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Microfiber articles from multi-layer substrates

a technology of microfiber articles and substrates, applied in the field of multi-layer films, can solve the problems of little if any recognition of the potential benefits and synergies that can be achieved, and achieve the effect of more efficient and economical

Inactive Publication Date: 2006-03-09
3M INNOVATIVE PROPERTIES CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0007] Advantageously, the different layers of the multi-layer film can be selected based on the independent properties of the different layers to produce a multi-layer microfiber article having a combination of desired properties. For example, different layers of a multi-layer film can be independently selected to provide one or more layers that are hydrophobic; hydrophilic; oleophobic; oleophilic; dielectric; to exhibit certain physical properties such as rigidity, flexibility, high or low elasticity, high or low strength, tear or puncture resistance, stain resistance, breathability, and being waterproof; to give a desired frictional property such as a high or low coefficient of friction; to provide a desired color or color combination; to provide a desired size of fibers, fibrils, or microfibers, or a desired surface area of a fiber or microfiber surface; to provide high or low temperature resistance or flame retardance; or a combination thereof.
[0010] In certain embodiments, the invention takes advantage of the understanding that films having multiple different layers with independently selected properties can be efficiently co-extruded to form a multi-layer film, which can then be microfibrillated to produce a microfiber article having a desired combination of properties based on the composition and properties of the different layers of the co-extruded film. The preparation of a multi-layer film by co-extruding can realize processing advantages because co-extruding different layers into a single film can be more efficient and economical than other possible (and still useful) methods of producing a multi-layer film, such as by separate production of individual layers and lamination or adhesion of those layers to one another.

Problems solved by technology

Until now, there has been little if any recognition of the potential benefits and synergies that can be achieved using multi-layer films, particularly co-extruded multi-layer films, to form microfibers, microfiber surfaces, and microfiber articles.

Method used

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  • Microfiber articles from multi-layer substrates

Examples

Experimental program
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Effect test

example 1

[0121] An “A-B-C” 3-layer cast film was prepared according to Process I using polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) for the A-layer melt stream, a tri-block copolymer with polystyrene end blocks and a rubbery poly(ethylene-butylene) mid block (Kraton G1657, available from Kraton Polymers, Houston Tex.) for the B-layer melt stream, and a polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) for the C-layer melt stream. The resulting 3-layer cast film had a thickness of 940 micrometer, a width of 241 mm, and a density of 0.9 gram / cm3.

[0122] The resulting cast film was calendered and length oriented according to Process II. The cast film was fed from an unwind station into the compressive nip of rolls 1 and 2 at a rate of 0.23 m / min. Rolls 1 and 2 each had surface speed of 0.91 m / min, a temperature of 120° C., and a gap between the rolls of 0.18 mm. Roll 3 had a surface speed of 2.97 m / min and a temperature of 120...

example 2

[0124] An “A-B-C” 3-layer cast film was prepared according to Process I using polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) for the A-layer melt stream, a blend of 80% polypropylene homopolymer (Fina 3271, available from ATOFINA Inc., Houston, Tex.) and 20% of an ethylene vinyl acetate copolymer (Elvax 670, available from DuPont Chemical Co., Wilmington, Del.) for the B-layer melt stream, and a polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) for the C-layer melt stream. The resulting cast film had a thickness of 880 micrometer, a width of 240 mm, and a density of 0.91 grams / cm3.

[0125] The resulting 3-layer cast film was calendered and length oriented according to Process II. The cast film was fed from an unwind station into the compressive nip of rolls 1 and 2 at a rate of 0.32 m / min. Rolls 1 and 2 each had surface speed of 0.91 m / min, a temperature of 100° C., and a gap between the rolls of 0.18 mm. Roll 3 had a...

example 3

[0127] An “A-B-C” 3-layer cast film was prepared according to Process I using a blend of 80% polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) and 20% of an ethylene vinyl acetate copolymer (Elvax 670, available from DuPont Chemical Co., Wilmington, Del.) for the A-layer melt stream, polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) for the B-layer melt stream, and a blend of 80% polypropylene homopolymer (Fina 3271, available from Atofina Inc., Houston, Tex.) and 20% of an ethylene vinyl acetate copolymer (Elvax 670, available from DuPont Chemical Co., Wilmington, Del.) for the C-layer melt stream. The resulting 3-layer cast film had a thickness of 920 micrometer, a width of 243 mm, and a density of 0.91 grams / cm3.

[0128] The resulting 3-layer cast film was calendered and length oriented according to Process II. The cast film was fed from an unwind station into the compressive nip of rolls 1 and 2 at a rate of 0.31 m / m...

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Abstract

Described are microfiber articles and methods and intermediates for their production, the microfiber articles being preferably produced from co-extruded multi-layer films, and the articles having a multi-layer construction that allows selection of the different layers to have different properties such that the article can have a desired combination of properties.

Description

[0001] This application is a divisional of U.S. Ser. No. 09 / 974040, filed Oct. 9, 2001, now allowed, the disclosure of which is herein incorporated by reference.FIELD OF THE INVENTION [0002] The invention relates to multi-layer films that bear a microfiber surface, films and methods used to prepare them, and articles made from them. BACKGROUND [0003] Polymeric materials that can be processed to form microfiber surfaces and microfiber articles have been identified, including mono-axially oriented films such as polypropylene. See U.S. Pat. No. 6,110,588. Such polymeric materials can be selected and processed using various techniques, to produce oriented films capable of being microfibrillated to a microfiber surface. [0004] Multi-layer films are generally known, and include a huge variety of different combinations of layer composition, sizes, and methods of preparing the different layers into a multi-layer film, e.g., lamination, co-extrusion, the use of adhesives, etc. [0005] Until n...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): H01B1/12C07D333/06C08G61/12H01L51/00H01L51/30
CPCB01D39/1623H01L51/0508B32B5/02B32B27/08B32B27/12B32B37/153B32B2262/0253B32B2307/306B32B2307/3065B32B2307/51B32B2307/724B32B2307/728B32B2307/73B82Y10/00B82Y30/00C07D333/06C08G61/126D04H1/465D04H13/005D04H13/02H01L51/0052H01L51/0054H01L51/0058H01L51/0068B01D2239/0663H10K85/622H10K85/626H10K85/655H10K85/615H10K10/46C07D409/14C07D409/10
Inventor KODY, ROBERT S.PEREZ, MARIO A.LONGABACH, JOHN W.KLEPZIG, KIMBERLEY D.SEBASTIAN, JOHN M.HOBBS, TERRY R.MICHEL, MATTHEW J.LINDQUIST, TIMOTHY J.SURA, RAVI K.
Owner 3M INNOVATIVE PROPERTIES CO
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