and the manufacturing method thereof. And the manufacturing method comprises: (a) providing a substrate, which has a precoating surface; (b) forming a film layer composed of 3D nano porous coating combination on the precoating surface; (c) supplying energy to the film layer to making polymerization reaction on the above combination so as to form organic-inorganic mixed layer on the precoating surface; and (d) dissolving out template from the mixed layer by second solvent to form the 3D nano porous film, which has effective refractive index below 1.45 and reflectivity not greater than 3%, and extremely good mechanical strength and rigidity, completely suitable to be used as antireflective and wearable coating for a display unit.

Description

technical field

[0001] The invention relates to a three-dimensional nanoporous film and a manufacturing method thereof, in particular to a three-dimensional nanoporous film with high mechanical strength and anti-reflection capability and a manufacturing method thereof. Background technique

[0002] In the manufacturing process of display devices (such as: optical lenses, cathode ray displays, plasma displays, liquid crystal displays, or light-emitting diode displays), in order to prevent the image from being disturbed by glare or reflected light, the outermost layer of the display device (such as a transparent substrate of a liquid crystal display) to configure an anti-reflection layer.

[0003] Anti-reflection optical films with a single-layer structure have gradually become the main research and development trend in anti-reflection technology due to their excellent processing convenience, high yield, high output and low equipment cost. However, known fluorine-containing i...

Examples

Embodiment 1

[0099] Oxygenate colloid A with polymerizable groups

[0100] Take a reaction bottle, put 3-(methacrylic acid group) propyl trimethoxy silane (3-methacrylicoxy-propyl trimethoxy silane), tetra-methoxy silane (tetra-methoxy silane, TMOS), hydrochloric acid (HCl ), deionized water (de-ionwater) and ethanol, after uniform mixing, reflux (reflux) at 60°C for 3 hours, wherein the 3-(methacryl)propyltrimethoxysilane, tetramethoxysilane, The molar ratio of hydrochloric acid, deionized water and ethanol is 0.25 / 0.75 / 0.1 / 4 / 15. After the reaction is complete, the oxygen-containing compound colloid A having a polymerizable group can be obtained.

Embodiment 2

[0102] Oxygenate colloid B with polymerizable groups

[0103] Take a reaction bottle, put Y-glycidoxypropyl-trimethoxysilane (Y-glycidoxypropyl-trimethoxysilane), tetra-ethoxysilane (tetra-ethoxy silane, TEOS), hydrochloric acid (HCl), deionized Water (de-ionwater) and ethanol, after uniform mixing, reflux (reflux) at 35°C for 1 hour, wherein the Y-glycidyl trimethoxysilane, tetraethoxysilane, hydrochloric acid, deionized water and The molar ratio of ethanol is 0.3:0.7:0.05:4:50. After the reaction is complete, the oxygen-containing compound colloid B (siloxane colloid) having a polymerizable group can be obtained.

Embodiment 3

[0105] Oxygenate colloid C with polymerizable groups

[0106] Take a reaction bottle, put vinyltriethoxysilane (vinyltriethoxysilane), tetraethoxysilane (tetra-ethoxy silane, TEOS), hydrochloric acid (HCl), deionized water (de-ion water) and ethanol in the bottle , after uniform mixing, reflux at 60°C for 3 hours, wherein the molar ratio of vinyltriethoxysilane, tetraethoxysilane, hydrochloric acid, deionized water and ethanol is 0.5:0.5:0.1:4: 60. After the reaction is complete, the oxygenate colloid C with polymerizable groups can be obtained.

technical field

[0001] The invention relates to a three-dimensional nanoporous film and a manufacturing method thereof, in particular to a three-dimensional nanoporous film with high mechanical strength and anti-reflection capability and a manufacturing method thereof. Background technique

[0002] In the manufacturing process of display devices (such as: optical lenses, cathode ray displays, plasma displays, liquid crystal displays, or light-emitting diode displays), in order to prevent the image from being disturbed by glare or reflected light, the outermost layer of the display device (such as a transparent substrate of a liquid crystal display) to configure an anti-reflection layer.

[0003] Anti-reflection optical films with a single-layer structure have gradually become the main research and development trend in anti-reflection technology due to their excellent processing convenience, high yield, high output and low equipment cost. However, known fluorine-containing i...

Examples

Embodiment 1

[0099] Oxygenate colloid A with polymerizable groups

[0100] Take a reaction bottle, put 3-(methacrylic acid group) propyl trimethoxy silane (3-methacrylicoxy-propyl trimethoxy silane), tetra-methoxy silane (tetra-methoxy silane, TMOS), hydrochloric acid (HCl ), deionized water (de-ionwater) and ethanol, after uniform mixing, reflux (reflux) at 60°C for 3 hours, wherein the 3-(methacryl)propyltrimethoxysilane, tetramethoxysilane, The molar ratio of hydrochloric acid, deionized water and ethanol is 0.25 / 0.75 / 0.1 / 4 / 15. After the reaction is complete, the oxygen-containing compound colloid A having a polymerizable group can be obtained.

Embodiment 2

[0102] Oxygenate colloid B with polymerizable groups

[0103] Take a reaction bottle, put Y-glycidoxypropyl-trimethoxysilane (Y-glycidoxypropyl-trimethoxysilane), tetra-ethoxysilane (tetra-ethoxy silane, TEOS), hydrochloric acid (HCl), deionized Water (de-ionwater) and ethanol, after uniform mixing, reflux (reflux) at 35°C for 1 hour, wherein the Y-glycidyl trimethoxysilane, tetraethoxysilane, hydrochloric acid, deionized water and The molar ratio of ethanol is 0.3:0.7:0.05:4:50. After the reaction is complete, the oxygen-containing compound colloid B (siloxane colloid) having a polymerizable group can be obtained.

Embodiment 3

[0105] Oxygenate colloid C with polymerizable groups

[0106] Take a reaction bottle, put vinyltriethoxysilane (vinyltriethoxysilane), tetraethoxysilane (tetra-ethoxy silane, TEOS), hydrochloric acid (HCl), deionized water (de-ion water) and ethanol in the bottle , after uniform mixing, reflux at 60°C for 3 hours, wherein the molar ratio of vinyltriethoxysilane, tetraethoxysilane, hydrochloric acid, deionized water and ethanol is 0.5:0.5:0.1:4: 60. After the reaction is complete, the oxygenate colloid C with polymerizable groups can be obtained.

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