Preparation method of surface of anti-drag copper

A technology of copper surface and pure copper, which is applied in the field of preparation of drag-reducing copper surface, can solve problems such as the difficulty of producing drag-reducing copper surface, and achieve the effect of improving service life and reducing frictional resistance

Inactive Publication Date: 2017-09-15
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] In view of the above-mentioned shortcomings of the prior art, the purpose of the present invention is to provide a method for preparing a lotus leaf-like micro-nano multi-level structure drag-reducing copper surface, which is used to solve the problem that the drag-reducing copper surface is difficult to produce in the prior art

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  • Preparation method of surface of anti-drag copper
  • Preparation method of surface of anti-drag copper
  • Preparation method of surface of anti-drag copper

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preparation example Construction

[0035] The invention provides a method for preparing a drag-reducing copper surface, which comprises the following steps:

[0036] 1) Pretreating pure copper or a copper-containing alloy to form a substrate 1. The copper content in the pure copper is more than 99.9%, and the copper content in the copper-containing alloy is more than 80%;

[0037] 2) Copper plating on the first substrate, specifically: the first substrate is immersed in an electroless plating solution containing copper elements for chemical deposition, and after the reaction is completed, the second substrate is formed;

[0038] 3) Nickel plating on the substrate 2, specifically: the prepared substrate 2 is used as the cathode, and the pure nickel plate is used as the anode, immersed in the electroplating solution for electrochemical deposition, and after the reaction is completed, nanometer-sized papillae are formed. Level villi crystal structure, which forms the base three;

[0039] 4) Modification, immersin...

specific Embodiment 1

[0046] 1) Metallographic grinding of pure copper or copper-containing alloys with silicon carbide sandpaper of 200 mesh to 2000 mesh, and ultrasonic cleaning in acetone;

[0047] 2) Use 50g / LNa again 3 PO 4 12H 2 O, 50g / L NaOH and 5g / L NaOH 2 SiO 3 The mixed solution is washed with alkali at room temperature for one minute to remove the oxide content of pure copper or copper-containing alloys, such as grease,

[0048] 3) pickling again with 10% H2SO4 solution, the pickling time is 10s, and drying in cold air to obtain the above-mentioned substrate 1; the substrate 1 is the substrate copper sheet, and its size is: 25mm×25mm×0.3mm;

[0049] 4) Activate with 0.001mol / L palladium chloride solution for 1min;

[0050] 5) Plating copper on the above-mentioned substrate copper sheet, specifically: immersing substrate 1 in an electroless plating solution containing copper elements for chemical deposition, after the reaction is completed, forming substrate 2 with a micron-scale pap...

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Abstract

The invention provides a preparation method of the surface of anti-drag copper. The method comprises the following steps that (1) pure copper or a copper-containing alloy is subjected to pre-treatment, and a first substrate is formed; (2) copper plating is conducted on the first substrate, specifically, the substrate is immersed in chemical plating liquid to conduct chemical sedimentation, and after a reaction is completed, a second substrate is formed; (3) nickel plating is conducted on the second substrate, specifically, the prepared second substrate serves as a cathode, a pure nickel plate serves as an anode, the prepared second substrate and the pure nickel plate are immersed in electroplating liquid to conduct electrochemical sedimentation, and after a reaction is completed, a third substrate is formed; and (4) modifying is conducted, the third substrate is immersed in organic molecule liquid with low surface energy, and the anti-drag copper is obtained. The copper prepared through the preparation method is provided with a super-hydrophobic surface similar to a lotus leaf, frictional drag is small, and production and preparation of the anti-drag copper are convenient.

Description

technical field [0001] The invention relates to the technical field of processing metal materials, in particular to a method for preparing a drag-reducing copper surface. Background technique [0002] As an important engineering metal material, brass is often used to manufacture condensers, water pipes, and air-conditioning internal and external units because of its good mechanical properties, thermoplasticity, machinability, easy welding, good electrical and thermal conductivity, and low price. Connect pipes, radiators, pins, conduits and other components. However, the surface energy of copper is high, and it is easy to absorb moisture in the air to cause corrosion and cracking, which affects the performance and service life of the product. [0003] In the 1980s, botanists Barthlott and Neihuis of the University of Bonn in Germany found that there were micron-scale protrusions and waxy tissue structures on the surface of the lotus leaf through observation of the surface st...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C23C18/16C23C28/02C23C18/40C25D3/12
CPCC23C18/1653C23C18/1689C23C18/40C23C28/023C25D3/12
Inventor卢艳魏青
OwnerWUHAN UNIV OF SCI & TECH