Semiconductor device including gate insulation film that is formed of pyroceramics, and method of manufacturing the same

a technology of pyroceramics and semiconductor devices, which is applied in the manufacture of semiconductor devices, nanostructures, electrical apparatus, etc., can solve the problems of increased so-called off-leak current, leak current, and ineffective improvement of the dielectric constant of the entire gate insulation film

Inactive Publication Date: 2011-04-12
KK TOSHIBA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The solution effectively increases the effective film thickness of the gate insulation film, reducing off-leak current and enabling fine patterning, while maintaining a stable interface with the silicon substrate and enhancing the reliability of the gate insulation film by canceling volume expansion due to temperature variations.

Problems solved by technology

Consequently, there arises a problem of an increase in so-called off-leak current.
That is, even when no voltage is applied to the gate electrode, carriers pass through the gate insulation film and a leak current occurs.
Thus, the dielectric constant of the entire gate insulation film is not effectively improved, nor is a stable interface with the silicon substrate formed (see, e.g. Z. Yu, J. Ramdani and J. A Curless et al., “Epitaxial oxide thin films on Si(001)”, J. Vac. Sci. Technol.
However, the amorphous structure has poor polarizability, and a high dielectric constant can hardly be obtained.

Method used

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  • Semiconductor device including gate insulation film that is formed of pyroceramics, and method of manufacturing the same
  • Semiconductor device including gate insulation film that is formed of pyroceramics, and method of manufacturing the same
  • Semiconductor device including gate insulation film that is formed of pyroceramics, and method of manufacturing the same

Examples

Experimental program
Comparison scheme
Effect test

first embodiment

[0026]A semiconductor device according to the first embodiment of the present invention is described with reference to FIG. 1 and FIG. 2. FIG. 1 is a cross-sectional view that schematically shows the semiconductor device according to the first embodiment. FIG. 2 is a cross-sectional view that shows, in enlarged scale, the structure of a gate insulation film 13 shown in FIG. 1.

[0027]As is shown in FIG. 1, a gate-insulated field-effect transistor TR is provided in a device region, which is isolated by a device isolation film 12 that is provided on a major surface of a silicon substrate 11. The transistor TR comprises a gate insulation film 13 provided on the substrate 11, a gate electrode 14 provided on the gate insulation film 13, a silicide layer 14S provided on the gate electrode 14, a source S and a drain D provided in the substrate 11 so as to sandwich the gate electrode 14, silicide layers 15 provided on the source S and drain D, and spacers 16 provided on side walls of the gate...

second embodiment

Ion Implantation Process

[0079]A method of manufacturing a semiconductor device according to a second embodiment of the invention is described with reference to FIG. 10 and FIG. 11. A description of the parts that are common to those in the first embodiment is omitted.

[0080]As is shown in FIG. 10, ion species 23 such as Ba, Ti or Al, are directly implanted into the silicon substrate 11 by, e.g. an ion implantation process, down to a depth 41 that is equal to a necessary thickness of a gate insulation film 13.

[0081]Subsequently, as shown in FIG. 11, the substrate 11 is heated at about 1,000° C. in an oxygen atmosphere by, e.g. a thermal oxidation process. Thus, a silicon oxide film (SiO2 film) 20 including the ion species 23 is formed.

[0082]Then, using the same fabrication steps as in the first embodiment, the semiconductor device shown in FIG. 1 and FIG. 2 can be manufactured.

[0083]According to this manufacturing method, the same advantageous effects as with the first embodiment can ...

third embodiment

Laser Evaporation Process

[0084]A method of manufacturing a semiconductor device according to a third embodiment of the invention is described with reference to FIG. 12. A description of the parts that are common to those in the first embodiment is omitted. FIG. 12 is a view that schematically illustrates a fabrication step of the semiconductor device according to the third embodiment of the invention.

[0085]To start with, as shown in FIG. 12, oxide powder of, e.g. SiO2, BaTiO3 or Al2O3 is uniformly mixed with a necessary composition. The mixture is sintered, and a ceramics target 51 in a pellet form is fabricated.

[0086]Subsequently, a laser beam 55 is applied from a light source 54 to the target 51, thereby heating the target 51. A plume 52 of the oxide powder emanates from the ablated target 51. Following the above, the plume 52 of the oxide powders is evaporated and deposited on the major surface of the semiconductor substrate 11. Thus, an amorphous layer 24 is formed. Thereafter, ...

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Abstract

A semiconductor device includes a gate insulation film that is formed of pyroceramics including an amorphous matrix layer, which is provided on a major surface of a silicon substrate, and crystalline phases lines with a high dielectric constant, which are dispersed in the amorphous matrix layer. The semiconductor device further includes a gate electrode that is provided on the gate insulation film.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2005-010739, filed Jan. 18, 2005, the entire contents of which are incorporated herein by reference.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The present invention relates generally to a semiconductor device and a method of manufacturing the semiconductor device, and the invention is applicable to, for example, a gate insulation film of a MOSFET (Metal Oxide Semiconductor Field Effect Transistor).[0004]2. Description of the Related Art[0005]With development in fine patterning of semiconductor devices in recent years, the thickness of a gate insulation film has been decreased more and more. Consequently, there arises a problem of an increase in so-called off-leak current. That is, even when no voltage is applied to the gate electrode, carriers pass through the gate insulation film and a leak current occurs. It ...

Claims

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Application Information

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Patent Type & AuthorityPatents(United States)
IPC IPC(8): B82B1/00B82B3/00H01L27/088
CPCH01L21/28185H01L21/28194H01L21/28211H01L29/517H01L21/31691H01L29/511H01L21/2822H01L21/32155Y10S977/776Y10S977/779Y10S977/773Y10S977/778Y10S977/785H01L21/02164H01L21/02321
InventorJIN, ZHENGWU
OwnerKK TOSHIBA