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31results about How to "Has shape memory properties" patented technology

Method for preparing poly(trimethylene terephthalate) fibre having shape memory characteristic

The invention discloses a preparation method of polytrimethylene terephthalate fiber with shape memory characteristics, including: firstly, selected polyester polymer is provided with at least 0.8dL/g of intrinsic viscosity and contains at least 85mol percent of polytrimethylene terephthalate, wherein, at least 85mol percent of the repeating unit is composed of three-methylene; secondly, the polyester polymer is melted and transported through a screw melting extruder, the melting body is metered through a metering pump and is extruded out through a spinneret, and as-spun fibers are drafted successively through a pair of drafting hot rollers after being cooled through lateral blowing; thirdly, the drafted fibers are introduced into a group of grouping roller stereotype boxes with steam; fourthly, tow is introduced into a winding head to be winded into mold. The fiber made through the invention has the advantages of good packaging appearance forming, good structural stability and soft handle. And with lower modulus, the fiber is still provided with good elasticity and tensile recoverability. The textiles made of the fiber which are produced through the process are provided with good shape memory characteristics.
Owner:方圆化纤有限公司

Low-cost and stable lithium battery silicon negative electrode and preparation method thereof

The invention provides a low-cost and stable lithium battery silicon negative electrode and a preparation method thereof. Silicon-based nanoparticles, liquid silicone rubber and ethylene-vinyl acetatecopolymer are uniformly mixed up according to a mass ratio of 10: 3: 1, and then are heated, melted and dispersed. In this way, silicon-based nanoparticles are uniformly dispersed in the melt. Afterthat, a curing agent, graphene powders and carbon fibers are added into the melt prefabricated in the step (1), and the mixture is ultrasonically dispersed to obtain a slurry. The slurry is coated onthe surface of a negative current collector, and then is cured at 80 DEG C for 2 hours. After that, the material is dried, slit and tabletted to obtain the lithium battery silicon negative electrode.According to the invention, nano silicon is directly dispersed in the deformation memory silicone rubber to prepare the silicon negative electrode. The system has self-repairing performance and shapememory performance at a certain temperature. The problem of silicon expansion fragmentation is well solved. The preparation process is greatly simplified, and the preparation cost is reduced. The defects that an existing technology for solving the problem that a silicon negative electrode is prone to expansion is complex and high in cost, and the size is increased after porosity is achieved are overcome.
Owner:CHENDU NEW KELI CHEM SCI CO LTD

Shape memory embedded double-layer metal grid conducting film and preparation method thereof

The invention provides a shape memory embedded double-layer metal grid conducting film and a preparation method thereof, which belong to the technical field of flexible photoelectrons. The preparationmethod for the shape memory embedded double-layer metal grid conducting film comprises the following steps of: preparing a grid template on the surface of a rigid substrate, depositing a double-layermetal film on the surface of the grid template, removing the grid template to obtain a double-layer metal grid protruding on the surface of the rigid substrate, and coating the surface of the rigid substrate with a shape memory polymer, and after curing, separating the rigid substrate from the double-layer metal grid wrapping the shape memory polymer to obtain the shape memory embedded double-layer metal grid conducting film. Compared with the prior art, the shape memory embedded double-layer metal grid conducting film prepared by the invention has good scratch resistance, bending stability,corrosion resistance, oxidation resistance and shape memory performance.
Owner:HARBIN INST OF TECH

Gas separation membrane having shape memory property

The invention discloses a gas separation membrane having a shape memory property; the gas separation membrane is prepared by the steps: firstly, forming a copolymerized linear oligomer from dianhydride 4,4'-(hexafluoroisopropylidene)diphthalic anhydride, diamine 4,4'-diaminodiphenyl ether and 2-(4-aminophenyl)-5-aminobenzoxazole, then carrying out a reaction of the copolymerized linear oligomer with 2,4,6-triaminopyrimidine gradually to form hyperbranched macromolecules, and finally, carrying out thermal imidization to obtain a hyperbranched polyimide membrane. The hyperbranched polyimide membrane has large specific surface area and can achieve gas adsorption; by adjusting the stiffness and flexibility of a structure of polyimide, the hyperbranched polyimide membrane has different adsorption characteristics on different gases, so as to achieve gas separation characteristics. In addition, the hyperbranched polyimide has obvious glass transition temperature, the transition can be used as a shape memory reversible phase, mutual entanglement of macromolecular chains and intermolecular strong interaction force in the polyimide structure can be used as a stationary phase, and thus the hyperbranched polyimide is endowed with the shape memory property.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Metamifop and butachlor-based composite herbicide for rice

The invention discloses a metamifop and butachlor-based composite herbicide for rice, belongs to the technical field of pesticides, and aims to solve the problems that the dosage of an existing herbicide is increased year by year and the drug resistance of weeds is delayed. The composite herbicide is prepared from the following raw materials in parts by weight: 1 to 20 parts of metamifop, 20 to 60 parts of butachlor, 5 to 30 parts of supramolecular sol-gel, 1.5 to 16.5 parts of methyl oleate, 5.5 to 15 parts of an emulsifier and 0 to 3.5 parts of organic bentonite. According to the invention, phthalic anhydride, N, N'-dimethyl- 1, 3-propanediamine and pentaerythritol are utilized as raw materials to prepare tree-shaped amide; four amino groups in the tree-shaped amide are reacted with carboxyl groups in adipic acid to form a hyperbranched supramolecule; and loading and slow release on metamifop and butachlor in the supramolecule structure is performed due to existence of a special hydrophobic cavity in the supramolecule structure. The pesticide application amount is reduced and the generation of pesticide resistance of weeds is slowed down.
Owner:安徽海日农业发展有限公司

Method for preparing poly(trimethylene terephthalate) fibre having shape memory characteristic

The invention discloses a preparation method of polytrimethylene terephthalate fiber with shape memory characteristics, including: firstly, selected polyester polymer is provided with at least 0.8dL / g of intrinsic viscosity and contains at least 85mol percent of polytrimethylene terephthalate, wherein, at least 85mol percent of the repeating unit is composed of three-methylene; secondly, the polyester polymer is melted and transported through a screw melting extruder, the melting body is metered through a metering pump and is extruded out through a spinneret, and as-spun fibers are drafted successively through a pair of drafting hot rollers after being cooled through lateral blowing; thirdly, the drafted fibers are introduced into a group of grouping roller stereotype boxes with steam; fourthly, tow is introduced into a winding head to be winded into mold. The fiber made through the invention has the advantages of good packaging appearance forming, good structural stability and soft handle. And with lower modulus, the fiber is still provided with good elasticity and tensile recoverability. The textiles made of the fiber which are produced through the process are provided with goodshape memory characteristics.
Owner:方圆化纤有限公司

Thermally reversible crosslinked polyurethane containing dicyclopentadiene crosslinked bridge, preparation method and application thereof

ActiveCN110128618BEnables repeated reprocessingEnables thermoplastic processingPolymer scienceCross linker
The invention provides thermally reversible crosslinked polyurethane containing dicyclopentadiene crosslinking bridged bonds, and a preparation method and applications thereof. Dicyclopentadiene dicarboxylic acid and polyisocyanate (I) carry out reactions to generate a terminal isocyanate component, which contains a dicyclopentadiene structure and is taken as a crosslinking agent, and the terminalisocyanate component and a terminal hydroxyl component carry out reactions to form a crosslinked polyurethane network. By introducing dicyclopentadiene bridged bonds into polyurethane, at a high temperature, bridged bonds are broken; at a low temperature, bridged bonds are formed again; and repeated processing of chemical crosslinking type polyurethane is realized. The primary reverse Diels-Alderreaction temperature of dicyclopentadiene bridged bonds is 170 DEG C; and dicyclopentadiene bridged bonds are introduced into polyurethane to realized thermoplastic processing of crosslinking type polyurethane in a temperature range of 170 to 210 DEG C. The prepared thermally reversible polyurethane has an excellent repeated processing property, and still has good mechanical properties after manytimes of processing and moulding.
Owner:BEIJING UNIV OF CHEM TECH +1

A gas separation membrane with shape memory properties

The invention discloses a gas separation membrane having a shape memory property; the gas separation membrane is prepared by the steps: firstly, forming a copolymerized linear oligomer from dianhydride 4,4'-(hexafluoroisopropylidene)diphthalic anhydride, diamine 4,4'-diaminodiphenyl ether and 2-(4-aminophenyl)-5-aminobenzoxazole, then carrying out a reaction of the copolymerized linear oligomer with 2,4,6-triaminopyrimidine gradually to form hyperbranched macromolecules, and finally, carrying out thermal imidization to obtain a hyperbranched polyimide membrane. The hyperbranched polyimide membrane has large specific surface area and can achieve gas adsorption; by adjusting the stiffness and flexibility of a structure of polyimide, the hyperbranched polyimide membrane has different adsorption characteristics on different gases, so as to achieve gas separation characteristics. In addition, the hyperbranched polyimide has obvious glass transition temperature, the transition can be used as a shape memory reversible phase, mutual entanglement of macromolecular chains and intermolecular strong interaction force in the polyimide structure can be used as a stationary phase, and thus the hyperbranched polyimide is endowed with the shape memory property.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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