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A preparation method for extracting carbon and preserving manganese by converting high-manganese, high-sulfur, and high-phosphorus iron into hot water

A converter smelting and molten iron technology, which is applied in the manufacture of converters, etc., can solve the problems of no relevant research reports on the smelting process of carbon extraction and manganese preservation, and achieve excellent slag dephosphorization and desulfurization effects, good slag dephosphorization, and avoid splashing Effect

Active Publication Date: 2020-04-10
WUKUN STEEL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, domestic steel mills basically use low-Mn, low-S and low-P molten iron with the following chemical composition (Mn≤0.60wt%, S≤0.040wt%, Si0.30-0.55wt%, P≤0.100wt%) Smelting, there are some domestic research reports on the converter smelting process of the above-mentioned molten iron composition, but there is no relevant research report on the smelting process using high-manganese, high-sulfur, high-phosphorus molten iron to extract carbon and preserve manganese

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0016] The preparation method of converter smelting high manganese, high sulfur and high phosphorus hot metal to extract carbon and preserve manganese in the present invention comprises the following process steps:

[0017] A. Smelting and loading process: After the steel tapping and slag splashing of the upper furnace, 1 / 2 of the final slag is kept in the converter, according to 4.0-5.0kg / t 钢 The amount, add conventional active lime to the converter; according to 60-80kg / t 钢 The scrap steel is put into the ratio, and the scrap steel is added to the 50-ton LD converter; according to 990-1010kg / t 钢 The molten iron is loaded into the ratio, and the following temperature and mass ratio of high manganese, high sulfur and high phosphorus molten iron are added to the 50-ton LD converter: molten iron temperature ≥ 1320 ° C, molten iron composition C 4.5-5.0wt%, Si 0.20-0.40wt%, S 0.070-0.090wt%, Mn 1.20-1.90wt%, P 0.120-0.200wt%, the rest is Fe and unavoidable impurities;

[0018] ...

Embodiment 1

[0029] A. Smelting and loading process: After the steel tapping and slag splashing of the upper furnace, 1 / 2 of the final slag is kept in the converter, according to 4.0kg / t 钢 The amount, add conventional active lime to the converter; according to 60kg / t 钢 The ratio of steel scrap is loaded into a 50-ton LD converter with the following mass ratios of steel scrap: C 0.21wt%, Si 0.40wt%, Mn 1.15wt%, P 0.030wt%, S 0.025wt%, the rest is Fe and unavoidable impurity; according to 1010kg / t 钢 The molten iron is loaded into the ratio, and the following temperature and mass ratio of high-manganese, high-sulfur, and high-phosphorus molten iron are added to a 50-ton LD converter: molten iron temperature 1320 ° C, molten iron composition C 4.5wt%, Si 0.20wt%, S 0.070wt%, Mn1 .20wt%, P 0.120wt%, the rest is Fe and unavoidable impurities.

[0030] B. Pre-smelting process: In step A, after the high-manganese and high-phosphorus molten iron and steel scrap cold material are loaded into a 50-...

Embodiment 2

[0035] A. Smelting and loading process: After the steel tapping and slag splashing of the upper furnace, 1 / 2 of the final slag is kept in the converter, according to 4.5kg / t 钢 The amount, add conventional active lime to the converter; according to 70kg / t 钢 The proportion of scrap steel is loaded into the 50-ton LD converter with the following mass ratio of scrap steel: C 0.23wt%, Si 0.50wt%, Mn 1.30wt%, P 0.036wt%, S 0.030wt%, the rest is Fe and unavoidable impurity; according to 1000kg / t 钢 The molten iron is loaded into the ratio, and the following temperature and mass ratio of high-manganese, high-sulfur, and high-phosphorus molten iron are added to a 50-ton LD converter: molten iron temperature 1340 ° C, molten iron composition C 4.8wt%, Si 0.30wt%, S 0.080wt%, Mn1 .60wt%, P 0.160wt%, the rest is Fe and unavoidable impurities.

[0036] B. Pre-smelting process: In step A, after the high-manganese and high-phosphorus molten iron and steel scrap cold material are loaded into...

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PUM

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Abstract

The invention discloses a preparation method for carbon extraction and manganese consercation in medium-manganese high-sulfur high-phosphorus molten steel (Mn is 1.20-1.90wt%, Si is 0.070-0.090wt%, Pis 0.120-0.200wt% and S is 0.20-0.40wt%) in converter steel making. By adopting the preparation method, processes such as slag retention operation, addition of a small amount of manganese spheres at the early stage of smelting, little slag smelting, constant pressure gun conversion operation in the smelting process, lowest gun position pressing operation in primary pouring of a converter, and slagwash of whole-process steel discharge, are integrated and created, smelting reaction kinetic and thermodynamic conditions are improved, excellent slugging and phosphorus removal effects are achieved,molten steel and slag splashing in the smelting process is avoided, a MnO allocation concentration is effectively increased, reduction of the MnO at the medium stage of smelting is promoted, secondary oxidation of Mn in molten steel at the later smelting stage is reduced, furthermore, the content of residual Mn in the molten steel at a final point is remarkably increased (0.40-0.60wt%), the addition amount of a manganese alloy in a deoxidation alloying process is reduced, the steel making alloy consumption and alloying cost can be remarkably reduced, improvement of economic indexes of a smelting technique is promoted, and the market competitiveness of products can be improved.

Description

technical field [0001] The invention belongs to the technical field of iron and steel metallurgy and steelmaking technology, and in particular relates to a preparation method for converting high manganese, high sulfur and high phosphorus iron into hot water to extract carbon and preserve manganese. Background technique [0002] Manganese (Mn) element is a beneficial element in steel. During the converter smelting process, with the continuous blowing process, most of the Mn in the molten iron is oxidized. The alloy cost is higher. The Mn content of molten steel at the end of converter smelting mainly comes from Mn in molten iron. During the blowing process, manganese oxidation and reduction reactions occur between the molten metal pool, slag and oxygen, and the residual Mn content in molten steel at the end of converter is affected by The influence of factors such as the amount of slag, the oxidation of molten steel and slag at the end of the converter, and the temperature a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C5/32C21C7/064C22C38/04
CPCC21C5/32C21C7/064C22C38/04
Inventor 陈伟高连坤董瑜苏华林杨春雷赵卫东张瑜曹云徐涛王卫东张红斌赵亮
Owner WUKUN STEEL
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