Diaryl hepatonoid-based compound useful as virus inhibitor
A compound and composition technology, applied in the direction of antiviral agents, active ingredients of carbohydrates, active ingredients of ketones, etc.
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Embodiment 1
[0108] Embodiment 1: the preparation of Japanese alder extract
[0109] 3.5 kg of Japanese alder (RNL BIO Co., Ltd.) bark was added to 9 L of 95% ethanol, sonicated three times at 55 °C, and then concentrated to obtain 900 g of ethanol fraction (12B-AJ-5A). Such as figure 1 As shown, the obtained 12B-AJ-5A component is CH 2 Cl 2 and ethanol to obtain dichloromethane (CH 2 Cl 2 ) component (12B-AJ-5B, 139 g), ethanol component (12B-AJ-5C, 400 g) and water component (12B-AJ-5D).
[0110] In addition, 12B-AJ-5D was treated with 20%, 50%, 70% and 100% methanol, respectively. As a result, 12B-AJ-5E, 12B-AJ-5F, 12B-AJ-5G and 12B-AJ-5H were obtained.
[0111] Among these fractions, the 12B-AJ-5B fraction was subjected to silica gel column chromatography (70230 mesh) with a hexane-ethyl acetate solvent gradient of 20:1 (100% ethyl acetate) to obtain 7 fractions (12B-AJ-20A to 12B-AJ-20G) ( figure 2 ).
Embodiment 2
[0112] Example 2: Measurement of Antiviral Activity of Japanese Alder Extracts and Compounds Derived from Japanese Alder Extracts
[0113] To measure the antiviral activity of the Japanese alder extract and compounds derived from the Japanese alder extract, KBNP-0028 (KCTC 10866BP), which has excellent proliferation ability, was used as an avian influenza virus. Herein, KBNP-0028 (KCTC 10866BP) was obtained by subculturing A / chicken / Korea / SNU0028 / 2000 (H9N2) isolated in Korea in 2000 and cloning the cultured virus.
[0114] For incubation of hatchery eggshell fragments, the shells of 10–11 day old SPF hatchery eggs (Sunrise Co., NY) were washed with 70% ethanol, and embryos and body fluids were removed. The resulting eggshells were cut to approximately 8 mm x 8 mm size so that the chorioallantoic membrane attached to the inner surface of the eggshell was not detached. Add the cut eggshell fragments to each well of a 24-well culture plate. The medium used in this experiment...
preparation Embodiment 1
[0117] Preparation Example 1: Isolation and Purification of 5-Hydroxy-1,7-bis(4-hydroxyphenyl)-3-heptanone
[0118] The 12B-AJ-20G component obtained in Example 1 is subjected to repeated column chromatography separation, such as image 3 As shown, thus obtaining pure compound 12B-AJ-31B (20 mg) and 12B-AJ-34A (10 mg).
[0119] The 12B-AJ-34A component was analyzed by NMR, and the analysis results showed that the 12B-AJ-34A component was platyphyllone (5-hydroxyl-1,7-bis(4-hydroxyphenyl)-3-heptanone) (Elita Smite et al., Phytochemistry , 33(2):365; Table 10 and Figure 11). Also, 12B-AJ-31B was analyzed by TLC and NMR, and it was found to have the same composition as 12B-AJ-34A.
[0120] [Formula 2]
[0121]
[0122] carbon number.
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