A kind of manufacturing method of spinning dope with memory function
A manufacturing method and technology of spinning dope, applied in spinning solution preparation, rayon manufacturing, textile and paper making, etc., can solve problems such as unsatisfactory results and lower production efficiency, and achieve good structural stability and smooth unwinding , the effect of low modulus
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Embodiment 1
[0031] A method for manufacturing a spinning dope with a memory function, comprising the following steps:
[0032] 1) Preparation of fiber-forming polymer solution: mix raw materials polytetramethylene ether glycol and 4,4-diphenylmethane diisocyanate, react at 75°C for 50 minutes, and prepare a prepolymer, in which 4,4-diphenyl The molar ratio of methyl methane diisocyanate to polytetramethylene ether glycol is (1.80~2.00): 1; after the prepolymerization is completed, N,N-dimethylacetamide solvent is added to the prepolymer to make a mass percentage A prepolymer solution with a concentration of 40%; pentamethylenediamine is added to the prepolymer solution to extend the chain, and after the chain extension, the N,N-dimethylacetamide solution of the fiber-forming polymer is obtained, and the amines account for The mass ratio of fiber polymer is 1.0%, and the mass percentage concentration of solution is 33%;
[0033] 2) Preparation of memory function slurry: including the foll...
Embodiment 2
[0048] A method for manufacturing a spinning dope with a memory function, comprising the following steps:
[0049]1) Preparation of fiber-forming polymer solution: mix raw materials polytetramethylene ether glycol and 4,4-diphenylmethane diisocyanate, react at 90°C for 90 minutes, and prepare a prepolymer, in which 4,4-diphenyl The molar ratio of methyl methane diisocyanate to polytetramethylene ether glycol is (1.80~2.00): 1; after the prepolymerization is completed, N,N-dimethylacetamide solvent is added to the prepolymer to make a mass percentage A prepolymer solution with a concentration of 50%; pentamethylenediamine is added to the prepolymer solution to extend the chain, and after the chain extension, the N,N-dimethylacetamide solution of the fiber-forming polymer is obtained, and the amines account for The mass ratio of fiber polymer is 2.0%, and the mass percentage concentration of solution is 35%;
[0050] 2) Preparation of memory function slurry: including the follo...
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