A kind of loaded type diesel oil hydrogenation treatment catalyst and its application

A hydrotreating, load-type technology, applied in the direction of physical/chemical process catalysts, hydrocarbon oil treatment, petroleum industry, etc., can solve the problems of not being able to reduce the content of the three substances at the same time, high catalyst cost, low catalytic efficiency, etc., to improve Improved heat resistance, dearomatization effect, and high catalytic efficiency

Active Publication Date: 2017-02-15
SHANDONG HUAXING PETROCHEM GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to solve this problem, the existing method generally adopts the method of hydrogenation refining of gasoline and diesel. The existing problems are that the cost of the required catalyst is high, the catalytic efficiency is low, and it is easy to deactivate, and hydrogen of higher purity is required in the refining process. ; In addition, the existing catalysts can only reduce one of sulfur, nitrogen or aromatic compounds in the refining process, but cannot reduce the content of the three substances at the same time

Method used

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  • A kind of loaded type diesel oil hydrogenation treatment catalyst and its application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Example 1 Preparation method of a supported diesel hydrotreating catalyst

[0033] (1) Nano Fe 2 The preparation steps of P are as follows:

[0034] ① Hydrothermal treatment of red phosphorus: Take an appropriate amount of lumpy red phosphorus, put it in a mortar, add distilled water to immerse the red phosphorus, grind for 10 minutes, turn the lumpy red phosphorus into powder, and mix it with distilled water to form a uniform and fine paste. Transfer the pasty red phosphorus to the PTFE lining, and add distilled water to make the filling rate of the lining reach 80%; cover the inner lining, put it vertically into the autoclave, and put it into the gasket , tighten the seal, then put the reaction kettle into a constant temperature oven, heat up to 180°C, keep it warm for 24 hours, cool down to room temperature naturally, take out the tetrafluoroethylene liner carefully, transfer the contents into a beaker, and obtain nano-scale The suspension of red phosphorus powder ...

Embodiment 2

[0039] Example 2 Preparation method of a supported diesel hydrotreating catalyst

[0040] (1) Nano Fe 2 The preparation steps of P are as follows:

[0041] ① Hydrothermal treatment of red phosphorus: Take out an appropriate amount of lumpy red phosphorus, put it in a mortar, add distilled water to immerse the red phosphorus, and grind for 30 minutes to turn the lumpy red phosphorus into powder, and mix it with distilled water to form a uniform and fine paste. Transfer the pasty red phosphorus to the PTFE lining, and add distilled water to make the filling rate of the lining reach 80%; cover the inner lining, put it vertically into the autoclave, and put it into the gasket , tighten the seal, then put the reaction kettle into a constant temperature oven, heat up to 220°C, keep warm for 20 hours, cool down to room temperature naturally, take out the tetrafluoroethylene liner carefully, transfer the contents into a beaker, and obtain nano-scale The suspension of red phosphorus ...

Embodiment 3

[0046] Example 3 Preparation method of a supported diesel hydrotreating catalyst

[0047] (1) Nano Fe 2 The preparation steps of P are as follows:

[0048] ① Hydrothermal treatment of red phosphorus: Take out an appropriate amount of lumpy red phosphorus, put it in a mortar, add distilled water to immerse the red phosphorus, grind for 15 minutes, turn the lumpy red phosphorus into powder, and mix it with distilled water to form a uniform and delicate paste. Transfer the pasty red phosphorus to the PTFE lining, and add distilled water to make the filling rate of the lining reach 80%; cover the inner lining, put it vertically into the autoclave, and put it into the gasket , tighten the seal, then put the reaction kettle into a constant temperature oven, heat up to 200°C, keep warm for 22 hours, cool down to room temperature naturally, take out the tetrafluoroethylene liner carefully, transfer the contents into a beaker, and obtain nano-scale The suspension of red phosphorus po...

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Abstract

The invention relates to a novel load type diesel hydrotreating catalyst and application thereof. According to the technical scheme, a metallic element and nano Fe2P are loaded onto an oxide carrier, wherein the oxide carrier is SiO2-TiO2-Al2O3 ternary oxide carrier, and the metallic element is one or a mixture of at least more than two in Mo, Co, Ni, Pt and Pd. The novel load type diesel hydrotreating catalyst has a mesopore (1-40nm) structure in microscopic view, and not only is high in hydrodesulfurization (HDS) activity and high in hydrodenitrification (HDN) activity in the aspect of diesel hydrofining, but also is high in activity in the aspect of hydrogenation saturation (HDA) of aromatic hydrocarbon. The novel load type diesel hydrotreating catalyst has the advantages that the operation is simple, and the technological conditions needed by the novel load type diesel hydrotreating catalyst are milder than original technological conditions.

Description

technical field [0001] The invention belongs to the field of diesel catalysts, and in particular relates to a loaded diesel hydroprocessing catalyst and its application in a hydrogenation process. Background technique [0002] In recent years, with the development of diesel engine technology, especially the application of EFI technology, the demand for diesel in countries around the world is increasing. According to statistics, from 1990 to 1999, the annual growth rate of diesel in the world reached 7.9%. Above, but a series of problems have also appeared while the demand for diesel oil is increasing rapidly, the most typical of which is the urban air pollution caused by automobile exhaust. [0003] For this reason, various countries have successively introduced new standards for diesel oil to limit the content of irrational components in diesel oil. The introduction of new standards has made the world's oil refining industry face the severe test of needing to produce cleane...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/19B01J27/185B01J35/10C10G49/06C10G49/04
Inventor 田爽孙学义李成华徐兴昌周文忠孙广辉文福庚崔向东聂义勇
Owner SHANDONG HUAXING PETROCHEM GRP
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