Restoring method for soil polluted by acephate pesticide
A technology for pesticide-contaminated soil and acephate, which is applied in the field of remediation of organic-contaminated soil, can solve problems such as soil pollution, and achieves the effects of low cost, simple and easy method, and complete remediation.
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Embodiment 1
[0023] Weigh 98g of soil into a 500ml beaker, add 2g of CaO, and mix well. Then add 80ml of acephate concentration of 750mg / L solution, stir evenly to obtain soil containing acephate concentration of 333.3mg / Kg. After 3 hours, the acephate in the soil was extracted with dichloromethane, and its content was measured with 4-(4-nitrobenzyl)pyridine as a color reagent. The degradation rate of acephate was above 97%.
Embodiment 2
[0025] Weigh 95g of soil into a 500ml beaker, add 5g of CaO, and mix well. Then add 80ml of acephate concentration of 750mg / L solution, stir evenly to obtain soil containing acephate concentration of 333.3mg / Kg. After 3 hours, the acephate in the soil was extracted with dichloromethane, and its content was measured with 4-(4-nitrobenzyl)pyridine as a chromogen. The degradation rate of acephate was above 98%.
Embodiment 3
[0027] Add 2Kg of soil with acephate concentration of 333.3mg / kg, and add enough water to just submerge the soil, insert a graphite electrode at room temperature and apply a constant voltage to make the potential gradient 1.5V / cm, for 10 Every other day, samples were taken at the anode area, the middle point and the cathode area to analyze the concentration of acephate. And after every 48 hours, the positive electrode and the negative electrode are reversed, and the cathode area is made alkaline by means of the electrochemical electrolysis reaction, and the acephate is degraded by the hydroxide generated by the cathode electrochemical reaction. After the electrode is adjusted, the original acidic anode area is transformed into alkaline, thereby degrading acephate. After 10 days, the average degradation rate of acephate at each site was above 90%.
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