Combined process method for heavy oil modification

A combined process and heavy oil upgrading technology, which is applied in the petroleum industry, hydrotreating process, hydrocarbon oil treatment, etc., can solve the problem of reducing the processing capacity and economic benefits of heavy oil catalytic cracking units, increasing the sulfur content of products, and increasing the load of regenerators, etc. problems, to achieve the effect of improving the fusion effect and reaction effect, increasing the yield of light oil, and reducing the load

Active Publication Date: 2011-01-12
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because the heavy cycle oil produced in catalytic cracking contains polycyclic aromatic hydrocarbons, the yield of light oil is low and the amount of coke is large, which increases the load of the regenerator and reduces the processing capacity and economic benefits of the heavy oil catalytic cracking unit.
In addition, the sulfur content of heavy cycle oil is relatively high, about twice that of hydrogenated tail oil, and the cycle of heavy cycle oil also increases the sulfur content of the product

Method used

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  • Combined process method for heavy oil modification
  • Combined process method for heavy oil modification
  • Combined process method for heavy oil modification

Examples

Experimental program
Comparison scheme
Effect test

Embodiment -1

[0021] After the Tahe residual oil is treated with the same filtration as the conventional process, the heavy oil raw material is subjected to supercritical treatment, and added to the static mixer with tetralin, (keep excess tetralin, the weight of heavy oil raw material and tetralin The ratio of oil to agent is 1:6), and then the material is heated, enters the CSTR (continuously stirred tank reactor), pressurizes, heats up and starts stirring, the speed is 800 rpm, pressurizes to 20MPa, heats up to 400°C, the reaction time for 3h. The reacted product enters the separator after being filtered, and the gas phase and liquid phase are separated. The solid impurities separated by filtration can be burned or used as needle coke raw materials, and the liquid phase enters the fractionation tower. The fractionation tower separates various light fractions (gasoline fraction and diesel fraction) and excess hydrogen-donating solvent. The excess hydrogen-donating solvent can be recycled...

Embodiment -2

[0023] Using Tahe residual oil as raw material, the supercritical treatment steps are the same as in Example-1. The heavy oil raw material is subjected to supercritical treatment, the hydrogen-donating solvent is decahydronaphthalene, the weight ratio of heavy oil raw material and hydrogen-donating solvent is 1:2, the reaction pressure is 35MPa, the reaction temperature is 450°C, and the reaction time is 0.5h (CSTR is a continuous feed discharge, the reaction time is the average residence time of the material). The heavy oil fraction separated from the fractionation tower enters catalytic cracking, the operating conditions are temperature 510°C, pressure 0.2MPa, solvent-oil ratio 5:1, space velocity 10h -1 . Separating the reaction products to obtain dry gas, liquefied petroleum gas, gasoline, diesel oil, heavy cycle oil and oil slurry, in which the heavy cycle oil is recycled to supercritical treatment; after the oil slurry is distilled to separate the residue, the distillat...

Embodiment -3

[0025] By the same method as in Example 2, water was added while using decahydronaphthalene, and the weight ratio of water and supercritical treatment feed was 2: 1. The catalytic cracking reaction results are shown in Table 2.

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Abstract

The invention discloses a combined process method for heavy oil modification, which comprises the following steps of: mixing heavy oil raw materials and a hydrogen supply solvent for supercritical treatment, and making the heavy oil subjected to the supercritical treatment enter a catalytic cracking unit for treatment; and performing a cracking reaction in the presence of a cracking catalyst, and separating reaction products to obtain dry gas, liquefied gas, gasoline, diesel oil, heavy cycle oil and slurry oil, wherein the heavy cycle oil partially or totally cycles for the supercritical treatment, and the slurry oil partially or totally cycles for the supercritical treatment. The supercritical treatment method for the heavy oil raw materials comprises the step of mixing the heavy oil raw materials and the hydrogen supply solvent for the supercritical treatment, wherein the hydrogen supply solvent comprises tetrahydronaphthalene or decahydronaphthalene. The method has the advantages of capacity of effectively improving the utilization rate of poor-quality heavy oil, low coking rate, stable production process, and suitability for light treatment of various heavy and poor-quality raw materials.

Description

technical field [0001] The invention relates to a combined process for upgrading heavy oil, in particular to a combined process for upgrading inferior heavy oil. Background technique [0002] At present, due to the depletion of oil resources and the increasing demand for oil due to economic development, oil resources are increasingly precious. Moreover, as crude oil resources become heavier, in the refining process of petroleum, the yield of residual oil is relatively high, generally 40%-50%. In addition, there are many heavy crude oils in the crude oil reserves in the world, most of which are residues, and they are low-quality residues with high impurity content. [0003] The currently industrialized methods for treating these residual oils or heavy oils include: catalytic cracking, residual oil hydrogenation, delayed coking, visbreaking and other methods or combined methods. As the residual oil becomes more and more inferior, and the content of sulfur, nitrogen and metal...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G69/04
Inventor 刘建锟杨涛胡长禄吴长安苗景安王志勇
Owner CHINA PETROLEUM & CHEM CORP
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