The invention discloses a metamifop and
butachlor-based composite herbicide for rice, belongs to the technical field of pesticides, and aims to solve the problems that the dosage of an existing herbicide is increased year by year and the
drug resistance of weeds is delayed. The composite herbicide is prepared from the following raw materials in parts by weight: 1 to 20 parts of metamifop, 20 to 60 parts of
butachlor, 5 to 30 parts of supramolecular
sol-gel, 1.5 to 16.5 parts of
methyl oleate, 5.5 to 15 parts of an emulsifier and 0 to 3.5 parts of organic
bentonite. According to the invention,
phthalic anhydride, N, N'-dimethyl- 1, 3-propanediamine and
pentaerythritol are utilized as raw materials to prepare tree-shaped
amide; four amino groups in the tree-shaped
amide are reacted with carboxyl groups in
adipic acid to form a hyperbranched supramolecule; and loading and slow release on metamifop and
butachlor in the supramolecule structure is performed due to existence of a special hydrophobic cavity in the supramolecule structure. The
pesticide application amount is reduced and the generation of
pesticide resistance of weeds is slowed down.