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Production process of carbazol and anthracene

A production process, carbazole technology, applied in the new production process field of high-quality carbazole and anthracene, which can solve problems such as lack of consideration, potential safety hazards, low product yield and product quality

Inactive Publication Date: 2010-06-30
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method has the following disadvantages: 1) when extracting phenanthrene, a certain amount of anthracene and carbazole are taken out, which reduces the yield of anthracene and carbazole; 2) this method improves product quality by increasing the number of times of washing , product quality and yield are a pair of contradictions
Therefore, the production scale of this method is small, the solvent consumption is large, and the product yield and product quality are both low; 3) the traditional crude anthracene washing and refining method is basically based on the assumption that anthracene, phenanthrene, and carbazole are separated from each other. 4) There are potential safety hazards and environmental pollution problems in the process; 5) The entire production process is intermittent operation, and the degree of automation is greatly limited by objective conditions

Method used

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  • Production process of carbazol and anthracene

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1: Crude anthracene processing capacity 1000kg / hr produces refined carbazole and refined anthracene

[0024] Crude anthracene raw material, which contains 28% of anthracene, 27% of phenanthrene, 14% of carbazole, about 13% of light components in total, and about 18% of derivatives and heavy components. Production equipment, processes such as figure 1As shown, the crude anthracene raw material enters the raw material pre-washing tank 01 in an amount of 1000kg / hr for pre-washing, and the pre-washing 1# solvent is xylene (mixed xylene, the same below), and the mass ratio of xylene to raw material is 2:1 , washing is carried out at 28°C under normal pressure, and after stirring for 10 minutes, the solid-liquid mixture in the raw material washing tank 01 is transported to the automatic centrifuge 02 for solid-liquid separation at a speed of 6000r / min, and the solid phase obtained from the separation is the filter residue , the components are carbazole, anthracene...

Embodiment 2

[0026] Embodiment 2: crude anthracene processing capacity 1000kg / hr produces refined carbazole and refined anthracene

[0027] Crude anthracene raw material, which contains 28% of anthracene, 27% of phenanthrene, 14% of carbazole, about 13% of light components in total, and about 18% of derivatives and heavy components. Production equipment, processes such as figure 1 As shown, the crude anthracene raw material enters the raw material pre-washing tank 01 in an amount of 1000kg / hr for pre-washing, the pre-washing 1# solvent is 200# solvent oil, the mass ratio of solvent to raw material is 2.5:1, and the washing is performed at normal pressure at 28°C After stirring for 10 minutes, the solid-liquid mixture in the raw material washing tank 01 is transported to the automatic centrifuge 02 for solid-liquid separation, the rotation speed is 5500r / min, and the solid phase obtained from the separation is the filter residue, and the components are carbazole, Anthracene, a small amount...

Embodiment 3

[0029] Embodiment 3: crude anthracene processing capacity 1100kg / hr produces refined carbazole and refined anthracene

[0030] The crude anthracene raw material contains 26% of anthracene, 28% of phenanthrene, 12% of carbazole, about 12% of light components in total, and about 24% of derivatives and heavy components. Production equipment, processes such as figure 1 As shown, the crude anthracene raw material enters the raw material pre-washing tank 01 at an amount of 1100kg / hr for pre-washing. The pre-washing 1# solvent is trimethylbenzene, and the mass ratio of the solvent to the raw material is 2.5:1, and the washing is carried out at normal pressure at 28°C After stirring for 10 minutes, the solid-liquid mixture in the raw material washing tank 01 is transported to the automatic centrifuge 02 for solid-liquid separation at a speed of 6500r / min. The solid phase obtained from the separation is the filter residue, and the components are carbazole, anthracene, A small amount o...

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Abstract

The present invention discloses a manufacture process for high quality carbazole and anthracene. The method is to wash the raw material once for removing a number of light constituent, phenanthrene, carbazole derivatives, a small quantity of anthracene and part of heavy constituent, and the loss of the carbazole is less. Afterwards, a vacuum rectification tower with siding withdrawing is adopted for withdrawing the carbazole from the siding at a proper height of the tower. The purity can reach 90 to 95 weight percent, and meanwhile a mixture with the overall purity of the anthracene and phenanthrene being up to more than 90 weight percent is obtained from the top of the tower. The two materials are respectively washed by a No.1 solvent and a No.2 solvent, and the trace impurities contained in the materials are removed. After centrifugalized, fine carbazole and fine anthracene products which are better than the first grade product (carbazole of more than 97 weight percent and fine anthracene of more than 95 weight percent) according to the national standard can be obtained. The solvent wash is operated at a normal temperature, the solvent can be withdrawn for periodic duty, is lessin loss quantity, and does not pollute environment. Not only the large-scale successive industrial production of fine carbazole and fine anthracene can be realized easily, but also the process is economic in investment, low in energy dissipation and friendly in environment.

Description

field of invention [0001] The invention relates to a new production process of high-quality carbazole and anthracene. Background technique [0002] Carbazole is an important dye and pigment intermediate, which can be used to synthesize Haichang blue, dyes for carbon paper, etc. Refined carbazole is the basic raw material for the production of permanent violet RL, which is known as the king of purple dyes. In addition, carbazole can also be used as a raw material for synthetic resins, precious metal ore flotation agents, water reducers, stabilizers for lubricating oils and heat transfer oils, surfactants, fluorescent plasticizers, etc. In the 21st century, the application of carbazole in light-conducting and conductive special high-tech materials and biologically active substances (stabilizers for pesticides, plant auxins, anti-inflammatory drugs, and drugs for treating heart disease) is even more eye-catching. [0003] The most important use of anthracene is to obtain anthr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D209/84C07C15/28C07C7/04C07C7/00
Inventor 张志炳周政耿皎王明明孟为民王宝荣
Owner NANJING UNIV
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