The invention discloses a preparation method of a high-stability photoresponse
covalent organic framework membrane and application of the high-stability photoresponse
covalent organic framework membrane in selective separation of multiple components. 4-azido
azobenzene is prepared by carrying out azido reaction on 4-aminoazobenzene in an acidic
aqueous solution, and then a BPTA-TAPB-COF membrane is used as a matrix to prepare the high-stability photoresponse
covalent organic framework membrane. 4-azido
azobenzene is efficiently grafted to the pore wall of the BPTA-TAPB-COF membrane through a click
chemical reaction, the photoresponse covalent organic framework membrane is constructed, and the covalent organic framework membrane can be used for multi-component selective separation and is suitable for multi-component systems with different sizes. The
azobenzene group in the pore channel of the prepared Azo-COF membrane is subjected to reversible cis-trans
isomerization under the
irradiation of
ultraviolet / visible light, the response speed is high, and the cycle performance is good; the Azo-COF membrane has good application in the light-operated
nanofiltration process, the performance of the Azo-COF membrane is not reduced after the Azo-COF membrane is continuously recycled for 12 days, and the structure of the Azo-COF membrane is kept stable.