Surface treatment agent for paper
A surface treatment agent and paper technology, applied in thin material treatment, fiber raw material treatment, papermaking, etc., can solve the problems of increased coating amount, difficult to coat paper, high gloss, light weight, low coating amount, etc.
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[0087] The practice of the invention is illustrated by the following examples. The examples describe the examples of the present invention and do not limit the present invention.
[0088] Hereinafter, "parts" and "%" indicating the compounding amount both represent "parts by weight of solid content" and "% by weight of solid content".
[0089] [Method for producing cationic group-containing copolymer]
[0090] Using the monomers in Table 1, a cationic group-containing copolymer was produced by the following method.
manufacture example 1
[0092] In a 1L beaker, 267.4 g of ion-exchanged water and MOEDES (an equimolar adduct of dimethylaminoethyl methacrylate and dimethyl sulfate (the active ingredient is 80% by weight) are mixed, all are reagents, produced by Wako Pure Chemical Industries, Ltd. Co., Ltd.) 185.63g (active ingredient 148.50g), DMAAm (N,N-dimethylacrylamide, reagent, Wako Pure Chemical Industries, Ltd.) 110.46g, NK-14G (cross-linking agent, polyethylene glycol Alcohol di(methacrylate), manufactured by Shin-Nakamura Chemical Co., Ltd.) 0.415 g, V-50 (polymerization initiator, 2,2'-azobis(2-amidinopropane) dihydrochloride, Wako Pure Chemical Industries, Ltd. Kogyo Co., Ltd.) 0.952 g to prepare monomer aqueous solution A. 1648 g of cyclohexane and 1.94 g of sugar ester S-770 (manufactured by Mitsubishi Kasei Co., Ltd.) as a dispersant were placed in a 5 L glass container, and were uniformly dissolved at 60° C. for 1 hour. After dissolving, it was cooled to 30° C. to prepare a dispersant solution B. ...
manufacture example 2~3
[0096] According to the method of the manufacture example 1 of the multipolymer containing cationic group, the monomer composition shown in Table 1 is composed of the copolymer containing cationic group 2 (average particle diameter is 3.8 μm) and 3 (average particle diameter is 5.1 μm).
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