Manufacturing method of polarizer
A manufacturing method and polarizer technology, applied in the direction of instruments, optics, polarizing elements, etc., can solve the problems of uneven content of dichroic substances, uneven phase difference, uneven dyeing, etc., and achieve less uneven dyeing and positive The effect of high cross-b value and excellent color sense
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Embodiment 1
[0104] A transparent unstretched polyvinyl alcohol film (PE60, average polymerization degree of 2400, KURARAY company) with a length and width of 100 cm, a thickness of 30 μm, and a degree of saponification of 99.9% or more was placed in water (deionized water) at 25°C. After soaking for 1 minute and 20 seconds to make it swell, immerse in a 30°C dyeing aqueous solution containing 1.25mM / L iodine, 1.25% by weight potassium iodide, and 0.3% by weight boric acid for 2 minutes and 30 seconds for dyeing. At this time, in the swelling step and the dyeing step, the stretching ratios of 1.56 times and 1.64 times were stretched respectively, and the cumulative stretching ratio up to the dyeing tank (that is, the stretching ratio of the swelling step and the stretching ratio of the dyeing step Stretching was carried out in such a way that the product of the stretching ratio reached 2.56 times.
[0105] Next, immerse in a cross-linking aqueous solution at 59°C containing 11% by weight o...
Embodiment 2~16 and comparative example 1~5
[0109] A polarizer was manufactured in the same manner as in Example 1 except that the preheat treatment and drying conditions shown in Table 1 below were changed.
[0110] Table 1
[0111]
experiment example
[0113] 1. Determination of transmittance and orthogonal b
[0114] The polarizers produced in Examples and Comparative Examples were cut into a size of 4 cm×4 cm, and the transmittance and cross b were measured using an ultraviolet-visible ray spectrometer (V-7100, JASC Corporation). Usually, when the orthogonal b value is -1.0 or less, uneven dyeing is observed.
[0115] 2. Determination of degree of polarization
[0116] The polarizers manufactured in Examples and Comparative Examples were cut into a size of 4 cm×4 cm, and the transmittance was measured using an ultraviolet-visible ray spectrometer (V-7100, JASC Corporation). At this time, the degree of polarization is defined by Mathematical Expression 1 below.
[0117] [mathematical formula 1]
[0118] Degree of polarization (P) = [(T 1 -T 2 ) / (T 1 +T 2 )] 1 / 2
[0119] (where, T 1 It refers to the parallel transmittance obtained when a pair of polarizers are arranged in a state in which the absorption axes are pa...
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