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A fluidized bed reactor

A technology of ebullating bed reactors and shells, applied in chemical instruments and methods, chemical/physical processes, etc., can solve the problems of lower product quality, high material requirements, and high energy consumption, and achieve optimized three-phase separation components, The effect of improving efficiency and flexibility, and easy operation

Active Publication Date: 2016-08-24
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing fluidized bed hydrogenation process has the following disadvantages: (1) The boiling material level of the catalyst is 30-50% higher than the static material level, and there needs to be a certain space between the boiling material level and the three-phase separator, so The amount of catalyst stored in the reactor is low, and the space utilization rate of the reactor is low; (2) The efficiency of the three-phase separator for separating solids is low, and a complicated material level monitor is required to monitor the catalyst material level; (3) The energy consumption is large, and the solids The fluidization of the catalyst is achieved by injecting a large amount of circulating oil into the circulating oil pump; (4) There is very little hydrogen in the circulating downcomer, which is a non-hydrogen environment, and the liquid will undergo secondary cracking reaction coking at high temperature and reduce product quality
[0006] CN201529519U discloses a kind of ebullating bed reactor of outer circulation type, and catalyzer can fluidize better, but there is almost no hydrogen to exist in the circulation downcomer of this reactor, and liquid can take place secondary cracking reaction coking at high temperature and reduce Product quality, at the same time, the structure of the outer loop reactor will have higher requirements on materials in actual production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0070] The specific dimensions of the ebullated bed reactor used in this example are shown in Table 1 below.

[0071] Table 1

[0072] code name

[0073] The above-mentioned ebullating bed reactor was used to carry out the cold model experiment, wherein the solid-phase catalyst was selected as a spherical catalyst with a particle size of 0.2-0.3mm, and the catalyst loading was 60% of the effective volume of the reactor. The liquid phase uses straight-run kerosene, and the volume space velocity is 0.25-3.0h -1. Nitrogen is used in the gas phase, and the gas-oil volume ratio is 20-150. The experimental results in the changing range of conditions show that the carryover of the solid phase catalyst is extremely low, the maximum is 1.5μg / g. At the same time, it can be observed in the experiment that there is sufficient circulating gas in the downcomer of the reactor, and the fluidization state of the solid-phase catalyst is good.

Embodiment 2

[0075] The specific dimensions of the ebullated bed reactor used in this example are shown in Table 2 below.

[0076] Table 2

[0077] code name

value

code name

value

d 1 / mm

300

h 1 / mm

5250

d 2 / mm

220

h 2 / mm

3000

d 3 / mm

400

h 3 / mm

600

d 4 / mm

360

h 4 / mm

87

d 5 / mm

300

h 5 / mm

480

d 6 / mm

480

α / °

60

d 7 / mm

340

β / °

60

d 8 / mm

540

ω / °

60

d 9 / mm

300

φ / °

60

d 10 / mm

550

θ / °

60

d 11 / mm

440

The total opening area of ​​the first gas separation pipe 24a / mm 2

3000

d 12 / mm

500

The total opening area of ​​the second gas separation pipe 24b / mm 2

6000

d 13 / mm

600

The total opening area of ​​the third gas separation pipe 24c / mm 2

8000

The total opening area of ​​the through hole / mm 2

...

Embodiment 3-5 and comparative example 1

[0082] Embodiment 3-5 uses the medium-sized hot state reactor made in the ratio of embodiment 1, and comparative example 1 uses the ebullating bed reactor described in CN1448212A. Examples 3-5 and Comparative Example 1 used the same ebullated bed catalyst and residual oil raw material, the physicochemical properties of the catalyst are shown in Table 3, and the properties of the residual oil raw material are shown in Table 4. The process conditions and test results of Examples 3-5 and Comparative Example 1 are shown in Table 5.

[0083] Table 3: Main physicochemical properties of ebullated bed catalysts

[0084]

[0085] Table 4: Properties of residual oil raw materials

[0086] nature

value

Density(20℃) / (g / cm 3 )

1.029

Carbon residue / wt%

19.61

Sulfur content / wt%

4.53

Nitrogen content / wt%

0.23

(Ni+V) content / (μg / g)

275.8

Asphaltenes (C 7 content) / wt%

6.5

[0087] Table 5: Process evaluatio...

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Abstract

The invention relates to a fluidized bed reactor. The fluidized bed reactor comprises a casing, a three-phase separation component, an inner tube and a gas-liquid distributor, wherein the casing successively comprises an expanding section, a transition section and a straight-drum section from top to bottom, the diameter of the expanding section is larger than that of the straight-drum section, the three-phase separation component is arranged in the expanding section and the transition section, the inner tube is arranged in the straight-drum section, and the gas-liquid distributor is arranged at the bottom of the inner tube; the three-phase separation component comprises a cone-shaped baffle which is formed in the circumferential direction, and a hollow revolving body arranged above the cone-shaped baffle, a through hole is formed in the cone-shaped baffle, the minimum distance from the through hole to the longitudinal central axis of the casing is larger than the minimum distance from the inner side of the hollow revolving body to the longitudinal central axis of the casing, the upper part of the hollow revolving body is in an inverted-frustum shape, and the lower part of the hollow revolving body is in a frustum shape. The fluidized bed reactor provided by the invention can obtain a better reacting effect.

Description

technical field [0001] The invention relates to an ebullating bed reactor, in particular to a gas-liquid-solid three-phase internal circulation ebullating bed reactor. Background technique [0002] The ebullating bed hydrogenation reactor is a gas-liquid-solid three-phase fluidized bed reactor. This type of reactor has the following advantages: it can process heavy and inferior raw materials with high metal content and high carbon residue value; the temperature of the reactor is easy to control and uniform, The pressure is low and constant; the catalyst can be added and taken out online, so the catalyst performance can be kept constant throughout the operation cycle; a higher conversion rate and a longer operation cycle can be achieved. [0003] Existing industrial ebullated bed hydrogenation technologies include H-oil process and LC-Fining process. The typical ebullating bed process is as follows: After the oil and gas are mixed, they enter the reactor from the lower part ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/24
CPCB01J8/22
Inventor 邓中活戴立顺牛传峰刘涛邵志才董凯施瑢杨清河
Owner CHINA PETROLEUM & CHEM CORP
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