Use of an aureolysin inhibitor for the treatment of inflammatory skin conditions characterised by colonisation with staphylococcus aureus
A technology of metalloprotease and staphylococcus, which is applied in the direction of skin diseases, antibacterial drugs, organic active ingredients, etc., and can solve the problems of no effect, no limited cutting, etc.
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[0096] Synthetic example
[0097] 1. Synthesis of compounds 11 and 12
[0098] Two interchangeable synthetic routes were used to generate compounds 11 and 12. The first is, for example, the synthesis of compound 11 from (R)-2-(2-methoxy-2-oxyethyl)-4-methylpentanoic acid. The second is, for example, the synthesis of compound 12 from L-leucine. The first route can be used to synthesize compound 12 by using (S)-2-(2-methoxy-2-oxyethyl)-4-methylvaleric acid, and the second route can be used to synthesize compound 12 by using D-leucine instead of Compound 11 was synthesized from L-leucine.
[0099] A.(R)-N1-((S)-3,3-Dimethyl-1-(methylamino)-1-oxobutan-2-yl)-N4-hydroxy-2-isobutyl Synthesis of Succinamide (Compound 11)
[0100] i) (R)-2-(2-Methoxy-2-oxoethyl)-4-methylpentanoic acid (0.5g, 2.4mmol), DCC (1.2eq, 0.61g) and HOBT were stirred at room temperature (1.02eq, 0.34g) in dichloromethane (5ml) for 10 minutes. (S)-2-Amino-N,3,3-trimethylbutanamide (1.1 eq, 0.39 g) was add...
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