Er<3+>/Ce<3+>/Yb<3+> tri-doped tellurate glass containing silver nano particles and preparation method thereof

A technology of tellurate glass and silver nanoparticles, which is applied in the field of glass and its preparation, to achieve the effects of increasing fluorescence emission intensity, improving luminous efficiency, and improving physical and chemical stability

Active Publication Date: 2016-07-13
NINGBO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, at present, there are few studies on metal nanoparticles for Er-doped 3+ Report on the Enhancement of Fluorescence of Tellurite Glass in 1.55μm Near Infrared Band

Method used

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  • Er&lt;3+&gt;/Ce&lt;3+&gt;/Yb&lt;3+&gt; tri-doped tellurate glass containing silver nano particles and preparation method thereof
  • Er&lt;3+&gt;/Ce&lt;3+&gt;/Yb&lt;3+&gt; tri-doped tellurate glass containing silver nano particles and preparation method thereof
  • Er&lt;3+&gt;/Ce&lt;3+&gt;/Yb&lt;3+&gt; tri-doped tellurate glass containing silver nano particles and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] A kind of Er containing silver nanoparticles proposed in this embodiment 3+ / C 3+ / Yb 3+ Tri-doped tellurite glass, the mole percent composition of which is:

[0032]

[0033]

[0034] In this particular example, TeO 2 、Er 2 o 3 and Yb 2 o 3 The mass percent purity is 99.99%, Bi 2 o 3 , ZnO and AgNO 3 The mass percent purity is 99.9%.

[0035] In this particular example, Ce 2 o 3 by CE 2 (CO 3 ) 3 converted to get, Ce 2 (CO 3 ) 3 The mass percent purity is 99.99%; Na 2 O by Na 2 CO 3 Converted to get, Na 2 CO 3 The mass percent purity is 99.9%.

[0036] Er of the above-mentioned silver-containing nanoparticles 3+ / C 3+ / Yb 3+ The specific steps of the preparation method of the three-doped tellurite glass are as follows:

[0037] ① Select the raw material formula according to the following mole percentage components of tellurite glass, then calculate the weight percentage of each raw material according to the total amount of tellurite gla...

Embodiment 2

[0050] A kind of Er containing silver nanoparticles proposed in this embodiment 3+ / C 3+ / Yb 3+ Tri-doped tellurite glass, the mole percent composition of which is:

[0051]

[0052]

[0053] In this particular example, TeO 2 、Er 2 o 3 and Yb 2 o 3 The mass percent purity is 99.99%, Bi 2 o 3 , ZnO and AgNO 3 The mass percent purity is 99.9%.

[0054] In this particular example, Ce 2 o 3 by CE 2 (CO 3 ) 3 converted to get, Ce 2 (CO 3 ) 3 The mass percent purity is 99.99%; Na 2 O by Na 2 CO 3 Converted to get, Na 2 CO 3 The mass percent purity is 99.9%.

[0055] Er of the above-mentioned silver-containing nanoparticles 3+ / C 3+ / Yb 3+ The specific steps of the preparation method of the three-doped tellurite glass are as follows:

[0056] ① Select the raw material formula according to the following mole percentage components of tellurite glass, then calculate the weight percentage of each raw material according to the total amount of tellurite gla...

Embodiment 3

[0069] A kind of Er containing silver nanoparticles proposed in this embodiment 3+ / C 3+ / Yb 3+ Tri-doped tellurite glass, the mole percent composition of which is:

[0070]

[0071] In this particular example, TeO 2 、Er 2 o 3 and Yb 2 o 3 The mass percent purity is 99.99%, Bi 2 o 3 , ZnO and AgNO 3 The mass percent purity is 99.9%.

[0072] In this particular example, Ce 2 o 3 by CE 2 (CO 3 ) 3 converted to get, Ce 2 (CO 3 ) 3 The mass percent purity is 99.99%; Na 2 O by Na 2 CO 3 Converted to get, Na 2 CO 3 The mass percent purity is 99.9%.

[0073] Er of the above-mentioned silver-containing nanoparticles 3+ / C 3+ / Yb 3+ The specific steps of the preparation method of the three-doped tellurite glass are as follows:

[0074] ① Select the raw material formula according to the following mole percentage components of tellurite glass, then calculate the weight percentage of each raw material according to the total amount of tellurite glass to be pre...

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Abstract

The invention discloses Er<3+> / Ce<3+> / Yb<3+> tri-doped tellurate glass containing silver nano particles and a preparation method thereof. The glass consists of the following components in percentage by mole: 65-75mol% of TeO2, 5-10mol% of Bi2O3, 10-20mol% of ZnO, 5-10mol% of Na2O, 0.1-1.0mol% of Er2O3, 0.1-1.0mol% of Ce2O3, 0.4-2.0mol% of Yb2O3 and 0.1-1.0mol% of AgNO3. The tellurate glass has the following advantages that by adopting tellurium oxide as a main component and adding bismuth oxide, zinc oxide and sodium oxide, the forming ability and physical-chemical stability of the glass are improved; due to the tri-doping way of rare earth Er<3+>, Ce<3+> and Yb<3+> ions, the sensitization among the rare earth ions is sufficiently utilized to improve the luminous efficiency of the rare earth Er<3+> ions under a commercial 980nm-wavelength semiconductor laser diode pump; and the fluorescence emission intensity of the doping Er<3+> ions in the 1.55mu m near infrared waveband is enhanced by the local field enhancement effect of the silver nano particles.

Description

technical field [0001] The present invention relates to a kind of glass that is used for optical fiber amplifier and its preparation technology, especially relate to a kind of near-infrared band fluorescence enhancement containing silver nano particle Er 3+ / C 3+ / Yb 3+ Triple-doped tellurite glasses and methods of making them. Background technique [0002] Erbium-doped (Er 3+ ) Fiber Amplifier (EDFA, Erbium-doped Optical Fiber Amplifier) ​​is an indispensable optical signal amplification device in the current Dense Wavelength Division Multiplexing (DWDM, DenseWavelengthDivisionMultiplexing) system and future high-speed systems and all-optical networks. With the widespread application of the new generation of information technology represented by big data, cloud computing, Internet of Things, and mobile Internet, it is urgent to develop broadband optical fiber amplifiers with high signal gain that can work in the optical fiber communication window (1.2-1.7 μm). [0003] ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/12C03C4/12C03B25/00
CPCC03B25/00C03C3/12C03C4/12
Inventor 周亚训吴立波杨风景黄波周自忠程盼
Owner NINGBO UNIV
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