Decorative sheet and manufacturing method thereof
A manufacturing method and technology of decorative sheets, which are applied in the directions of decorations, chemical instruments and methods, transportation and packaging, etc., can solve problems such as poor appearance, and achieve excellent elongation and excellent embossing maintenance.
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Embodiment 1
[0140] The base material was prepared by mixing and stirring 100 parts by weight of acrylonitrile-butadiene-styrene, 20 parts by weight of acrylic impact reinforcing material, 1 part by weight of lubricant, 1 part by weight of antioxidant and 1 part by weight of pigment Layer-Forming Composition Next, a substrate layer having a thickness of 200 μm was formed by using the above-mentioned composition for substrate layer formation by a rolling method.
[0141] Next, a printed layer with a thickness of 3 μm was formed by a gravure printing method using urethane ink on the upper surface of the base layer, and a surface layer with a thickness of 10 μm was formed on the upper surface of the printed layer by a slot die method to form a Flake layer.
[0142] And, as an ultraviolet curing compound, 70.5% by weight of urethane acrylate oligomer, 15% by weight of isobornyl acrylate monomer, 10% by weight of 2-hydroxyethyl acrylate monomer, 0.5% by weight % photoinitiator and 4% by weight...
experiment example 1
[0151] Experimental Example 1: Embossing retention rate
[0152] Detection method: using a confocal microscope (DCM3D, LEICA) under the conditions of Magnification: x100, Stitching3X3, the average value of the embossing that exists on the upper surface of each decorative sheet according to the above-mentioned Example 1 and the above-mentioned Comparative Examples 1 and 2 is produced. Depth, M i Tested. Next, apply heat and pressure to each of the above-mentioned decorative sheets at a temperature of 135° C. and a pressure of 290 Pa for 2 minutes, and then, after standing at room temperature for 10 minutes, use a confocal microscope to examine the particles present on the upper surface under the same conditions. Average depth of embossing, M f Tested.
[0153] The above M obtained by this i and above M f Values were substituted into the following formula 1 to calculate the embossment retention rate.
[0154] Formula 1
[0155] Embossing maintenance rate (%) = 1-(M f -...
experiment example 2
[0156] Experimental Example 2: Elongation
[0157] Detection method: according to JIS K 6251-1 conditions, use a universal testing machine (Zwick-Roell Universal Testing Machine, Z100) to perform detection, and calculate the elongation according to the following formula 2, specifically, calculate the elongation under heating conditions. Specifically, after standing in a high-temperature chamber at a temperature of 35°C for 1 minute and taking it out, the length was measured before stretching at normal temperature, and then stretched at normal temperature to measure the length at break.
[0158] Tensile conditions: dumbbell-shaped test piece, tensile speed: 600mm / min, gauge length: 60mm
[0159] Formula 2
[0160] Elongation under heating conditions (%) = (length at break - initial length) / initial length x 100
[0161] In the above formula 2, the above-mentioned initial length is the length detected before stretching under normal temperature conditions after being placed in...
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