Acrylic resin emulsion for hairdressing agents, hairdressing agent comprising same, and hairdressing method
A technology of acrylic resin and hair conditioner, which is applied in the field of acrylic resin emulsion, which can solve the problem that hair can no longer be styled, and achieve the effect of excellent redispersibility
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Embodiment 1
[0143]
[0144] In a reaction tank made of SUS equipped with cooling pipes and stirring blades, a PVA-based resin containing a 1,2-diol structural unit in the side chain (average degree of saponification 99 mol%, average degree of polymerization 300, side chain 1,2- The content of diol structural unit (8 mol% / Nippon Synthetic Chemical Industry Co., Ltd.) 10 parts, 0.2 parts of sodium bisulfite and 0.4 parts of sodium carbonate trihydrate are completely dissolved in deionized water (92 parts), and the temperature is raised to 75°C.
[0145] Prepare in advance a substance emulsified with 77 parts of deionized water, unmodified PVA-based resin (manufactured by Nippon Synthetic Chemical Industry Co., Ltd.; trade name "GOHSENOL GL05"), and 100 parts of 2-ethylhexyl acrylate ( i), and 2.7 parts of 10% APS (ammonium persulfate) aqueous solution (ii), first add 10% of (i) and 30% of (ii) to the reaction tank, and make it react for 45 minutes.
[0146] Next, the remaining 90% of (i)...
Embodiment 2
[0149]
[0150] In embodiment 1, 100 parts of 2-ethylhexyl acrylate are changed to 90 parts of 2-ethylhexyl acrylate and 10 parts of methyl methacrylate, and then as unmodified PVA resin, "GOHSENOL GL05" (trade name , Nippon Synthetic Chemical Industry Co., Ltd.) was changed to the product name "GOHSENOL EG05" produced by Nippon Synthetic Chemical Industry Co., Ltd., except that it was carried out in the same manner as Example 1 to obtain an acrylic resin emulsion (2) (non-volatile component 43 %; viscosity 160 mPa·s (B-type viscometer 12 rpm, 23°C); glass transition temperature (Tg) of acrylic resin = -60°C). The acrylic resin emulsion (2) is dispersed and stabilized.
Embodiment 3
[0151]
[0152]In Example 2, 0.3 parts of ethylene glycol dimethacrylate (manufactured by Mitsubish Rayon Co., Ltd.; trade name "ACRYESTER ED") was further added as an acrylic acid monomer, and the procedure was the same as in Example 2. This was carried out to obtain an acrylic resin emulsion (3) (44% non-volatile content; viscosity 210 mPa·s (B-type viscometer 12 rpm, 23° C.); glass transition temperature (Tg) of acrylic resin = -60° C.). The acrylic resin emulsion (3) is dispersed and stabilized.
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