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The application provides a benzamide bromide-modified perovskite solar cell and a preparation method thereof, and belongs to the technical field of perovskite solar cells; the application solves the problem of low photoelectric conversion rate and poor stability of existing perovskite solar cells caused by uncoordinated lead ions; the application comprises the following steps: S1, placing a substrate covered with a transparent metal electrode into deionized water, acetone and ethanol for ultrasonic cleaning in sequence, and then drying and treating by ultraviolet ozone to form a conductive substrate; S2, spin coating an electron transport layer on the conductive substrate; S3, spin coating and depositing a perovskite active layer on the surface of the electron transport layer, wherein the perovskite active layer uses benzamide bromide as a passivation agent; S4, spin coating a hole transport material on the surface of the perovskite active layer to obtain a hole transport layer; and S5, evaporating a metal electrode on the hole transport layer; the application is applied to perovskite solar cells.