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A kind of preparation method and application of polymer polymerization catalyst

A polymer polymerization and catalyst technology, which is applied in the application of the catalyst and the preparation of polymer polymerization catalysts, can solve the problems that cannot fully meet the requirements, and achieve the effects of low production cost, mild reaction conditions and good stability

Active Publication Date: 2017-01-04
SUZHOU XIANGYUAN SPEICAL FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in actual production, a single titanate catalyst often cannot fully meet the requirements and needs to be compounded with other compounds to form a composite catalyst.

Method used

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  • A kind of preparation method and application of polymer polymerization catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Add 0.55 mol of 1,4-butanediol to the flask, add 0.015 mol of manganese acetate into it, then add 0.067 mol of isopropyl titanate, stir continuously, react at 230°C for 1 hour, then add octanoic acid suboxide 5g of tin, after continuous stirring for 2 hours, 3g of calcium aluminate was added, and the stirring was continued for 2 hours to obtain Catalyst 1.

Embodiment 2

[0019] Add 0.55 mol of 1,4-butanediol to the flask, add 0.015 mol of manganese acetate into it, then add 0.067 mol of isopropyl titanate, stir continuously, react at 220 for 1 hour, then add stannous octoate After stirring continuously for 2 hours, 4 g of calcium aluminate was added, and stirring was continued for 2 hours to obtain catalyst 2.

Embodiment 3

[0021] Add 0.55mol of 1,4-butanediol to the flask, add 0.015mol of manganese acetate into it, then add 0.067mol of isopropyl titanate, stir continuously, react at 220 for 1 hour, then add stannous octoate After stirring continuously for 2 hours, 5 g of calcium aluminate was added, and stirring was continued for 2 hours to obtain catalyst 3.

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Abstract

The invention discloses a preparation method and application of a macromolecular polymerization catalyst. The preparation method comprises the following steps: adding manganese acetate to 1,4-butanediol, mixing, stirring, adding titanium isopropoxide, continuously stirring for 0.5-1 hour at 220-240 DEG C, adding stannous octoate, and continuously stirring for 1-2 hours to obtain the catalyst. The preparation method of the macromolecular polymerization catalyst is simple, easy to operate and mild in the reaction conditions and can be put into the continuous industrial production favorably.

Description

technical field [0001] The invention belongs to the field of macromolecular synthesis, and relates to a preparation method of a macromolecule polymerization catalyst, and also relates to the application of the catalyst. Background technique [0002] High-molecular polymers refer to high-molecular-weight (usually up to 10-106) compounds composed of many identical and simple structural units linked repeatedly through covalent bonds. Polymers polymerized from one monomer are called homopolymers, such as polyvinyl chloride, polyethylene, etc. Polymers formed by the copolymerization of two or more monomers are called copolymers, such as vinyl chloride-vinyl acetate copolymers. A polymer catalyst is a polymer that catalyzes a chemical reaction. Enzymes in living organisms are natural polymer catalysts with high activity and high selectivity, but because they are water-soluble, their industrial applications are limited. Therefore, immobilized enzymes that are insoluble in water h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/85C08G63/16
Inventor 周建颜玉荣
Owner SUZHOU XIANGYUAN SPEICAL FINE CHEM
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