1819 results about "Vanadium atom" patented technology

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at pressure less than atmospheric pressure; a pump-out / evacuation tube extending at least partly into an aperture in one of the substrates; and a pump-out / evacuation tube seal. The pump-out / evacuation tube seal may include at least one of: (a) from about 20-80 wt. % tellurium oxide, the tellurium oxide comprising TeO4 and TeO3, wherein the pump-out tube seal comprises more TeO3 than TeO4 by wt. %; and / or (b) tellurium oxide and from about 10-50 wt. % vanadium oxide, wherein the pump-out tube seal by wt. % comprises more tellurium oxide than vanadium oxide, and wherein the vanadium oxide comprises VO2 and V2O5, and wherein more V in the pump-out tube seal is in a form of VO2 than V2O5. A substantially donut-shaped laser beam may be used to heat pump-out tube material in order to form a pump-out tube seal.

The invention provides a metallurgical process optimization method and system for a low-oxygen low-nitrogen aluminum-vanadium alloy, and relates to the technical field of process optimizing.The method comprises the steps that correlation characteristics among process parameters are extracted through a three-layer gating map attention network, and a parameter coupling state vector is constructed in combination with a time sequence attention module; constructing a process prediction model based on the state vector, and fusing a thermodynamic equilibrium equation and a long-short term memory network to predict the oxygen and nitrogen content; a deep reinforcement learning network of a Soft Actor-Critic algorithm is adopted, the parameter coupling state vector and the oxygen and nitrogen content prediction value serve as state input, and the technological parameter adjustment amount is output; and planning and iteratively training a future adjustment strategy through Monte Carlo tree search to finally obtain an optimal process parameter combination meeting oxygen and nitrogen content constraints, thereby realizing intelligent optimization control of the metallurgical process.

The invention relates to the field of chemical engineering and steel smelting, and discloses a method for extracting vanadium by top-blowing nitrogen-oxygen mixed gas, which comprises the following steps: S1, measuring the temperature of overline-crossing molten iron, sampling, and testing and analyzing the components of the molten iron; s2, measuring the temperature of the molten iron mixed into the converter; s3, according to the temperature measurement result in the S1 and the temperature measurement result in the S2, the charging temperature is corrected; s4, according to the corrected charging temperature, the proportion of the mixed gas is adjusted in a staged mode for blowing; s5, adding a coolant and pig iron into the furnace according to an analysis result in S1; and S6, after blowing is completed, slag and steel are separated, and vanadium slag and low-residue vanadium semisteel are obtained. According to the scheme, in order to solve the problems that in an existing vanadium extraction process, the temperature of a molten pool rises too fast, the stirring effect is insufficient, and the vanadium oxidation rate is limited, the recovery rate of vanadium is increased and the content of residual vanadium in semi-steel is reduced by accurately controlling the nitrogen-oxygen mixed blowing proportion, reasonably distributing the blowing time and combining heat balance calculation and end point control; and meanwhile, molten steel quality and subsequent steelmaking process requirements are guaranteed.

The invention relates to the technical field of new energy storage, in particular to electric pile temperature monitoring and control equipment of an all-vanadium redox flow energy storage system. The system is composed of a distributed temperature sensing array, a multi-parameter coupling analysis module, a self-adaptive temperature regulation and control system, a main control unit, a double-circulation heat management framework and a fault diagnosis module. The control method comprises the following steps: establishing a pile three-dimensional temperature field reference model; monitoring temperature distribution and electrolyte parameters in real time; calculating an efficiency loss coefficient caused by the local temperature difference; dynamically adjusting the refrigeration power and the pump set rotating speed; and executing temperature balance degree verification and system self-inspection. The invention provides an electric pile temperature management scheme integrating high-precision three-dimensional temperature monitoring, multi-parameter dynamic coupling regulation and control and intelligent fault diagnosis so as to solve the problems of monitoring blind areas, regulation and control delay, insufficient risk prediction capability and the like in the prior art, thereby improving the operation efficiency and safety of an all-vanadium redox flow energy storage system.

The invention relates to the technical field of vanadium pentoxide preparation, and particularly discloses a preparation method of high-purity vanadium pentoxide, which comprises the following steps: S1, vanadium slag pretreatment: carrying out microwave activation on vanadium slag, and then carrying out ball milling and roasting to obtain clinker; the sulfuric acid-oxalic acid composite acid and the clinker are mixed and leached, the pH is adjusted after leaching is completed, and vanadium-containing leachate is obtained through filtering; s3, vanadium enrichment: heating the vanadium-containing leachate, adding a sodium carbonate solution while stirring, adjusting the pH value, preserving heat and curing, and then carrying out hot filtration to obtain vanadium-rich filter residues; s4, vanadium purification: mixing the vanadium-rich filter residues with a sodium hydroxide solution, stirring, introducing compressed air while stirring, and carrying out hot filtration after the reaction is finished, so as to obtain vanadium-rich filtrate; and S5, calcining: carrying out two-stage calcining on the ammonium metavanadate precursor to obtain high-purity V2O5. The preparation method is high in vanadium recovery rate, and the purity of the prepared V2O5 is 99% or above.

The invention belongs to the field of hydrometallurgy, and particularly discloses a high-purity vanadium oxide electrode and a preparation method thereof. The method comprises the following steps: pre-treating the alkaline vanadium leaching solution by using an activated aluminum oxide adsorption column to obtain a pre-treated solution; adding a composite impurity removal agent taking modified lignosulfonate as a main agent into the pretreatment liquid for primary impurity removal to obtain primary impurity-removed filtrate; adding a calcium hydroxide suspension and a flocculating agent into the primary impurity-removed filtrate for secondary impurity removal to obtain secondary impurity-removed filtrate; purifying the secondary impurity-removed filtrate by using an ion exchange column to obtain a purified solution; ammonium salt is added into the purified liquid for vanadium precipitation, and ammonium metavanadate crystals are obtained; calcining the ammonium metavanadate crystal to obtain high-purity vanadium pentoxide; and preparing the high-purity vanadium oxide electrode by using the high-purity vanadium pentoxide. According to the scheme, the high-purity vanadium pentoxide is prepared by taking the alkaline vanadium leaching solution as a raw material through a multi-stage deep impurity removal process, and the high-purity vanadium oxide electrode is prepared by taking the alkaline vanadium leaching solution as the raw material.

The invention discloses a stone coal vanadium extraction method, and belongs to the technical field of stone coal vanadium extraction, and the method comprises the following steps: crushing stone coal vanadium ore, and simultaneously carrying out microwave irradiation to obtain an activated sample; immersing the activated sample and an oxidizing agent solution into an acid solution, heating and reacting to obtain a suspension, and carrying out solid-liquid separation to obtain a leachate; then, vanadium in the leachate is adsorbed and enriched through ion exchange resin containing quaternary ammonium groups, and an enriched vanadium solution is obtained through desorption with alkali liquor; then adjusting the pH value of the enriched vanadium liquid, adding an impurity removal agent, uniformly stirring, standing, and carrying out solid-liquid separation to obtain a purified liquid; finally, a precipitator is added into the purified liquid, solid-liquid separation is carried out after the reaction is completed, and the ammonium polyvanadate product is obtained.The method not only can remarkably reduce energy consumption, but also can effectively improve the purity of ammonium polyvanadate.

The invention discloses a composite thermochromic window with a dual-band dynamic regulation and control function. The composite thermochromic window comprises a first transparent substrate, a tungsten-doped vanadium dioxide film, a second transparent substrate and a hydrogel layer. The tungsten-doped vanadium dioxide film is deposited on the upper surface of the first transparent substrate, and the phase transition temperature is 25-32 DEG C; the hydrogel layer is thermo-sensitive poly (N-isopropylacrylamide) and is encapsulated between the two transparent substrates, and the low critical phase transition temperature is 32 + / -2 DEG C. When the temperature is lower than 25 DEG C, the infrared transmittance of the tungsten-doped vanadium dioxide film is larger than or equal to 75%, and the visible light scattering rate of the hydrogel layer is smaller than or equal to 10%; when the temperature is higher than 32 DEG C, the near-infrared transmittance of the tungsten-doped vanadium dioxide film is reduced to the minimum value, and the visible light scattering rate of the hydrogel layer is increased to 35% or above. Compared with the prior art, the system and the method have the advantages that dual-band dynamic regulation and control of visible light and near-infrared light are achieved, the indoor photo-thermal environment can be automatically regulated according to the environment temperature, and the building energy utilization efficiency is improved.

The invention discloses a functionalized carbon quantum dot modified all-vanadium redox flow battery electrolyte. The functionalized carbon quantum dot has a large specific surface area and a carboxyl functional group on the surface; the electrolyte of the flow battery is a dilute sulfuric acid solution of vanadium; the main evaluation indexes of the electrochemical performance are the cycle efficiency, the capacity retention ratio and the battery performance of the electrolyte; the invention aims to discuss the catalytic action of the surface functional groups of the functionalized carbon quantum dots on the oxidation-reduction reaction of vanadium ions in the electrolyte of the all-vanadium redox flow battery by using the functionalized carbon quantum dots as an additive of the electrolyte. Meanwhile, the influence of the concentration and doping of the carbon quantum dots on the electrochemical performance of the electrolyte of the all-vanadium redox flow battery is researched, so that the working efficiency and the overall performance of the battery are improved, the characteristics of the electrolyte are improved, and the energy consumption of the battery is reduced.

The invention provides a preparation method of a vanadium electrolyte for an all-vanadium redox flow battery, the vanadium electrolyte and application. The method comprises the following steps: (1) dissolving concentrated sulfuric acid in water to obtain a sulfuric acid solution with a preset concentration, then adding vanadium pentoxide into the sulfuric acid solution, and reacting to obtain a first vanadium solution; (2) the temperature of the first vanadium solution is kept to be the preset temperature, low-valence vanadium oxide is added into the first vanadium solution for reaction, water or hydrochloric acid is supplemented in the reaction process, a second vanadium solution is obtained, and the low-valence vanadium oxide is vanadium oxide with the valence of 3-3.5; and (3) filtering the second vanadium solution to obtain the vanadium electrolyte. The method provided by the invention can save energy consumption, reduce cost and improve dissolution efficiency.

The invention discloses a method for removing impurities and extracting vanadium from calcification roasting vanadium slag leachate, which comprises the following steps: S1, adding water and a leaching agent into calcification roasting vanadium slag clinker, and uniformly mixing to obtain first ore pulp, the leaching agent at least comprising triethanolamine, potassium sodium tartrate and acid liquor; s2, the pH value of the first ore pulp is adjusted to be 1-6, leaching is conducted under the preset leaching condition, and second ore pulp is obtained; and S3, the second ore pulp is filtered, and vanadium-containing leaching liquid and leaching residues are obtained. According to the method, impurity ion magnesium in the solution is complexed with triethanolamine to generate precipitates during leaching, so that the impurity ions are removed, the obtained leaching solution is low in impurity content and can be directly used for subsequent vanadium precipitation, the magnesium precipitates are flocculent, the leaching slag tailings of vanadium are granular, metals such as magnesium can be separated and recycled, and maximization of economic benefits is realized.

The invention discloses a bifunctional chiral metamaterial surface capable of switching polarization conversion and wave absorption, and belongs to the technical field of electromagnetic metamaterials. The method is used for solving the problem that most existing chiral super-structure surfaces cannot realize dynamic adjustability and quantitative controllability and cannot have dual functions of polarization conversion and wave absorption at the same time. The super-structure surface unit structure is composed of a graphene film layer, a gold-vanadium dioxide resonance layer, a silicon dielectric layer and a bottom-layer continuous gold film. Switching of two functions of polarization conversion and wave absorption is realized by changing the conductivity of vanadium dioxide; polarization conversion and dynamic regulation and control of the wave absorbing efficiency are realized by changing the Fermi level of the graphene; quantitative controllability of polarization conversion and a wave absorbing function is realized by controlling a function weighting function. Besides, the chiral super-structure surface also has the advantages of incident angle robustness, small thickness and small size, has double functions of broadband, and has potential application value in the fields of optical devices, communication equipment, biomedical sensors and the like.

The present invention discloses an aqueous zinc-ion battery, comprising: a positive electrode sheet, a negative electrode sheet and an electrolyte. The positive electrode material of the positive electrode sheet is a layered vanadium-based positive electrode material. Since cations and water molecules are inserted into the layers of vanadium pentoxide, the interlayer spacing is increased and the structure of the host material is supported and stabilized. Therefore, the fast and reversible insertion and extraction performance of charge and discharge ions can be improved, and the high rate and long cycle life of the layered vanadium-based positive electrode material can be achieved. The negative electrode sheet is a zinc foil with a surface coating. By defining the thickness of the surface coating to be 100 nm to 20 μm, the surface coating can prevent the zinc foil from directly contacting the electrolyte, and zinc will be deposited between the coating and the zinc foil during the charge and discharge process. In this way, the direct contact between zinc and the electrolyte is avoided, which helps to solve problems such as dendrites, corrosion and hydrogen evolution of the zinc negative electrode. Compared with the traditional aqueous zinc-ion battery, the electrochemical performance of this aqueous zinc-ion battery is enhanced.

The invention relates to the field of solid hydrogen storage, in particular to a nanocrystalline vanadium-based hydrogen storage material as well as a preparation method and application thereof. The invention provides a method for simply preparing a nanocrystalline vanadium-based hydrogen storage material by a mechanical alloying method, and the preparation method comprises the following steps: 1, crushing vanadium: carrying out vacuum heat treatment on a vanadium block, and adding hydrogen pressure at room temperature to carry out hydrogenation crushing treatment; and 2, in an inert atmosphere, carrying out mixing and ball-milling reaction with an oxide to prepare the nanocrystalline vanadium-based hydrogen storage material. The nanocrystalline vanadium-based material is directly prepared in a ball milling mode, the preparation process and operation are simple, the production period is short, energy consumption is low, and the method is suitable for large-scale production. The nanocrystalline vanadium-based material only contains vanadium and hydrogen, the reversible hydrogen storage capacity is 1.6 wt% at the temperature of 50 DEG C, the hydrogen desorption platform pressure is 6.3 bar, and the capacity retention rate is 96% after 10 times of hydrogen absorption and desorption cycles at the temperature of 30 DEG C.

The invention discloses a preparation method of a superfine WC-Co hard alloy. 89.8-90% wt of superfine tungsten carbide, 9% wt of superfine Co powder and 1-1.2% wt of composite additive chromium carbide and vanadium carbide are adopted; wherein the weight ratio of chromium carbide to vanadium carbide is 1 / 2; ball-milling the raw materials to obtain a mixture; and the pressed blank is subjected to a specific oscillation pressure and rapid cooling sintering process, the contact form and interface state among particles are improved, the density of the hard alloy is improved, WC grain growth is inhibited, flowing of binding phase Co is promoted, the structure and mechanical properties of the alloy are remarkably improved, and the nanocrystalline WC-Co hard alloy with high strength and high density is obtained.

The invention relates to the technical field of preparation of an electrolyte for a vanadium redox flow battery, in particular to a reduction method of an alkaline vanadium-containing solution during short-process preparation of a vanadium electrolyte. The reduction method comprises the following steps: (1) adding a reducing agent sodium sulfite into an alkaline vanadium-containing solution and dissolving; and (2) acid is added into the solution obtained after dissolving in the step (1), the pH is adjusted, a reduction reaction is conducted, and vanadium is reduced to be tetravalent. The method provided by the invention effectively solves the problem of vanadium loss caused by precipitation generated in the sequential operation process of acidification and reduction of the alkaline vanadium-containing solution in the prior art, and meanwhile, the method provided by the invention is easy for engineering implementation.

The invention discloses a selective desiliconization method for alkaline vanadium liquid. According to the process, magnesium-aluminum hydrotalcite prepared in advance is introduced into the alkaline vanadium liquid, the pH does not need to be regulated and controlled, silicon can be selectively adsorbed, desilicication slag is desorbed and then recycled as a desilicication agent, and a sodium silicate-containing solution can be used for preparing a water glass product. According to the method for deeply adsorbing silicon in the alkaline vanadium liquid by adopting the magnesium-aluminum hydrotalcite, various conditions of an existing process are not greatly changed, disturbance to existing industrial production is small, meanwhile, the problems that the desilicication limit of the alkaline vanadium liquid is insufficient and vanadium loss is high at present can be solved, silicon in the alkaline vanadium liquid can be reduced to 30 mg / L or below, and the requirements of vanadium products are met.

The invention discloses a KTP type sodium-rich phosphate positive electrode material and a preparation method and application thereof, the chemical formula of the phosphate positive electrode material is NaxV1-yTyPO4F1-zOz, 1 < x < = 2, 0 < y < = 1, and 0 < = z < = 1; the preparation method of the material comprises the following steps: adding a vanadium source, a T source, a phosphorus source and a fluorine source in a stoichiometric ratio into a reaction kettle containing a reaction solvent, adding an ammonium source to keep the pH value to be 6-10, maintaining the temperature to be 120-250 DEG C, and reacting for 2-24 hours; naturally cooling, and washing with clear water to obtain a (NH4) xV < 1-y > TyPO4F < 1-z > Oz precursor; the preparation method comprises the following steps: fully grinding an excessive sodium source and a (NH4) xV < 1-y > TyPO4F < 1-z > Oz precursor, carrying out Na < + > / NH4 < + > molten salt exchange in a tubular furnace at 60-400 DEG C for 1-48 hours, introducing inert gas during reaction, and washing an obtained product with a washing solvent after the reaction is finished to remove the excessive sodium source; and drying in a drying oven at 50-250 DEG C for 1-30 hours to obtain the KTP type sodium-rich phosphate positive electrode material. By utilizing the induction effect of KTP configuration on V-O or T-O bonds, the voltage of V and T transition metal related redox couple is increased, and the energy density is improved.

The invention provides a coding metasurface with terahertz wave absorption and reflection functions and application, the coding metasurface comprises at least one coding unit arranged in an array, each coding unit comprises a top resonance layer, a dielectric layer and a metal reflection layer which are sequentially arranged from top to bottom, the top resonance layer comprises a graphene resonance layer and a vanadium dioxide phase change layer, and the dielectric layer comprises a dielectric layer and a metal reflection layer. The graphene resonance layer comprises square graphene, the vanadium dioxide phase change layer comprises a square vanadium dioxide outer ring and a vanadium dioxide strip embedded in the vanadium dioxide outer ring, the vanadium dioxide outer ring is located on the inner side of the graphene, and the square edge of the vanadium dioxide outer ring and the square edge of the graphene are arranged in parallel at an interval; wherein the vanadium dioxide strips are arranged at the diagonal positions of the vanadium dioxide outer ring and are arranged at intervals with the vanadium dioxide outer ring, the advantages of a wave-absorbing metasurface and a reflection coding metasurface are integrated, and the signal generation power of 6G communication is greatly optimized.

The invention discloses a carbon-coated high-entropy NASICON positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of sodium ion battery electrode materials. The method comprises the following steps: adding a vanadium source, a carbon source, a chromium source, an iron source, a manganese source, a zinc source, an aluminum source, a sodium source and a phosphorus source into deionized water, heating and dissolving to obtain a clear solution; and heating the solution to form gel, and then carrying out the steps of vacuum drying, crushing, pre-sintering, calcining and the like to obtain the Na3V2-y (CrFeMnZnAl) y (PO4) 3 / C (0 < y < 1) positive electrode material. The positive electrode material has a stable NASICON structure, and the morphology is of a scaly structure. According to the invention, a high-entropy doping mode is adopted to replace part of vanadium sites in sodium vanadium phosphate, and the conductivity of the positive electrode material is improved through carbon coating, so that the prepared positive electrode material has relatively good cycling stability and rate capability.

The invention discloses a flowing type vanadium-based electric fuel energy storage and supply system which comprises an electric pile reaction module, an electrolyte driving module and a medium storage module, and the electric pile reaction module comprises an oxygen evolution reaction flowing unit, a vanadium electrolyte flowing unit and an oxygen reduction reaction flowing unit which are arranged adjacently in pairs; a first flow field plate in the oxygen evolution reaction flow unit is provided with a bionic dendritic interdigital first flow channel; a second flow field plate in the vanadium electrolyte flowing unit is provided with a bidirectional spiral interdigital second flow channel; a third flow field plate in the oxygen reduction reaction flow unit is provided with a third multi-stage fractal interdigital flow channel; the medium storage module comprises a vanadium electrolyte storage tank and a reaction medium storage tank, the vanadium electrolyte storage tank and the reaction medium storage tank are arranged on the two opposite sides of the galvanic pile reaction module, the vanadium electrolyte storage tank is connected with the second flow field plate, and the reaction medium storage tank is connected with the second flow field plate and the third flow field plate. According to the system, the integration level of the system is improved on the basis of reducing the cost.

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at a pressure less than atmospheric pressure; a seal provided between at least the first substrate and the second substrate, the seal comprising a first seal layer; wherein the first seal layer comprises tellurium oxide and vanadium oxide; wherein the first seal layer comprises, on a wt. %, more tellurium oxide than vanadium oxide, and has a density of from about 2.8-4.0 g / cm3.

The invention relates to a composite additive for an all-vanadium redox flow battery electrolyte and a preparation method and application thereof, the composite additive comprises an organic ligand, organic sulfonate, phosphate and halide, and the molar ratio of the organic ligand to the organic sulfonate to the phosphate to the halide is 1: (1-2): (1-2): (1-10). Through the synergistic effect of the four added components, the precipitation problem of divalent vanadium ions under a low-temperature condition and pentavalent vanadium ions under a high-temperature condition is remarkably improved, the high-temperature stability of the positive electrode electrolyte and the low-temperature stability of the negative electrode electrolyte of the all-vanadium redox flow battery are effectively improved, the service life of the battery is prolonged, and the service life of the battery is prolonged. Meanwhile, through the synergistic effect of the four effective components, the use amount of the additive is reduced, and the use cost of the additive is reduced.

The invention discloses a vanadium dioxide-based spin coupling and decoupling dynamic switching metasurface. The unit structure of the metasurface is divided into three reflecting layers; a dielectric layer; the metal layer is of an S-shaped structure and comprises a rectangle in the middle and circular arcs at the two ends, the rectangle is made of gold, and the circular arcs are made of vanadium dioxide; when vanadium dioxide is in a metal state, adjusting an opening angle alpha between the arc and the rectangle and a rotation angle theta of the metal layer around an X axis, and realizing decoupling of left-handed polarized light and right-handed polarized light through combination of a PB phase and a transmission phase; when vanadium dioxide is in an insulated state, the PB phase is regulated and controlled only by rotating the angle theta, and coupling of left-handed polarized light and right-handed polarized light is achieved. Compared with other coding metasurfaces, the modulation mode is simpler, the design is more flexible, the functions are more diversified, the defect that the function of the metasurface is fixed is overcome, the coupling characteristic and the decoupling characteristic of left-handed and right-handed polarized light are integrated together, and the application prospect of a coding metasurface device is expanded.

The invention belongs to the technical field of vanadium enrichment mechanisms of phosphorus vanadium ores, and discloses a research method of a vanadium enrichment mechanism in a diagenetic stage of phosphorus vanadium ores, which comprises the following steps: S1, sample collection and treatment; s2, rock ore identification and mineral composition analysis; s3, analyzing the occurrence state and microcell morphology of vanadium; s4, performing geochemical analysis on the whole rock; s5, in-situ microcell geochemical analysis is carried out; s6, phosphorus nodule analysis; s7, comprehensive analysis and mineralization model establishment; according to the method, mineralogy, total rock geochemistry, micro-area surface scanning and other multi-scale and multi-means research methods are comprehensively utilized, and the vanadium occurrence state, the ore-forming fluid evolution and the phosphorus-vanadium coupling relation are finely described; in-situ microcell geochemical analysis is introduced into phosphorus nodule analysis, the internal structure, the growth sequence and element distribution of the phosphorus nodule are directly revealed, obvious frontier and systematicness are achieved, and reliable theoretical support is provided for accurate exploration of vanadium ore resources and green and efficient dressing and smelting process research and development.

The invention relates to the field of redox flow batteries, in particular to a battery health state detection method and system in an all-vanadium redox flow battery energy storage system. The method comprises the following steps: firstly, connecting an SOH reference battery into an all-vanadium redox flow battery energy storage system, connecting electrolyte for operation, then collecting the cathode voltage of the SOH reference battery, and calculating a reaction quotient corresponding to the collected cathode voltage through a Nernst equation, and finally, calculating the concentration of vanadium ions generated by the oxidation-reduction reaction in the SOH reference battery cathode electrolyte according to the reaction quotient, and calculating the health state of the battery. The system comprises an SOH reference battery, a data acquisition unit and a calculation unit. The method can effectively solve the problems of complex calculation and low accuracy of the battery health state in the all-vanadium redox flow battery energy storage system, and realizes accurate calculation of the battery health state in the all-vanadium redox flow battery energy storage system.

The invention discloses a method for detecting the concentration of vanadium ions in an electrolyte of an all-vanadium redox flow battery, and relates to the technical field of batteries. The method for detecting the concentration of vanadium ions in the electrolyte of the all-vanadium redox flow battery comprises the following steps: preparing trivalent and tetravalent vanadium ion reference solutions and trivalent and tetravalent vanadium ion standard solutions with different concentrations; performing baseline correction by using a high-concentration reference solution, setting an absorbance difference value between a corresponding reference cell and a sample cell as 0, and obtaining a trivalent vanadium ion standard curve and a tetravalent vanadium ion standard curve by using standard solutions with different concentration gradients; and detecting the absorbance difference value of the electrolyte stock solution to be detected, and substituting the absorbance difference value into the corresponding standard curve to calculate the vanadium ion concentration. According to the present invention, the detection can be performed without diluting the electrolyte stock solution during the detection, the interference of the adjacent valence vanadium ions is not easily generated, and the detection result is accurate.

The invention belongs to the field of chemical engineering, and relates to a preparation method of a high-chroma bismuth vanadate pigment for a coating, which comprises the following steps: mixing a titanium-based ion sieve with an acidic vanadium leachate, filtering after the reaction is completed to obtain a first filtrate, adding mercaptoacetic acid into the first filtrate, and filtering after the reaction is completed to obtain a second filtrate; preparing a bismuth salt solution containing yttrium ions and zirconium ions, mixing the bismuth salt solution with the second filtrate, adjusting the pH value to be in linear gradient change from acidity to neutrality, heating to a first temperature at a set heating rate, aging, centrifuging and drying to obtain a precursor; and calcining the precursor at a second temperature to obtain the bismuth vanadate pigment. According to the method, the acid vanadium leaching solution is used as a raw material, and the bismuth vanadate pigment with high chromaticity and chemical stability is obtained while the production cost is reduced through an innovative ion sieve purification technology and lattice stabilization doping, so that the method has obvious economic benefits.

The invention belongs to the field of functional nano materials, and relates to a method for large-scale preparation of monoclinic phase vanadium dioxide nano powder, a heat insulation film and application of the heat insulation film, and large-scale preparation of the monoclinic phase vanadium dioxide nano powder is successfully achieved by combining a coprecipitation method with low-temperature calcination. The obtained product has excellent size uniformity (the average particle size is 65 + / -10 nm) and an adjustable phase change characteristic (61-68 DEG C). The polymer-based composite film prepared based on the nano powder shows excellent optical performance, and the method has the advantages of mild reaction conditions (less than or equal to 600 DEG C), controllable product morphology and phase transition temperature and the like, and provides a reliable solution for industrial production of nano functional materials for intelligent windows.

The invention discloses a preparation method of 5N specified-grade high-purity vanadium pentoxide, which comprises the following steps: step S1, taking high-purity ammonium metavanadate as a raw material, mixing the raw material with pure water in proportion, heating for dissolving, and cooling to obtain an ammonium metavanadate solution; s2, enabling the ammonium metavanadate solution to pass through a resin column for adsorption, and collecting column passing liquid; s3, carrying out vacuum concentration on the column passing liquid, cooling and crystallizing the obtained concentrated liquid, and carrying out suction filtration to obtain primary crystals; s4, mixing the primary crystal with pure water in proportion, heating, filtering, cooling filtrate, crystallizing, filtering and washing with water to obtain a secondary crystal; step S5, repeating crystallization operation for 1-3 times to obtain recrystallized ammonium metavanadate; and step S6, putting ammonium metavanadate into a porcelain baking tray, putting the porcelain baking tray into a calcining furnace, vacuumizing, calcining and cooling to obtain a 5N specified-grade high-purity vanadium pentoxide product. The method has the characteristics of simple principle, convenience in operation, high reliability and the like, and the purity of vanadium pentoxide is remarkably improved.