In-depth profile controlling agent for medium temperature oil deposit three compound combination flooding

A technology of deep profile control and ternary compounding, which is applied in the direction of drilling compositions, chemical instruments and methods, etc., can solve the problems of high damage to low-permeability layers, limited scope of application, and difficulty in forming gel systems, etc., and achieves improved sweep Volume, low initial viscosity, and the effect of solving injectability problems

Inactive Publication Date: 2015-01-07
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Fan Wengang mentioned the chromium gel system formula that can withstand a pH value above 13, but due to the three-dimensional network structure of the gel system, it is difficult to achieve deep migration in bedrock reservoirs, and it will cause great damage to low-permeability layers. Therefore, it is difficult to be used for diversion of deep liquid flow after ASP flooding (Fan Wengang, A new profile control agent suitable for ASP flooding, Zhongwai Energy, Issue 9, 2011, 51-53)
In US3759857, a sodium hypochlorite catalyzed cross-linked polyacrylamide gel formula system was proposed. Although this system can form a gel at a pH value above 13, the scope of application is limited, and it can only adapt to lower oil reservoir temperatures. It is difficult to form a gel system due to the side reaction of sodium hypochlorite that violently degrades polyacrylamide

Method used

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  • In-depth profile controlling agent for medium temperature oil deposit three compound combination flooding
  • In-depth profile controlling agent for medium temperature oil deposit three compound combination flooding
  • In-depth profile controlling agent for medium temperature oil deposit three compound combination flooding

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Under the conditions of simulated water, select partially hydrolyzed polyacrylamide NJ-1 (molecular weight 10 million, degree of hydrolysis 1%) and NJ-2 (molecular weight 20 million, degree of hydrolysis 10%) with different degrees of hydrolysis and molecular weight, respectively configure the mass An aqueous solution of NJ-1 polymer with a concentration of 0.15% and an aqueous solution of NJ-2 polymer with a mass concentration of 0.1%. Then take a part of the above two polymer aqueous solutions respectively, and add sodium hydroxide therein to make the mass concentration of sodium hydroxide 0.2%. Another part of the above-mentioned two polymer aqueous solutions without adding alkali is reserved. Using a Brookfield viscometer at 45°C, 7.34s -1 Measure the initial viscosities of these four solutions under the conditions of 45°C, put the four solutions into an oven at 45°C and measure their viscosity after aging for 1 day, and calculate the viscosity adjustment times bas...

Embodiment 2

[0040] Under the condition of simulating water, configuration mass concentration is the NJ-1 polymer aqueous solution of 0.2%, then adds sodium hydroxide to it and is made into the solution of different sodium hydroxide mass concentrations (0,0.05,0.2,1.0%), then Put the prepared solution in a 45°C oven for aging, take it out after different times (0, 1, 3, 7, 15, 30, 60, 90, 120, 180 days), and use a Brookfield viscometer at 45°C, 7.34s -1 Measure the viscosity of the solution regularly under the conditions, and calculate the viscosity adjustment multiple based on the solution viscosity without adding alkali. The results are as follows: figure 2 shown.

[0041] Depend on figure 2 It can be seen that during the 180-day investigation period, under different sodium hydroxide concentrations, the NJ-1 alkali-resistant polymer can delay the viscosity increase for one month, and realize the adjustment of the viscosity ratio up to 30 times. increase, the viscosity increase ratio ...

Embodiment 3

[0043] Under the condition of simulating water, configure the NJ-1 polymer aqueous solution that mass concentration is 0.2%, then add sodium carbonate to it and be made into the solution of different sodium carbonate mass concentration (0,0.05,0.2,1.0%), then will prepare Put the solution in a 45°C oven for aging, take it out after different times (0, 1, 3, 7, 15, 30, 60, 90, 120, 180 days), and use a Brookfield viscometer at 45°C, 7.34s -1 Measure the viscosity of the solution regularly under the conditions, and calculate the viscosity adjustment multiple based on the solution viscosity without adding alkali. The results are as follows: image 3 shown.

[0044] Depend on image 3 It can be seen that under the condition of sodium carbonate, during the 180-day investigation period, the viscosity ratio of NJ-1 alkali-resistant polymer can be adjusted by 10 times. With the increase of sodium carbonate concentration, the viscosity increase ratio first increases and then decreases...

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Abstract

The invention provides an in-depth profile controlling agent for medium temperature oil deposit three compound combination flooding. The in-depth profile controlling agent comprises the following components in percentage by mass: 0.05-1.0 percent of acrylamide homopolymer or copolymer and the balance of water and also comprises less than 1.0 percent of inorganic salt. The profile controlling agent is low in initial viscosity during injection, a high-pH value environment generated by residual alkali in the formation pores is affected by utilizing the three compound combination flooding, the viscosity of the polymer solution is gradually increased under the action of the oil deposit temperature, and the tackifying time can last 3-180 days. Moreover, the viscosity ratio of displacing fluid in different pores is regulated, so that the effects of changing the deep liquid flow direction, enlarging the swept volume and finally improving the recovery efficiency are achieved.

Description

technical field [0001] The invention relates to a deep profile control agent used after three-element compound flooding in medium-temperature oil reservoirs, in particular to a deep profile control agent used after three-element compound flooding in medium-temperature sandstone oil and gas reservoirs, and belongs to the technical field of petroleum exploitation. Background technique [0002] In my country's Daqing, Xinjiang, Jilin and Liaohe oilfields, ASP flooding has entered the stage of industrialization test and pilot test respectively, and has achieved a development effect of increasing the recovery rate by more than 18%. Now it has become the next step of PetroChina's tertiary oil recovery. direction of the subject. [0003] ASP flooding is a compound system composed of alkali, polymer and surfactant. Through compounding, it forms an ultra-low interfacial tension with formation crude oil, improves oil displacement efficiency, and achieves the purpose of enhancing oil re...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C09K8/508
CPCC09K8/5083C09K8/588
Inventor樊剑罗文利蔡红岩黄丽周新宇龙杭李建国武劼朱友益
OwnerPETROCHINA CO LTD