Method for extracting V2O5 and KAl(SO4)2.12H2O from mica-type stone coal

Abstract

The invention particularly relates to a method for extracting V2O5 and KAl(SO4)2.12H2O from mica-type stone coal. The technical scheme is as follows: the method comprises the following steps: crushing mica-type stone coal raw ore, grinding, and carrying out sulfating roasting to obtain a roasted product; carrying out primary leaching and primary solid-liquid separation on the roasted product to obtain a primary leach solution and a primary leach residue; carrying out secondary leaching on the primary leach residue, carrying out secondary solid-liquid separation to obtain a secondary leach solution and a secondary leach residue, returning the secondary leach solution as a primary leaching agent, and using the secondary leach residue as end tailings; cooling the primary leach solution to crystallize to obtain a crude product and a mother solution, and recrystallizing the crude product to obtain the KAl(SO4)2.12H2O; and extracting the mother solution to obtain an extraction raffinate and a vanadium-rich solution, returning the extraction raffinate as a secondary leaching agent, and precipitating vanadium from the vanadium-rich solution to obtain the product V2O5. The method has the characteristics of high V and K leaching rates, high yield, high production continuity and environment friendliness, and is simple to operate.

Description

Technical field

[0001] The invention belongs to the field of Yunmu -type stone coal technology.Especially involved a kind of cloud -mother stone coal extraction V 2 O 5 And kal (so 4 Cure 2 · 12H 2 O method. Background technique

[0002] my country's potassium resource reserves are small, the distribution is uneven, and the self -sufficiency rate is low.At present, the potassium minerals that have been developed and used are mainly brine potassium ore, which cannot meet my country's needs.Due to the low quality of potassium containing potassium minerals (cloud mother, potassium long stone, alum stone, etc.), the high cost of developing economic costs has not been fully utilized.

[0003] Stone coal is a unique type of puppet resource in my country. Most of the stone coal is existed in cloudmate aluminum silicate minerals. While extracting V from the stone coal, the silicate mineral structure is destroyed. Enter the immersion solution with V and be enriched.Product V only extracts...